File name: Pandora103s1_Downsview_20190807_L2Fit_fwvt1c10d20181123p1-8.txt File generation date: 20241101T044742.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c10p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20190801.txt Level 1 file used: Pandora103s1_Downsview_20190807_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20190807 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 1620 1769 Nominal wavelengths inside fitting window [nm]: 492.0103 492.1315 492.2527 492.3739 492.4950 492.6162 492.7373 492.8584 492.9795 493.1006 493.2216 493.3426 493.4637 493.5847 493.7057 493.8266 493.9476 494.0685 494.1894 494.3103 494.4312 494.5521 494.6730 494.7938 494.9146 495.0354 495.1562 495.2770 495.3977 495.5185 495.6392 495.7599 495.8806 496.0012 496.1219 496.2425 496.3631 496.4837 496.6043 496.7249 496.8454 496.9660 497.0865 497.2070 497.3275 497.4480 497.5684 497.6888 497.8093 497.9297 498.0500 498.1704 498.2907 498.4111 498.5314 498.6517 498.7720 498.8922 499.0125 499.1327 499.2529 499.3731 499.4933 499.6135 499.7336 499.8537 499.9739 500.0940 500.2140 500.3341 500.4541 500.5742 500.6942 500.8142 500.9341 501.0541 501.1740 501.2940 501.4139 501.5338 501.6536 501.7735 501.8933 502.0132 502.1330 502.2528 502.3725 502.4923 502.6120 502.7318 502.8515 502.9711 503.0908 503.2105 503.3301 503.4497 503.5693 503.6889 503.8085 503.9280 504.0476 504.1671 504.2866 504.4061 504.5255 504.6450 504.7644 504.8838 505.0032 505.1226 505.2420 505.3613 505.4807 505.6000 505.7193 505.8385 505.9578 506.0770 506.1963 506.3155 506.4347 506.5539 506.6730 506.7922 506.9113 507.0304 507.1495 507.2685 507.3876 507.5066 507.6257 507.7447 507.8637 507.9826 508.1016 508.2205 508.3394 508.4583 508.5772 508.6961 508.8149 508.9338 509.0526 509.1714 509.2902 509.4089 509.5277 509.6464 509.7651 509.8838 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190807T101937.0Z 7158.430290 351 1 32.08 2 89.74 67.20 146.40 344.32 0.00 1 0.00 1 0 36 1.563e-01 1.420e-01 1.503e-01 1.422e-01 1.698393e+04 1.059893e+04 1.451972e+03 -6.000000e+00 8.258099e+03 287.28 -2.00 20.00 -2.00 505.25 0.00e+00 2.719463e-03 3.905030e-03 5.318726e-05 -6.000000e+00 4.342094e-03 287.28 -2.00 20.00 -2.00 499.86 0.00e+00 1.367249e+00 2.889571e+00 5.271013e-02 -6.000000e+00 3.047384e+00 232.21 -2.00 3.57 -2.00 501.52 0.00e+00 19.945 0.155 489.00 513.00 1 1.0448e+01 2.2149e-01 3.5786e-02 -6.0000e+00 2.3245e-01 1.4110e-01 5.7685e-02 2.7782e-03 -6.0000e+00 6.2622e-02 2.8818e-06 -5.9817e-03 1.0250e-02 1.4249e-04 -6.0000e+00 1.2233e-02 -1.9565e-02 -2.0468e-04 12 8 8 10 0 0 -0.53 14.99 8.94 -0.01957 -0.06106 8 1 1 4 0 4000.000 22.19 14.99 19.12 900000 -26387 31632 6381 14826 9996 9709 1347 14500 -9002 -7650 -2627 -2502 -3594 -5507 -3202 1320 12418 -9574 7688 -16369 16123 -17648 8367 10879 -7754 -758 14199 -157 13940 13384 -6298 9456 -5852 -1035 -2192 54000 3067 14131 -15941 10700 -13495 -1324 -8269 25365 -1866 2887 5663 2473 -14593 5592 24721 14409 17491 -194 36337 4178 18450 -4502 24221 -19860 49311 -2505 11086 -14672 -25766 8601 12186 -11926 31774 -4450 -3988 -10107 14794 17214 535 -26544 -5689 18320 -9577 -6748 -5097 41048 -16858 40701 -4021 1101 2325 19741 2646 16943 -12961 10128 1172 16178 3859 8179 293 -4549 -1458 2509 986 6712 18211 -29150 1587 1291 19343 1513 3498 -4980 36 -9865 1719 20684 -9919 -21945 32342 -5837 13335 11033 12375 13916 16274 12630 420 11066 -145 23470 -4490 15013 -17517 7054 -13283 19830 -24042 23514 9922 3834 22264 -13922 -16230 25264 -6005 -10001 6202 -8806 