File name: Pandora103s1_Downsview_20190920_L2Fit_fwvt1c10d20181123p1-8.txt File generation date: 20241101T054108.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c10p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20190801.txt Level 1 file used: Pandora103s1_Downsview_20190920_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20190920 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 1620 1769 Nominal wavelengths inside fitting window [nm]: 492.0103 492.1315 492.2527 492.3739 492.4950 492.6162 492.7373 492.8584 492.9795 493.1006 493.2216 493.3426 493.4637 493.5847 493.7057 493.8266 493.9476 494.0685 494.1894 494.3103 494.4312 494.5521 494.6730 494.7938 494.9146 495.0354 495.1562 495.2770 495.3977 495.5185 495.6392 495.7599 495.8806 496.0012 496.1219 496.2425 496.3631 496.4837 496.6043 496.7249 496.8454 496.9660 497.0865 497.2070 497.3275 497.4480 497.5684 497.6888 497.8093 497.9297 498.0500 498.1704 498.2907 498.4111 498.5314 498.6517 498.7720 498.8922 499.0125 499.1327 499.2529 499.3731 499.4933 499.6135 499.7336 499.8537 499.9739 500.0940 500.2140 500.3341 500.4541 500.5742 500.6942 500.8142 500.9341 501.0541 501.1740 501.2940 501.4139 501.5338 501.6536 501.7735 501.8933 502.0132 502.1330 502.2528 502.3725 502.4923 502.6120 502.7318 502.8515 502.9711 503.0908 503.2105 503.3301 503.4497 503.5693 503.6889 503.8085 503.9280 504.0476 504.1671 504.2866 504.4061 504.5255 504.6450 504.7644 504.8838 505.0032 505.1226 505.2420 505.3613 505.4807 505.6000 505.7193 505.8385 505.9578 506.0770 506.1963 506.3155 506.4347 506.5539 506.6730 506.7922 506.9113 507.0304 507.1495 507.2685 507.3876 507.5066 507.6257 507.7447 507.8637 507.9826 508.1016 508.2205 508.3394 508.4583 508.5772 508.6961 508.8149 508.9338 509.0526 509.1714 509.2902 509.4089 509.5277 509.6464 509.7651 509.8838 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190920T110841.0Z 7202.464363 195 1 32.01 2 89.73 88.73 31.06 220.90 0.00 1 0.00 1 0 29 3.705e-02 3.622e-02 3.616e-02 3.577e-02 7.295275e+03 2.325268e+03 6.979534e+02 -6.000000e+00 1.932770e+03 284.25 -2.00 20.00 -2.00 505.29 0.00e+00 2.838119e-03 9.624514e-04 1.816156e-04 -6.000000e+00 1.019590e-03 284.25 -2.00 20.00 -2.00 500.13 0.00e+00 2.651698e+00 7.049038e-01 2.677809e-02 -6.000000e+00 7.147627e-01 228.46 -2.00 3.57 -2.00 501.77 0.00e+00 20.039 0.157 489.00 513.00 1 8.9666e+00 5.3843e-02 3.5964e-02 -6.0000e+00 5.4582e-02 9.5716e-02 1.4090e-02 2.0778e-03 -6.0000e+00 1.4538e-02 1.1875e-05 1.1131e-03 2.6783e-03 7.8001e-05 -6.0000e+00 2.8903e-03 -8.8288e-03 8.1524e-05 12 8 8 10 0 0 14.99 15.00 2.31 -0.00883 -0.00111 8 1 1 4 0 4000.000 22.09 15.00 18.97 -133 -5367 7679 2883 -1271 -3079 5894 -2956 3881 2576 1 -173 159 3658 -1952 -2869 -210 357 679 -5240 -2063 1960 588 150 -4921 1773 -2442 298 -1321 1646 -1692 1802 -6002 -3149 4543 3479 276 1057 -929 -1936 4322 622 6088 -1144 5638 -530 6365 -2259 2195 593 -3078 -2003 -251 -4498 630 -1015 -2470 -3448 653 -1085 -4035 1664 307 5281 -3269 -1425 -1226 626 718 5913 -2652 -1173 4156 2516 -4414 -1550 647 6787 4466 -6068 -2507 6830 4566 -435 746 -5347 2575 -1885 4266 -1923 67 -3549 2573 3007 6277 877 3286 -142 996 -7104 -4123 1815 -3328 3385 3427 1079 9852 -1751 -6261 488 -3175 8231 -2374 2178 -8668 3128 187 -1040 -6682 1439 -2391 1450 2687 -681 -2562 163 -2120 2168 636 1535 -496 2397 -7297 4883 3954 467 5652 -5040 5936 1104 -2130 -4445 1140 -6713 4327 7033 -347 -6261 8775 336 -123 -5292 6903 2836 -1339 -3363 6034 -3345 4114 2729 1 -183 165 3592 -2005 -2971 -214 371 728 -6051 -2304 2105 639 164 -5709 1936 -2766 327 -1444 1671 -1718 1769 -6460 -3434 4799 3754 303 1134 -1003 -2085 4379 658 6186 -1263 5909 -593 6631 -2525 2311 620 -3222 -2011 -243 -4545 623 -1062 -2693 -3832 696 -1166 -4449 1747 328 5379 -3590 -1510 -1270 626 711 5473 -2623 -1144 3882 2424 -4622 -1570 625 6016 4000 -5978 -2384 5983 4106 -412 708 -5438 2422 -1839 3889 -1855 64 -3542 2471 2891 5729 820 2913 -127 854 -6431 -3579 1505 -3006 3025 3182 1030 8510 -1659 -6102 448 -3091 7299 -2361 2088 -9251 2986 186 -1058 -7163 1401 -2365 1351 2445 -648 -2509 156 -2073 2031 602 1448 -476 2182 -7157 4217 3429 426 5054 -5093 5455 1078 -2161 -4629 1130 -7223 4187 6596 -343 -6354 7500 311 SO 20190920T111304.0Z 7202.467407 199 1 32.01 2 88.94 89.49 31.57 222.60 0.00 1 0.00 1 0 22 1.898e-02 1.881e-02 1.858e-02 1.844e-02 1.012379e+04 1.239345e+03 6.905527e+02 -6.000000e+00 9.901264e+02 284.25 -2.00 20.00 -2.00 505.29 0.00e+00 3.198126e-03 4.961961e-04 1.604434e-04 -6.000000e+00 5.226599e-04 284.25 -2.00 20.00 -2.00 500.19 0.00e+00 1.164997e+00 3.633221e-01 6.349249e-02 -6.000000e+00 3.675521e-01 228.46 -2.00 3.57 -2.00 501.81 0.00e+00 18.469 0.123 489.00 513.00 1 8.6032e+00 2.7705e-02 3.1772e-02 -6.0000e+00 2.8037e-02 1.1038e-01 7.2954e-03 2.2740e-03 -6.0000e+00 7.5231e-03 2.3552e-05 4.2819e-04 1.3537e-03 7.6733e-05 -6.0000e+00 1.4829e-03 -1.4076e-02 -8.7990e-06 12 8 8 10 0 0 -8.03 15.00 2.02 -0.01408 -0.01111 8 1 1 4 0 4000.000 22.09 15.00 18.98 900000 -4191 -3169 -2355 -1073 -1788 2297 1002 141 597 -1429 -1127 -1372 -1069 874 479 220 1176 1224 -1974 1646 1528 -932 340 -1414 1393 824 1850 -2382 78 -2627 435 -2535 -1248 -2616 1728 1483 248 1260 832 -661 1586 5422 3300 354 1034 2818 164 -248 -1836 -1748 -1835 2418 979 -2888 355 -610 2353 2939 -784 419 2293 -1769 -759 278 2309 1700 -1855 203 -1688 94 888 2931 2004 -3336 3191 -3076 -725 -598 -1605 715 -1089 -2726 1763 -2362 -393 1439 1589 35 189 -898 -1062 2574 4136 4823 1689 2520 -476 -3092 -2403 777 17 2555 -2478 2878 -1395 -676 -2723 328 2206 1323 -1481 -706 390 144 1213 1786 117 596 1795 -1117 -661 -2933 262 -513 779 840 1212 -548 959 -756 -3141 -3426 834 -2185 -843 -2096 -1137 -1679 -776 1440 2139 3008 -66 1812 -1749 1771 -3824 798 -2319 900000 -4079 -3148 -2423 -1126 -1923 2425 1088 154 646 -1544 -1197 -1441 -1099 871 478 222 1199 1289 -2190 1762 1635 -1020 368 -1569 1513 897 1986 -2623 81 -2677 429 -2600 -1310 -2915 1879 1598 266 1321 866 -696 1645 5488 3454 386 1131 3025 179 -267 -1965 -1810 -1840 2279 933 -2925 363 -648 2466 3062 -840 442 2389 -1931 -821 296 2375 1723 -1913 204 -1696 91 852 2781 1947 -3470 3118 -3119 -700 -568 -1528 664 -1036 -2650 1646 -2324 -384 1383 1515 33 180 -866 -1037 2480 3960 4501 1572 2252 -424 -2757 -2079 641 14 2156 -2321 2686 -1376 -656 -2644 304 2011 1241 -1454 -695 382 141 1182 1749 118 602 1764 -1103 -635 -2827 246 -492 740 799 1148 -524 907 -727 -3022 -3229 748 -2005 -773 -2002 -1097 -1644 -764 1402 2074 2905 -66 1778 -1768 1703 -3771 732 -2173 SO 20190920T111714.0Z 7202.470301 203 1 32.01 2 88.19 90.21 32.07 224.17 0.00 1 0.00 1 0 15 1.234e-02 1.216e-02 1.081e-02 1.074e-02 9.976218e+03 7.196637e+02 7.069395e+02 -6.000000e+00 6.436286e+02 284.25 -2.00 20.00 -2.00 505.31 0.00e+00 2.742469e-03 2.896619e-04 1.342611e-04 -6.000000e+00 3.396891e-04 284.25 -2.00 20.00 -2.00 500.25 0.00e+00 1.752662e+00 2.109109e-01 5.797843e-02 -6.000000e+00 2.388188e-01 228.46 -2.00 3.57 -2.00 501.87 0.00e+00 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