File name: Pandora103s1_Downsview_20190819_L2Fit_fwvt1c10d20181123p1-8.txt File generation date: 20241101T051520.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c10p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20190801.txt Level 1 file used: Pandora103s1_Downsview_20190819_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20190819 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 1620 1769 Nominal wavelengths inside fitting window [nm]: 492.0103 492.1315 492.2527 492.3739 492.4950 492.6162 492.7373 492.8584 492.9795 493.1006 493.2216 493.3426 493.4637 493.5847 493.7057 493.8266 493.9476 494.0685 494.1894 494.3103 494.4312 494.5521 494.6730 494.7938 494.9146 495.0354 495.1562 495.2770 495.3977 495.5185 495.6392 495.7599 495.8806 496.0012 496.1219 496.2425 496.3631 496.4837 496.6043 496.7249 496.8454 496.9660 497.0865 497.2070 497.3275 497.4480 497.5684 497.6888 497.8093 497.9297 498.0500 498.1704 498.2907 498.4111 498.5314 498.6517 498.7720 498.8922 499.0125 499.1327 499.2529 499.3731 499.4933 499.6135 499.7336 499.8537 499.9739 500.0940 500.2140 500.3341 500.4541 500.5742 500.6942 500.8142 500.9341 501.0541 501.1740 501.2940 501.4139 501.5338 501.6536 501.7735 501.8933 502.0132 502.1330 502.2528 502.3725 502.4923 502.6120 502.7318 502.8515 502.9711 503.0908 503.2105 503.3301 503.4497 503.5693 503.6889 503.8085 503.9280 504.0476 504.1671 504.2866 504.4061 504.5255 504.6450 504.7644 504.8838 505.0032 505.1226 505.2420 505.3613 505.4807 505.6000 505.7193 505.8385 505.9578 506.0770 506.1963 506.3155 506.4347 506.5539 506.6730 506.7922 506.9113 507.0304 507.1495 507.2685 507.3876 507.5066 507.6257 507.7447 507.8637 507.9826 508.1016 508.2205 508.3394 508.4583 508.5772 508.6961 508.8149 508.9338 509.0526 509.1714 509.2902 509.4089 509.5277 509.6464 509.7651 509.8838 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190819T103251.0Z 7170.439479 175 1 32.01 2 89.74 72.41 55.99 225.68 0.00 1 0.00 1 0 15 2.364e-02 2.368e-02 2.093e-02 2.072e-02 9.238361e+03 1.403912e+03 5.611346e+02 -6.000000e+00 1.247732e+03 287.16 -2.00 20.00 -2.00 505.26 0.00e+00 4.244135e-03 5.616556e-04 2.541365e-04 -6.000000e+00 6.560570e-04 287.16 -2.00 20.00 -2.00 500.07 0.00e+00 1.979156e+00 4.136447e-01 7.476939e-02 -6.000000e+00 4.598419e-01 231.56 -2.00 3.57 -2.00 501.70 0.00e+00 19.960 0.155 489.00 513.00 1 8.4261e+00 3.1584e-02 3.6425e-02 -6.0000e+00 3.5088e-02 1.2032e-01 8.3189e-03 2.4566e-03 -6.0000e+00 9.4367e-03 2.1178e-05 -4.2669e-04 1.5353e-03 8.0261e-05 -6.0000e+00 1.8483e-03 1.8184e-02 -3.4191e-04 12 8 8 10 0 0 16.23 15.00 1.92 0.01818 0.01522 8 1 1 4 0 4000.000 22.19 15.00 19.13 900000 -3107 -294 -3652 3009 17 1860 -2965 3970 -646 -97 -2457 2007 -1929 -647 -184 -2256 753 -1667 2941 -578 462 -3947 2684 -2744 2846 1393 -1205 280 143 -4865 1447 -5300 -2047 839 4500 528 4991 -1276 -21 974 4564 5360 -1481 1030 1968 2205 303 2962 -185 1507 -4930 -183 -2469 1312 -3516 -990 941 2267 294 2224 1106 -1373 1720 438 -1800 -475 -616 -200 789 -5168 2406 2551 -2274 -567 1432 -1815 -63 -6143 2155 -1836 4387 2308 -1682 670 2386 -295 2927 2215 -2634 823 -2887 1446 -1171 1162 1034 -615 427 353 -6346 3348 273 1010 59 -1691 -472 3706 -325 -438 -579 -1568 -1373 -3301 2986 4099 1328 -326 3499 -1031 1527 -910 5774 -2147 200 -2620 1668 -1906 770 -1958 1143 -2525 -176 376 2475 1606 -479 2104 -1598 2328 142 1530 -3092 1495 -3019 -2442 1792 -1870 -1481 -723 115 900000 -3021 -286 -3828 3063 18 1992 -3386 4259 -718 -105 -2679 2068 -2027 -662 -187 -2347 