File name: Pandora103s1_Downsview_20190901_L2Fit_fwvt1c10d20181123p1-8.txt File generation date: 20241101T054049.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c10p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20190801.txt Level 1 file used: Pandora103s1_Downsview_20190901_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20190901 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 1620 1769 Nominal wavelengths inside fitting window [nm]: 492.0103 492.1315 492.2527 492.3739 492.4950 492.6162 492.7373 492.8584 492.9795 493.1006 493.2216 493.3426 493.4637 493.5847 493.7057 493.8266 493.9476 494.0685 494.1894 494.3103 494.4312 494.5521 494.6730 494.7938 494.9146 495.0354 495.1562 495.2770 495.3977 495.5185 495.6392 495.7599 495.8806 496.0012 496.1219 496.2425 496.3631 496.4837 496.6043 496.7249 496.8454 496.9660 497.0865 497.2070 497.3275 497.4480 497.5684 497.6888 497.8093 497.9297 498.0500 498.1704 498.2907 498.4111 498.5314 498.6517 498.7720 498.8922 499.0125 499.1327 499.2529 499.3731 499.4933 499.6135 499.7336 499.8537 499.9739 500.0940 500.2140 500.3341 500.4541 500.5742 500.6942 500.8142 500.9341 501.0541 501.1740 501.2940 501.4139 501.5338 501.6536 501.7735 501.8933 502.0132 502.1330 502.2528 502.3725 502.4923 502.6120 502.7318 502.8515 502.9711 503.0908 503.2105 503.3301 503.4497 503.5693 503.6889 503.8085 503.9280 504.0476 504.1671 504.2866 504.4061 504.5255 504.6450 504.7644 504.8838 505.0032 505.1226 505.2420 505.3613 505.4807 505.6000 505.7193 505.8385 505.9578 506.0770 506.1963 506.3155 506.4347 506.5539 506.6730 506.7922 506.9113 507.0304 507.1495 507.2685 507.3876 507.5066 507.6257 507.7447 507.8637 507.9826 508.1016 508.2205 508.3394 508.4583 508.5772 508.6961 508.8149 508.9338 509.0526 509.1714 509.2902 509.4089 509.5277 509.6464 509.7651 509.8838 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190901T104726.0Z 7183.449607 382 1 32.01 2 89.73 78.74 114.71 62.10 0.00 1 0.00 1 0 15 1.920e-01 1.628e-01 1.594e-01 1.484e-01 2.320319e+04 1.124333e+04 1.625640e+03 -6.000000e+00 1.009094e+04 286.06 -2.00 20.00 -2.00 505.43 0.00e+00 6.445572e-03 4.025609e-03 1.085277e-04 -6.000000e+00 5.309720e-03 286.06 -2.00 20.00 -2.00 500.25 0.00e+00 7.099884e-01 2.919230e+00 9.832890e-02 -6.000000e+00 3.713658e+00 230.36 -2.00 3.57 -2.00 501.89 0.00e+00 19.973 0.155 489.00 513.00 1 1.0472e+01 2.2214e-01 3.6683e-02 -6.0000e+00 2.8365e-01 1.0240e-01 5.7757e-02 3.4764e-03 -6.0000e+00 7.5658e-02 2.7289e-06 -1.3234e-04 1.0203e-02 1.0883e-04 -6.0000e+00 1.4981e-02 1.0040e-02 -1.2780e-04 12 8 8 10 0 0 -0.90 15.00 16.18 0.01004 0.00912 8 1 1 4 0 4000.000 22.19 15.00 19.14 33745 -21651 -2909 -6912 23212 30840 -9477 9932 -22364 -12035 -10158 6702 -12825 38128 13549 -5991 -9913 1229 -14590 13948 6605 -5105 23709 -2882 -4570 30490 4844 7410 27408 -5667 20480 23974 27331 -5851 -103 10348 -7207 -2657 27957 -17744 -52 -25538 -19056 -13715 9279 5554 -9958 3752 20536 -7307 34883 5163 67956 19191 14993 20576 1722 -1430 8203 38188 -19634 8219 21024 10831 -17293 15233 -12551 -10866 5911 41627 -25993 -2061 -2732 41261 14449 35123 14921 -11840 25966 -21065 47703 -9470 -14010 5466 24782 7366 10178 -9108 1740 6336 26860 30547 15702 30604 725 7357 40357 -23133 8178 -8856 26766 -16476 11682 40210 -8655 -4561 8698 -12489 -17310 50970 -14971 5623 16419 3851 -4106 25173 -8342 10387 6110 -13351 8900 -23370 30289 -8204 15237 8472 -22318 -12781 -7075 3373 3986 -614 14022 -869 27674 -11152 -13292 -2615 -6193 -10893 13085 -7377 15693 -14610 