File name: Pandora103s1_Downsview_20190907_L2Fit_fwvt1c10d20181123p1-8.txt File generation date: 20241101T053554.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c10p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20190801.txt Level 1 file used: Pandora103s1_Downsview_20190907_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20190907 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 1620 1769 Nominal wavelengths inside fitting window [nm]: 492.0103 492.1315 492.2527 492.3739 492.4950 492.6162 492.7373 492.8584 492.9795 493.1006 493.2216 493.3426 493.4637 493.5847 493.7057 493.8266 493.9476 494.0685 494.1894 494.3103 494.4312 494.5521 494.6730 494.7938 494.9146 495.0354 495.1562 495.2770 495.3977 495.5185 495.6392 495.7599 495.8806 496.0012 496.1219 496.2425 496.3631 496.4837 496.6043 496.7249 496.8454 496.9660 497.0865 497.2070 497.3275 497.4480 497.5684 497.6888 497.8093 497.9297 498.0500 498.1704 498.2907 498.4111 498.5314 498.6517 498.7720 498.8922 499.0125 499.1327 499.2529 499.3731 499.4933 499.6135 499.7336 499.8537 499.9739 500.0940 500.2140 500.3341 500.4541 500.5742 500.6942 500.8142 500.9341 501.0541 501.1740 501.2940 501.4139 501.5338 501.6536 501.7735 501.8933 502.0132 502.1330 502.2528 502.3725 502.4923 502.6120 502.7318 502.8515 502.9711 503.0908 503.2105 503.3301 503.4497 503.5693 503.6889 503.8085 503.9280 504.0476 504.1671 504.2866 504.4061 504.5255 504.6450 504.7644 504.8838 505.0032 505.1226 505.2420 505.3613 505.4807 505.6000 505.7193 505.8385 505.9578 506.0770 506.1963 506.3155 506.4347 506.5539 506.6730 506.7922 506.9113 507.0304 507.1495 507.2685 507.3876 507.5066 507.6257 507.7447 507.8637 507.9826 508.1016 508.2205 508.3394 508.4583 508.5772 508.6961 508.8149 508.9338 509.0526 509.1714 509.2902 509.4089 509.5277 509.6464 509.7651 509.8838 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190907T105408.0Z 7189.454259 388 1 32.01 2 89.73 81.83 153.18 316.42 0.00 1 0.00 1 0 50 1.915e-01 1.656e-01 1.872e-01 1.734e-01 2.174527e+04 1.414679e+04 5.284224e+02 -6.000000e+00 1.004261e+04 285.55 -2.00 20.00 -2.00 505.36 0.00e+00 5.238828e-03 4.700310e-03 4.109536e-04 -6.000000e+00 5.286739e-03 285.55 -2.00 20.00 -2.00 499.97 0.00e+00 5.092441e+00 3.532866e+00 2.307165e-01 -6.000000e+00 3.698562e+00 229.80 -2.00 3.57 -2.00 501.63 0.00e+00 19.987 0.156 489.00 513.00 1 1.0332e+01 2.6890e-01 4.0815e-02 -6.0000e+00 2.8252e-01 3.5078e-02 6.8233e-02 4.3983e-03 -6.0000e+00 7.5254e-02 2.3085e-06 -7.4646e-03 1.1721e-02 7.4177e-05 -6.0000e+00 1.4937e-02 -3.0141e-02 1.9515e-04 12 8 8 10 0 0 2.99 14.99 16.47 -0.03014 -0.08192 8 1 1 4 0 4000.000 21.98 14.99 18.90 -9756 32503 -3812 2845 -4869 25805 -1752 21708 4037 8371 1709 -2030 -355 -17492 -585 -3629 -2650 -18130 -21829 -7810 10239 -17516 4379 -1904 6730 15670 61682 349 30765 -2196 1955 10641 1683 2863 -2959 11829 13358 -27585 24830 2234 11206 24899 18304 -9758 2055 5579 -14434 28811 22018 8546 -14092 333 15049 41960 -24532 10060 17019 -4999 -19880 21958 12935 3781 -13788 31123 -32213 -9503 9322 35603 23847 8414 21215 43 1702 -5964 36937 14959 24453 1578 20209 42196 -30269 -19122 -21825 7055 34603 2543 -19238 16662 -5705 28968 24410 -1567 -18484 -10251 -14380 7319 12674 22977 6925 -8245 5909 20700 -14556 18036 -41 -6544 11909 5664 -8031 7373 16427 14788 5480 -6181 -12555 -5229 84591 14299 28037 6237 -4410 -9217 -21501 2414 13599 2080 31190 28131 27623 -17214 -6174 234 -14067 -9774 26369 11482 -7175 39271 -17959 -2779 17442 -7830 8653 -2211 -19716 29232 