File name: Pandora103s1_Downsview_20190911_L2Fit_fwvt1c10d20181123p1-8.txt File generation date: 20241101T054143.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c10p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20190801.txt Level 1 file used: Pandora103s1_Downsview_20190911_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20190911 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 1620 1769 Nominal wavelengths inside fitting window [nm]: 492.0103 492.1315 492.2527 492.3739 492.4950 492.6162 492.7373 492.8584 492.9795 493.1006 493.2216 493.3426 493.4637 493.5847 493.7057 493.8266 493.9476 494.0685 494.1894 494.3103 494.4312 494.5521 494.6730 494.7938 494.9146 495.0354 495.1562 495.2770 495.3977 495.5185 495.6392 495.7599 495.8806 496.0012 496.1219 496.2425 496.3631 496.4837 496.6043 496.7249 496.8454 496.9660 497.0865 497.2070 497.3275 497.4480 497.5684 497.6888 497.8093 497.9297 498.0500 498.1704 498.2907 498.4111 498.5314 498.6517 498.7720 498.8922 499.0125 499.1327 499.2529 499.3731 499.4933 499.6135 499.7336 499.8537 499.9739 500.0940 500.2140 500.3341 500.4541 500.5742 500.6942 500.8142 500.9341 501.0541 501.1740 501.2940 501.4139 501.5338 501.6536 501.7735 501.8933 502.0132 502.1330 502.2528 502.3725 502.4923 502.6120 502.7318 502.8515 502.9711 503.0908 503.2105 503.3301 503.4497 503.5693 503.6889 503.8085 503.9280 504.0476 504.1671 504.2866 504.4061 504.5255 504.6450 504.7644 504.8838 505.0032 505.1226 505.2420 505.3613 505.4807 505.6000 505.7193 505.8385 505.9578 506.0770 506.1963 506.3155 506.4347 506.5539 506.6730 506.7922 506.9113 507.0304 507.1495 507.2685 507.3876 507.5066 507.6257 507.7447 507.8637 507.9826 508.1016 508.2205 508.3394 508.4583 508.5772 508.6961 508.8149 508.9338 509.0526 509.1714 509.2902 509.4089 509.5277 509.6464 509.7651 509.8838 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190911T105837.0Z 7193.457373 301 1 32.01 2 89.72 83.93 119.77 272.61 0.00 1 0.00 1 0 15 1.834e-02 1.817e-02 1.554e-02 1.548e-02 8.923097e+03 1.009593e+03 5.708140e+02 -6.000000e+00 9.605320e+02 285.22 -2.00 20.00 -2.00 505.36 0.00e+00 3.598677e-03 4.190704e-04 1.696069e-04 -6.000000e+00 5.060860e-04 285.22 -2.00 20.00 -2.00 500.47 0.00e+00 2.031688e+00 2.989104e-01 6.901250e-02 -6.000000e+00 3.544246e-01 229.43 -2.00 3.57 -2.00 502.07 0.00e+00 19.994 0.156 489.00 513.00 1 8.1330e+00 2.2831e-02 3.6218e-02 -6.0000e+00 2.7066e-02 6.4683e-02 5.9344e-03 2.4598e-03 -6.0000e+00 7.2191e-03 2.8434e-05 -3.6311e-04 1.1498e-03 7.3746e-05 -6.0000e+00 1.4306e-03 -4.9724e-03 -3.4940e-05 12 8 8 10 0 0 13.73 15.00 4.19 -0.00497 -0.00749 8 1 1 4 0 4000.000 22.09 15.00 18.95 -4066 -3873 -1595 -1972 -1160 -160 -976 -1557 1471 2447 -2635 -2137 452 -1428 -604 -1144 -462 -803 -658 1337 2698 222 -1298 1798 240 -207 1185 797 -2103 535 -2626 -117 -317 -264 -777 4035 2327 1246 -764 223 425 -1934 3480 -71 2188 1721 3022 465 2282 22 2866 -2231 -1215 -1997 266 250 -113 1242 2242 -128 1280 760 1634 -284 102 235 766 2284 154 -644 -469 -866 1089 1401 -2036 201 -4679 -353 -1281 -1040 -1317 1372 -76 -528 -1728 338 116 -2729 1709 2335 2730 42 2181 826 -474 2366 2358 -1254 -1040 -3105 1188 -3196 -2499 1891 1166 1800 703 -1803 -262 -1888 -2506 1502 2670 -783 2688 2505 638 2178 78 2188 374 -344 -3671 2033 -1183 3010 162 -1631 870 1315 286 -1355 -2311 -699 -2496 -3775 -2202 2623 -39 -1072 2283 1753 1182 -249 493 582 716 -2138 -3608 -4541 -3724 -3569 -1484 -1924 -1159 -161 -1015 -1656 1525 2487 -2755 -2195 447 -1413 -586 -1115 -451 -803 -680 1385 2758 232 -1378 1856 254 -221 1247 840 -2245 534 -2605 -113 -311 -268 -830 4194 2432 1297 -800 229 434 -2038 3527 -75 2312 1842 3192 498 2365 22 2807 -2223 -1175 -1941 259 254 -118 1305 2336 -135 1331 799 1718 -304 109 246 781 2257 154 -640 -457 -845 1052 1368 -2091 202 -4823 -340 -1228 -987 -1250 1278 -72 -506 -1696 330 113 -2725 1621 2192 2559 40 2127 825 -472 2223 2150 -1148 -928 -2759 996 -2816 -2258 1727 1124 1747 683 -1762 -248 -1821 -2485 1461 2602 -795 2647 2476 650 2219 81 2202 375 -339 -3683 1945 -1185 2903 161 -1650 855 1292 284 -1339 -2256 -666 -2405 -3727 -2206 2562 -39 -1113 2319 1795 1224 -263 518 608 736 -2197 -3660 -4611 SO 20190911T110308.2Z 7193.460511 305 1 32.30 2 88.91 84.71 120.55 273.39 0.00 1 0.00 1 0 43 1.894e-02 1.866e-02 1.593e-03 1.581e-03 1.389098e+04 1.027621e+02 9.288884e+02 -6.000000e+00 9.917900e+02 285.22 -2.00 20.00 -2.00 505.46 0.00e+00 4.520316e-03 4.306409e-05 2.150067e-04 -6.000000e+00 5.231700e-04 285.22 -2.00 20.00 -2.00 501.18 0.00e+00 1.464493e+00 2.975955e-02 9.554887e-02 -6.000000e+00 3.678826e-01 229.43 -2.00 3.57 -2.00 502.63 0.00e+00 18.372 0.121 489.00 513.00 1 5.9406e+00 2.2679e-03 3.2313e-02 -6.0000e+00 2.8056e-02 -4.7883e-02 5.8666e-04 2.8215e-03 -6.0000e+00 7.5487e-03 3.2784e-04 7.1276e-03 1.1439e-04 1.2387e-04 -6.0000e+00 1.4810e-03 8.3746e-03 -3.0006e-04 12 8 8 10 0 0 48.58 15.00 8.27 0.00837 0.05781 9 2 1 4 0 3587.750 22.09 15.00 18.96 900000 -6460 -4550 -1766 -807 -12 1100 1633 1574 635 -383 -725 -1983 -2710 -2966 -2703 -2141 -638 1123 1242 1421 1006 1125 1407 2206 2202 1927 1448 233 -1903 -3123 -3113 -1770 298 2030 2013 1526 569 542 168 23 313 985 1943 2756 2922 2443 1826 1005 333 -1692 -2761 -3246 -2813 -1631 278 1604 1925 1669 1396 1764 2207 2364 2267 2031 1417 301 -432 -694 -1643 -2525 -2010 -1353 -251 293 -175 -1542 -2168 -2159 -2802 -2207 -1505 -954 -908 -561 -273 -419 -292 -478 -396 195 1396 2523 2723 2662 1771 938 74 -1684 -3103 -4053 -3159 -1709 666 1361 1487 170 -1361 -1984 -1606 -464 164 1109 1734 2767 2937 3459 3262 2260 785 -155 -379 -423 611 1186 1118 1128 643 433 940 545 -785 -1600 -2558 -2786 -2032 -1182 131 305 1158 639 391 371 1046 1404 1030 -81 -2138 -3932 -3765 900000 -5711 -4104 -1624 -759 -12 983 1474 1426 574 -343 -645 -1762 -2390 -2604 -2371 -1893 -571 1025 1153 1316 936 1049 1317 2077 2089 1833 1381 221 -1762 -2844 -2846 -1629 281 1976 1986 1495 557 525 162 23 307 976 1943 2783 2975 2497 1859 1018 333 -1672 -2681 -3118 -2704 -1605 280 1649 1999 1738 1452 1830 2307 2492 2401 2147 1485 314 -447 -714 -1684 -2576 -2046 -1385 -259 284 -171 -1598 -2209 -2178 -2830 -2217 -1516 -963 -923 -537 -264 -406 -281 -457 -376 185 1337 2451 2652 2527 1761 908 70 -1591 -2915 -3801 -2984 -1663 628 1341 1485 171 -1367 -1981 -1617 -475 170 1151 1801 2852 3039 3631 3510 2470 858 -167 -400 -441 638 1252 1187 1206 693 466 1015 590 -840 -1698 -2734 -2988 -2209 -1317 137 322 1238 696 430 412 1158 1551 1138 -90 -2339 -4287 -4096 SO 20190911T110721.1Z 7193.463439 309 1 34.21 2 88.15 85.44 121.27 274.14 0.00 1 0.00 1 0 29 1.246e-02 1.211e-02 9.830e-04 9.774e-04 1.735548e+04 6.690904e+01 1.141938e+03 -6.000000e+00 6.526671e+02 285.22 -2.00 20.00 -2.00 505.44 0.00e+00 4.321766e-03 2.651873e-05 2.318114e-04 -6.000000e+00 3.438345e-04 285.22 -2.00 20.00 -2.00 500.99 0.00e+00 1.282463e+00 1.835742e-02 1.124601e-01 -6.000000e+00 2.407765e-01 229.43 -2.00 3.57 -2.00 502.51 0.00e+00 16.412 0.086 489.00 513.00 1 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