25413 13926 -3090 3734 1945 5491 22819 -25131 -2911 -7515 19495 24523 -11345 10006 -30806 -14819 -12009 6636 -15105 27039 12019 -6395 -11063 1257 -17936 13293 6735 -5815 20470 -3219 -5245 25199 5113 7606 22852 -6221 16847 18996 21251 -6487 -113 10460 -8530 -2965 22969 -22395 -55 -35134 -25020 -17385 9579 5998 -12492 4082 18746 -8550 26396 5037 35693 16038 13377 18136 1876 -1630 8523 29587 -26441 8526 19442 11061 -23039 14614 -15406 -12898 5911 29154 -34236 -2150 -2890 29002 13345 26570 13373 -13351 20056 -25290 29408 -10125 -15723 5106 19506 6940 9318 -9922 1678 5768 20080 22359 13541 22961 700 6341 24138 -24444 6277 -7855 16592 -15571 8769 24571 -8979 -4676 7852 -13612 -19449 29955 -16947 5316 14055 3715 -4261 19717 -9170 9823 6104 -15908 8331 -28877 21782 -8547 12879 7691 -27374 -14350 -7471 3229 3791 -594 11529 -823 19939 -11838 -14818 -2667 -6582 -12326 11937 -8254 14127 -17595 20733 12591 -3243 3585 1858 5041 SO 20190901T105144.0Z 7183.452593 386 1 32.01 2 88.97 79.49 114.07 62.98 0.00 1 0.00 1 0 15 5.215e-02 5.091e-02 5.067e-02 5.005e-02 1.501445e+04 3.565341e+03 8.167953e+02 -6.000000e+00 2.740786e+03 286.06 -2.00 20.00 -2.00 505.39 0.00e+00 -1.339506e-04 1.355330e-03 7.574163e-05 -6.000000e+00 1.442827e-03 286.06 -2.00 20.00 -2.00 500.41 0.00e+00 2.134872e+00 9.764948e-01 1.126697e-01 -6.000000e+00 1.012048e+00 230.36 -2.00 3.57 -2.00 502.02 0.00e+00 18.480 0.123 489.00 513.00 1 9.5837e+00 7.4356e-02 3.2491e-02 -6.0000e+00 7.7228e-02 4.5779e-02 1.9453e-02 2.9803e-03 -6.0000e+00 2.0732e-02 8.4970e-06 -3.9844e-03 3.5350e-03 7.4816e-05 -6.0000e+00 4.0759e-03 -6.2003e-03 -9.2448e-05 12 8 8 10 0 0 13.42 15.00 3.37 -0.00620 -0.03384 8 1 1 4 0 4000.000 22.19 15.00 19.15 900000 -5845 10479 -1405 2901 -3814 -3583 -1538 -1189 -5522 -5131 5179 7219 1209 13327 271 -6040 -3911 -2001 11139 -9245 -4333 -2091 8342 5220 5435 -3306 11577 -2718 -614 1940 2226 -5962 4067 -9155 -3082 2326 -2546 -5560 2067 10399 1478 3750 -6481 7650 -1408 -1455 -2750 5477 -7556 6588 -471 -796 1241 3051 -177 967 -3826 3923 4535 -2408 7454 -1314 -1145 -1063 5088 -1803 9709 1843 1881 84 -1931 -5729 357 -2702 1321 3853 1253 -5188 -1747 -2099 -7032 -505 -1963 8301 9631 8345 -5386 1851 -6083 2155 -1221 8019 5839 6517 -4137 -1964 -8332 11007 -3920 9790 3553 5101 -7 7098 -4838 -2078 8547 -7798 -2966 3164 -710 -2582 7776 7726 -10307 -1626 3992 1133 -2936 498 -2728 823 6235 -6327 -4168 -3679 6390 1658 -1143 -9902 3857 -625 242 -6049 -2257 2428 -5512 2294 -5293 4063 3139 -654 989 4324 827 8671 2547 -3701 -3335 900000 -5498 8625 -1354 2782 -3987 -3822 -1642 -1277 -6159 -5605 5048 6827 1192 11530 265 -6324 -4090 -2125 10735 -10927 -4881 -2306 8306 5389 5642 -3727 11250 -3010 -644 1900 2149 -6291 4004 -10761 -3517 2507 -2831 -6285 2138 9849 1530 3833 -7399 7712 -1565 -1618 -3066 5550 -8536 6296 -465 -769 1163 2852 -177 994 -4198 4004 4569 -2577 7266 -1406 -1227 -1134 5055 -1878 8870 1797 1814 81 -1885 -5844 348 -2767 1311 3667 1188 -5139 -1657 -1986 -7017 -478 -1893 7337 8557 7556 -5555 1764 -6209 2028 -1197 7319 5501 5982 -4047 -1804 -7842 8367 -3382 7272 2816 4114 -6 6365 -5042 -2113 7731 -8097 -2917 2978 -706 -2636 7184 7127 -11299 -1653 3932 1164 -3117 501 -2755 782 5597 -6511 -4230 -3720 5876 1588 -1124 -10665 3575 -590 225 -5960 -2162 2292 -5764 2250 -5681 4047 3184 -693 1038 4398 869 8358 2551 -3838 -3401 SO 20190901T105557.0Z 7183.455521 390 1 32.01 2 88.22 80.21 113.43 63.83 0.00 1 0.00 1 0 15 3.530e-02 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