774 -1812 3135 -638 503 -4484 2860 -3105 3077 1524 -1347 305 150 -5133 1422 -5613 -2166 905 4801 581 5168 -1386 -22 1017 4630 5467 -1635 1126 2153 2409 334 3130 -198 1538 -5175 -179 -2453 1280 -3739 -1062 1008 2401 315 2325 1174 -1504 1831 470 -1947 -496 -632 -202 780 -5311 2282 2430 -2296 -573 1426 -1828 -61 -6160 1976 -1741 3936 2127 -1613 634 2249 -286 2732 2062 -2551 771 -2829 1388 -1169 1121 969 -568 378 305 -5698 2679 225 848 52 -1612 -453 3388 -304 -402 -531 -1478 -1319 -3275 2811 3830 1276 -321 3370 -1043 1488 -889 5165 -2032 185 -2532 1553 -1839 725 -1882 1067 -2452 -164 340 2166 1407 -430 1896 -1527 2165 137 1467 -3113 1445 -3064 -2468 1733 -1849 -1420 -667 104 SO 20190819T103716.0Z 7170.442546 179 1 32.01 2 88.98 73.17 56.54 226.80 0.00 1 0.00 1 0 15 1.290e-02 1.291e-02 1.098e-02 1.089e-02 1.292788e+04 7.674739e+02 8.254979e+02 -6.000000e+00 6.808968e+02 287.16 -2.00 20.00 -2.00 505.29 0.00e+00 3.084627e-03 2.955934e-04 1.764231e-04 -6.000000e+00 3.578420e-04 287.16 -2.00 20.00 -2.00 500.15 0.00e+00 1.519095e+00 2.160593e-01 8.209491e-02 -6.000000e+00 2.504921e-01 231.56 -2.00 3.57 -2.00 501.77 0.00e+00 18.492 0.123 489.00 513.00 1 8.0045e+00 1.6484e-02 3.2173e-02 -6.0000e+00 1.9122e-02 1.0265e-01 4.3263e-03 2.5529e-03 -6.0000e+00 5.1307e-03 4.1432e-05 3.5169e-04 7.9058e-04 8.4793e-05 -6.0000e+00 1.0083e-03 -1.5022e-02 -1.3844e-05 12 8 8 10 0 0 -0.46 15.00 1.07 -0.01502 -0.01258 8 1 1 4 0 4000.000 22.19 15.00 19.13 900000 -2779 -799 -1345 1441 -575 1007 713 2192 -407 338 -685 -1762 -2342 -1984 515 -1902 80 -1953 -63 2096 -46 972 -1213 1294 851 -99 1336 -1601 -394 997 -547 -511 918 1557 304 386 4 -535 -5 -562 196 1745 752 1060 -6 2064 1501 2685 -1431 -1009 -3661 465 -4001 -931 -427 1028 1134 501 -138 373 1384 -1212 1412 -615 2442 436 -1158 918 401 -859 -379 -938 1132 -24 -408 552 1005 1610 -145 -252 -647 -630 -1342 1518 -755 127 -789 -700 -870 -1109 1825 964 786 867 340 368 961 52 -2247 600 -389 86 241 -453 703 1008 1257 -2571 -624 168 -378 -7 -385 301 1621 93 3105 1408 -1205 793 -981 1696 -889 244 -1 145 -2770 1368 -1957 541 -85 -359 -3149 -341 -1018 -750 -841 2569 -2019 -285 283 -1118 222 979 -977 1066 2002 631 -1926 900000 -2674 -778 -1372 1477 -612 1078 777 2366 -446 360 -727 -1863 -2445 -2040 516 -1964 83 -2127 -69 2243 -51 1049 -1337 1405 934 -109 1449 -1759 -411 987 -547 -517 949 1673 337 423 5 -574 -5 -594 207 1838 810 1155 -7 2241 1620 2821 -1533 -1043 -3755 450 -4018 -929 -441 1080 1206 536 -148 395 1459 -1318 1499 -662 2516 449 -1188 914 396 -844 -370 -926 1111 -25 -413 542 955 1499 -136 -236 -612 -599 -1288 1436 -740 123 -769 -674 -832 -1065 1724 937 771 831 316 329 827 44 -1907 487 -322 73 217 -433 675 959 1172 -2441 -582 159 -365 -7 -377 293 1557 91 3032 1405 -1216 767 -940 1553 -838 230 -1 138 -2710 1278 -1892 512 -79 -326 -2922 -307 -934 -706 -807 2410 -2009 -282 280 -1126 222 969 -981 1034 1875 583 -1809 SO 20190819T104128.0Z 7170.445463 183 1 32.01 2 88.26 73.89 57.08 227.85 0.00 1 0.00 1 0 22 8.148e-03 8.025e-03 4.084e-03 4.066e-03 1.624738e+04 2.888937e+02 1.062945e+03 -6.000000e+00 4.300705e+02 287.16 -2.00 20.00 -2.00 505.38 0.00e+00 3.412194e-03 1.106987e-04 1.892746e-04 -6.000000e+00 2.260200e-04 287.16 -2.00 20.00 -2.00 500.55 0.00e+00 1.802712e+00 7.885502e-02 9.891353e-02 -6.000000e+00 1.582152e-01 231.56 -2.00 3.57 -2.00 502.12 0.00e+00 16.648 0.090 489.00 513.00 1 7.1584e+00 6.0165e-03 2.8185e-02 -6.0000e+00 1.2078e-02 2.5983e-02 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