9898 -4961 10849 900000 -33264 23224 6188 13803 9991 9913 1522 14592 -11342 -9363 -3004 -2823 -4030 -6182 -3486 1375 11772 -11510 8086 -21968 15778 -23857 8793 11190 -9632 -881 14238 -179 13579 12511 -6929 8967 -6545 -1153 -2571 37125 3378 13805 -20509 10541 -16777 -1477 -9980 22465 -2172 3224 6118 2716 -18576 5717 20313 12689 14707 -194 26469 4300 16971 -5205 21133 -26265 33526 -2818 10992 -18625 -36077 8486 11369 -13823 23977 -4667 -4108 -11054 12853 14847 549 -35014 -5964 14890 -10037 -6822 -5063 26399 -18948 26541 -4086 1075 2236 15899 2477 13742 -14052 8933 1146 13600 3521 6848 254 -3996 -1219 1979 782 5133 13080 -35211 1494 1233 15395 1400 3132 -4884 34 -10469 1636 16398 -10503 -26156 23331 -6199 11790 9792 10549 11344 12762 10349 392 9320 -137 17566 -4364 12162 -19241 5947 -13385 14504 -26787 16966 8379 3472 17080 -15362 -18495 19438 -6264 -10840 5733 -9328 8603 -4838 8905 SO 20190807T102359.0Z 7158.433322 355 1 32.01 2 89.01 67.95 146.60 346.13 0.00 1 0.00 1 0 15 1.006e-01 9.361e-02 9.781e-02 9.368e-02 8.062659e+03 6.646619e+03 6.009127e+02 -6.000000e+00 5.311940e+03 287.28 -2.00 20.00 -2.00 505.17 0.00e+00 2.829755e-03 2.559888e-03 1.734342e-04 -6.000000e+00 2.788719e-03 287.28 -2.00 20.00 -2.00 499.53 0.00e+00 2.957824e+00 1.936268e+00 4.420006e-02 -6.000000e+00 1.946900e+00 232.21 -2.00 3.57 -2.00 501.21 0.00e+00 18.552 0.124 489.00 513.00 1 1.0120e+01 1.4809e-01 3.1761e-02 -6.0000e+00 1.4878e-01 1.5131e-01 3.8855e-02 2.0197e-03 -6.0000e+00 3.9631e-02 4.4527e-06 4.3572e-05 7.0230e-03 5.6104e-05 -6.0000e+00 7.8478e-03 -1.6043e-02 1.0760e-04 12 8 8 10 0 0 -6.89 15.00 5.95 -0.01604 -0.01574 8 1 1 4 0 4000.000 22.19 15.00 19.13 -20420 6148 -627 13183 8630 570 2256 4467 865 136 5465 4159 20357 2683 3317 16394 -4914 -10374 6153 -4278 4258 12339 -5012 -12926 4276 -55 1894 -6311 8867 8249 -14688 21146 -3651 6753 -2415 11163 -14233 7727 -6157 10710 -17173 22511 -5929 7096 -4404 -1653 -8186 -5890 -9438 -1076 -3830 -3381 -3150 -3181 2936 3790 -170 7287 1409 12490 1702 12564 7503 -5689 837 11183 329 6917 -5817 -5041 950 -18761 -595 5642 12873 -1059 1664 29057 -10971 19167 4912 -2845 -9738 1857 -14788 17576 66 1824 -11576 30423 -10632 -3385 -40 -4085 -2676 3091 6965 8596 2004 -9854 24599 -8333 14424 -731 6721 -3781 -5040 -5956 17888 6994 19665 3555 5166 -5779 -9164 -6804 12873 -11778 3271 -1798 934 18248 16620 -14149 -603 -14504 -11364 -5531 103 -1331 628 18590 4461 10626 -2077 11185 -13747 -11665 -2958 -3470 3223 2948 18303 14385 7601 -1287 8649 8056 -4656 3069 -25224 5926 -666 12779 8997 654 2600 5107 1026 161 5983 4548 18746 2877 3493 15175 -5636 -12822 6693 -5245 4792 12819 -6148 -17122 4833 -66 2188 -7854 9346 8359 -17936 18194 -4046 7021 -2866 11764 -18920 8164 -7334 10689 -22384 20100 -7050 7525 -5284 -1941 -10196 -7073 -11527 -1184 -4180 -3554 -3232 -3257 2905 3866 -185 7458 1523 12010 1807 12064 7603 -6537 896 10631 340 6578 -6188 -5233 913 -21759 -583 5271 11383 -1067 1590 20728 -11351 14696 4307 -2707 -9940 1698 -16063 14096 63 1687 -12069 21038 -10939 -3285 -39 -4094 -2591 2742 5773 6794 1644 -8841 15587 -7312 10502 -650 5789 -3627 -4830 -5637 13212 5760 14621 3139 4539 -5675 -9309 -6763 10690 -12565 3011 -1706 845 13642 12434 -14362 -543 -14949 -11370 -5222 92 -1204 556 13513 3635 8079 -1774 8521 -13715 -11620 -2736 -3268 2866 2634 14171 11612 6554 -1203 7205 6546 -4161 2529 SO 20190807T102815.0Z 7158.436285 359 1 32.01 2 88.30 68.69 146.78 347.92 0.00 1 0.00 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