4657 -502 -9166 16072 -10204 22657 -3855 2815 -5396 21780 -1967 19863 4408 8724 1862 -2255 -384 -21914 -615 -3907 -2838 -22891 -29439 -9476 10499 -23390 4739 -2191 7182 15522 39406 400 26116 -2473 2023 9986 1735 2996 -3433 12277 13612 -40978 22018 2430 11120 21795 17297 -12238 2336 6200 -19499 25480 20471 8883 -17694 352 13462 28727 -32162 9825 16092 -5951 -27400 20112 12823 4099 -17834 26215 -49672 -11618 9312 27073 20021 8084 17676 43 1697 -6458 26932 13541 19835 1544 16195 27060 -38434 -21781 -25621 6287 23909 2421 -22628 13766 -5743 20590 18013 -1493 -21119 -10947 -15626 6165 9645 15159 5184 -7015 4301 13060 -13226 12725 -37 -6495 9976 4980 -7902 6236 12994 12141 4960 -6259 -13494 -5226 36329 12325 21653 5917 -4537 -9640 -24586 2181 11217 1937 22115 20679 20354 -19480 -6325 222 -14897 -9879 18906 9583 -7375 26499 -21142 -2874 15154 -8764 8332 -2372 -25001 23105 4613 -513 -9941 13536 SO 20190907T105837.0Z 7189.457373 392 1 32.01 2 88.92 82.61 153.70 318.29 0.00 1 0.00 1 0 15 8.727e-02 8.286e-02 8.674e-02 8.449e-02 1.948363e+04 6.430015e+03 7.071476e+02 -6.000000e+00 4.577033e+03 285.55 -2.00 20.00 -2.00 505.29 0.00e+00 7.873672e-03 2.294676e-03 4.947691e-04 -6.000000e+00 2.410042e-03 285.55 -2.00 20.00 -2.00 500.10 0.00e+00 1.799224e+00 1.682308e+00 2.282071e-01 -6.000000e+00 1.686898e+00 229.80 -2.00 3.57 -2.00 501.70 0.00e+00 18.394 0.121 489.00 513.00 1 1.0040e+01 1.2851e-01 3.7419e-02 -6.0000e+00 1.2883e-01 9.1736e-02 3.3056e-02 4.3422e-03 -6.0000e+00 3.4358e-02 4.9150e-06 1.3098e-03 5.8090e-03 1.2909e-04 -6.0000e+00 6.8091e-03 1.6255e-02 -1.5258e-04 12 8 8 10 0 0 95.89 15.00 1.34 0.01626 0.02534 8 1 1 4 0 4000.000 21.98 15.00 18.91 -18010 7656 -16653 10572 12369 17930 4701 3479 -1597 -8585 -7887 2917 12255 -3078 4639 28 6313 -12363 23348 -1414 -2932 4443 10589 -5014 4976 1559 4761 -6528 -3506 -6349 -2214 2424 -2318 -7959 -7807 3398 13761 4064 -128 16023 1933 809 -214 5343 -5930 8905 -3980 6962 -3458 -7145 -4402 12583 -1046 1887 6453 -4448 8139 4463 -5884 -1441 -13554 7168 8498 -6231 4136 1961 11479 -5804 10301 -1762 -4850 1861 -6015 -3220 8008 -990 10719 -5808 10594 -2001 -6529 477 -17639 5775 2365 8095 3927 -3014 -5166 2402 -11071 7364 -10886 4395 -5687 1785 -11255 14039 -12719 28946 846 8539 -1545 4771 -9985 23135 2963 -11721 4873 -1069 12952 -6783 1289 -589 5188 6857 -5248 -1440 2233 -5005 13483 3323 11843 420 4480 5258 12604 296 1556 -2394 14915 5800 2604 -8909 -5146 10928 -16849 9064 -1926 -3601 -439 -4547 -1466 13602 4340 -11504 -17390 4651 21182 3480 -20044 6724 -19158 9772 11571 16191 4927 3737 -1802 -10207 -9094 2985 11278 -3227 4464 28 6008 -14387 19846 -1552 -3252 4580 10280 -5681 5178 1691 4997 -7617 -3897 -6932 -2242 2344 -2382 -8978 -9195 3637 13151 4201 -136 14442 2002 857 -233 5606 -7055 9256 -4683 7286 -3942 -8272 -4805 11310 -1054 1850 6223 -4967 8282 4764 -6938 -1617 -17067 7444 8774 -7417 4424 2106 11005 -6463 9717 -1838 -5118 1836 -6451 -3404 7706 -1035 9744 -6026 9247 -1952 -6610 453 -20007 5236 2244 7336 3689 -2990 -5141 2195 -11539 6525 -11774 4110 -5685 1585 -10845 10222 -11742 17506 659 6222 -1288 3985 -10139 17391 2691 -12067 4214 -988 10734 -6927 1227 -572 4760 6200 -5430 -1474 2223 -5267 11560 3049 9799 391 4069 4767 10700 284 1464 -2351 12364 5108 2316 -8827 -4914 9078 -18829 7986 -1901 -3675 -439 -4766 -1497 12004 4174 -12805 -20152 4242 16096 3126 SO 20190907T110301.0Z 7189.460428 396 1 32.01 2 88.14 83.37 154.20 320.19 0.00 1 0.00 1 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