File name: Pandora103s1_Downsview_20190921_L2Fit_fwvt1c10d20181123p1-8.txt File generation date: 20241101T054153.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c10p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20190801.txt Level 1 file used: Pandora103s1_Downsview_20190921_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20190921 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 1620 1769 Nominal wavelengths inside fitting window [nm]: 492.0103 492.1315 492.2527 492.3739 492.4950 492.6162 492.7373 492.8584 492.9795 493.1006 493.2216 493.3426 493.4637 493.5847 493.7057 493.8266 493.9476 494.0685 494.1894 494.3103 494.4312 494.5521 494.6730 494.7938 494.9146 495.0354 495.1562 495.2770 495.3977 495.5185 495.6392 495.7599 495.8806 496.0012 496.1219 496.2425 496.3631 496.4837 496.6043 496.7249 496.8454 496.9660 497.0865 497.2070 497.3275 497.4480 497.5684 497.6888 497.8093 497.9297 498.0500 498.1704 498.2907 498.4111 498.5314 498.6517 498.7720 498.8922 499.0125 499.1327 499.2529 499.3731 499.4933 499.6135 499.7336 499.8537 499.9739 500.0940 500.2140 500.3341 500.4541 500.5742 500.6942 500.8142 500.9341 501.0541 501.1740 501.2940 501.4139 501.5338 501.6536 501.7735 501.8933 502.0132 502.1330 502.2528 502.3725 502.4923 502.6120 502.7318 502.8515 502.9711 503.0908 503.2105 503.3301 503.4497 503.5693 503.6889 503.8085 503.9280 504.0476 504.1671 504.2866 504.4061 504.5255 504.6450 504.7644 504.8838 505.0032 505.1226 505.2420 505.3613 505.4807 505.6000 505.7193 505.8385 505.9578 506.0770 506.1963 506.3155 506.4347 506.5539 506.6730 506.7922 506.9113 507.0304 507.1495 507.2685 507.3876 507.5066 507.6257 507.7447 507.8637 507.9826 508.1016 508.2205 508.3394 508.4583 508.5772 508.6961 508.8149 508.9338 509.0526 509.1714 509.2902 509.4089 509.5277 509.6464 509.7651 509.8838 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190921T110952.0Z 7203.465185 187 1 32.01 2 89.72 89.27 24.20 199.78 0.00 1 0.00 1 0 15 3.802e-02 3.741e-02 3.402e-02 3.368e-02 1.025476e+04 2.281915e+03 7.230857e+02 -6.000000e+00 1.983231e+03 284.13 -2.00 20.00 -2.00 505.30 0.00e+00 2.530549e-03 9.089326e-04 1.406709e-04 -6.000000e+00 1.047099e-03 284.13 -2.00 20.00 -2.00 500.20 0.00e+00 1.502217e+00 6.660956e-01 6.039004e-02 -6.000000e+00 7.371102e-01 228.34 -2.00 3.57 -2.00 501.82 0.00e+00 20.030 0.157 489.00 513.00 1 8.9908e+00 5.0772e-02 3.6157e-02 -6.0000e+00 5.6214e-02 1.1110e-01 1.3382e-02 2.4593e-03 -6.0000e+00 1.5102e-02 1.2636e-05 -2.0375e-03 2.4872e-03 7.8835e-05 -6.0000e+00 2.9714e-03 3.8368e-03 -1.8915e-04 12 8 8 10 0 0 87.49 15.00 3.41 0.00384 -0.01030 8 1 1 4 0 4000.000 22.19 15.00 19.08 900000 -2620 -1444 -2224 9173 -1622 4472 -3262 1455 1474 -412 -3536 2149 -6230 961 -4758 -2225 -6628 5141 -4838 5355 3080 -1783 557 2702 -4774 4959 498 -5921 -965 -1587 3788 -999 5010 624 -1135 -1653 141 3852 4033 -2041 2071 -4009 1224 390 3778 3215 2729 -363 2299 1270 -3073 3426 -406 6438 -2611 538 -6462 4078 -22 100 741 -724 -665 -3730 1677 -1232 -355 4723 -1682 7106 1400 275 1434 -3226 1083 434 -2170 -4476 5406 2050 -569 -5380 -682 -3401 6766 3814 -1671 -6428 10619 -3697 2921 -1030 3939 -2577 4014 6618 892 1059 -853 -2503 -2222 595 -3787 8337 -1582 1596 1442 1770 -6044 -2248 2737 933 1317 -2294 -1041 9518 2432 -2074 2212 2392 3629 -2801 -2271 -8594 3264 -3643 -1903 -10486 5395 -4337 3548 -711 3803 -4891 706 -2125 773 -4060 3718 7090 631 -273 2071 578 162 353 -6094 7651 -3663 900000 -2488 -1392 -2255 8622 -1727 4583 -3673 1574 1582 -442 -3848 2185 -6750 958 -4990 -2290 -7250 5181 -5519 5545 3255 -1974 602 2882 -5520 5203 544 -6806 -1018 -1614 3616 -1009 4918 671 -1273 -1850 153 3966 4090 -2184 2138 -4442 1305 425 4024 3445 2907 -392 2377 1286 -3137 3205 -391 5904 -2721 562 -7359 4200 -24 105 781 -780 -717 -4132 1739 -1288 -361 4521 -1693 6444 1333 266 1392 -3338 1081 428 -2130 -4415 4803 1873 -536 -5354 -650 -3366 6156 3583 -1648 -6580 9147 -3660 2736 -1023 3779 -2596 3674 5710 787 909 -729 -2132 -1891 506 -3548 7330 -1567 1525 1356 1626 -5969 -2179 2577 904 1279 -2312 -1037 8623 2400 -2155 2179 2302 3368 -2708 -2183 -8915 3031 -3620 -1862 -11085 4887 -4337 3228 -657 3328 -4629 636 -2027 734 -4085 3516 6566 625 -274 2043 579 162 350 -6253 6668 -3514 SO 20190921T111408.0Z 7203.468148 191 1 32.01 2 88.95 90.01 24.46 202.06 0.00 1 0.00 1 0 36 2.388e-02 2.343e-02 6.912e-03 6.889e-03 7.420544e+03 4.178286e+02 4.885853e+02 -6.000000e+00 1.245368e+03 284.13 -2.00 20.00 -2.00 505.33 0.00e+00 3.761097e-03 1.857957e-04 1.637541e-04 -6.000000e+00 6.572203e-04 284.13 -2.00 20.00 -2.00 500.88 0.00e+00 1.401497e+00 1.297263e-01 6.150760e-02 -6.000000e+00 4.611262e-01 228.34 -2.00 3.57 -2.00 502.37 0.00e+00 18.502 0.123 489.00 513.00 1 7.5321e+00 9.9050e-03 3.1864e-02 -6.0000e+00 3.5204e-02 1.9604e-02 2.5746e-03 2.1543e-03 -6.0000e+00 9.3897e-03 6.7088e-05 2.0780e-03 5.1571e-04 7.5929e-05 -6.0000e+00 1.8628e-03 8.0347e-04 -6.2423e-05 12 8 8 10 0 0 40.85 15.00 10.81 0.00080 0.01522 8 1 1 4 0 4000.000 22.19 15.00 19.08 -7110 -6861 -5962 -4138 -9 -314 1784 890 1957 980 798 -1960 -1507 -3193 -3580 -3543 -2101 -1639 296 1316 2218 657 829 1439 2044 3719 2925 1973 -420 -1077 -4282 -3262 -3306 714 1583 2961 2634 2279 45 71 349 2189 1591 1964 2841 2186 3424 433 2479 -287 -488 -2668 -3389 -1843 -1375 -523 2086 2958 1960 1101 2707 3041 3502 3905 2835 732 104 1260 -1336 -1375 -1942 -2746 -858 377 -757 413 -2604 -2177 -3737 -3078 -2424 -1223 -704 -1022 -1491 263 -692 -848 22 440 990 1400 3004 2361 2756 2114 2568 -867 55 -4275 -3582 -4225 -1368 669 2121 1934 420 -1621 -2319 -2217 155 1067 1763 2038 2338 2807 4922 3965 2583 1178 -248 -495 -1275 559 2084 180 638 516 -571 158 405 -2314 -1255 -3158 -4052 -2987 -895 -281 210 152 1564 141 1058 30 2000 1972 302 -3078 -3902 -6095 -6152 -6008 -5367 -3832 -8 -295 1682 861 1877 939 750 -1871 -1413 -2996 -3342 -3307 -1955 -1558 286 1284 2142 645 814 1410 2014 3628 2872 1950 -417 -1031 -4099 -3095 -3193 691 1596 2987 2635 2259 45 71 346 2154 1599 2001 2917 2279 3520 453 2509 -293 -483 -2615 -3286 -1764 -1353 -533 2136 3044 2036 1148 2776 3139 3631 4045 2954 767 108 1270 -1372 -1392 -1948 -2779 -862 381 -788 424 -2691 -2187 -3772 -3073 -2407 -1213 -699 -1024 -1524 268 -711 -870 22 442 995 1425 3086 2464 2817 2117 2491 -846 51 -4116 -3381 -4063 -1327 672 2194 2020 440 -1560 -2217 -2136 149 1042 1735 2021 2323 2789 4853 4006 2644 1203 -252 -493 -1267 552 2058 182 644 522 -581 161 411 -2359 -1241 -3157 -4071 -3020 -916 -292 219 162 1655 152 1138 33 2152 2116 324 -3311 -4124 -6562 SO 20190921T111810.8Z 7203.470959 195 1 21.63 2 88.22 90.71 24.74 204.18 0.00 1 0.00 1 0 57 1.929e-02 1.890e-02 1.743e-03 1.734e-03 1.301283e+04 1.120590e+02 8.732417e+02 -6.000000e+00 1.005991e+03 284.13 -2.00 20.00 -2.00 505.42 0.00e+00 4.342349e-03 4.729156e-05 2.161247e-04 -6.000000e+00 5.311679e-04 284.13 -2.00 20.00 -2.00 501.11 0.00e+00 1.267476e+00 3.259669e-02 9.185777e-02 -6.000000e+00 3.738697e-01 228.34 -2.00 3.57 -2.00 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