File name: Pandora103s1_Downsview_20190925_L2Fit_fwvt1c10d20181123p1-8.txt File generation date: 20241101T060505.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c10p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20190801.txt Level 1 file used: Pandora103s1_Downsview_20190925_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20190925 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 1620 1769 Nominal wavelengths inside fitting window [nm]: 492.0103 492.1315 492.2527 492.3739 492.4950 492.6162 492.7373 492.8584 492.9795 493.1006 493.2216 493.3426 493.4637 493.5847 493.7057 493.8266 493.9476 494.0685 494.1894 494.3103 494.4312 494.5521 494.6730 494.7938 494.9146 495.0354 495.1562 495.2770 495.3977 495.5185 495.6392 495.7599 495.8806 496.0012 496.1219 496.2425 496.3631 496.4837 496.6043 496.7249 496.8454 496.9660 497.0865 497.2070 497.3275 497.4480 497.5684 497.6888 497.8093 497.9297 498.0500 498.1704 498.2907 498.4111 498.5314 498.6517 498.7720 498.8922 499.0125 499.1327 499.2529 499.3731 499.4933 499.6135 499.7336 499.8537 499.9739 500.0940 500.2140 500.3341 500.4541 500.5742 500.6942 500.8142 500.9341 501.0541 501.1740 501.2940 501.4139 501.5338 501.6536 501.7735 501.8933 502.0132 502.1330 502.2528 502.3725 502.4923 502.6120 502.7318 502.8515 502.9711 503.0908 503.2105 503.3301 503.4497 503.5693 503.6889 503.8085 503.9280 504.0476 504.1671 504.2866 504.4061 504.5255 504.6450 504.7644 504.8838 505.0032 505.1226 505.2420 505.3613 505.4807 505.6000 505.7193 505.8385 505.9578 506.0770 506.1963 506.3155 506.4347 506.5539 506.6730 506.7922 506.9113 507.0304 507.1495 507.2685 507.3876 507.5066 507.6257 507.7447 507.8637 507.9826 508.1016 508.2205 508.3394 508.4583 508.5772 508.6961 508.8149 508.9338 509.0526 509.1714 509.2902 509.4089 509.5277 509.6464 509.7651 509.8838 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190925T111428.0Z 7207.468380 305 1 32.01 2 89.72 91.44 46.41 108.42 0.00 1 0.00 1 0 15 3.120e-02 3.095e-02 3.087e-02 3.066e-02 6.588683e+03 1.952595e+03 3.685092e+02 -6.000000e+00 1.624136e+03 283.63 -2.00 20.00 -2.00 505.33 0.00e+00 5.132333e-03 8.254230e-04 2.465474e-04 -6.000000e+00 8.581757e-04 283.63 -2.00 20.00 -2.00 500.37 0.00e+00 3.158804e+00 5.997947e-01 7.183248e-02 -6.000000e+00 6.046555e-01 227.86 -2.00 3.57 -2.00 501.96 0.00e+00 20.036 0.157 489.00 513.00 1 8.7417e+00 4.5779e-02 3.6595e-02 -6.0000e+00 4.6107e-02 6.3357e-02 1.1981e-02 2.3697e-03 -6.0000e+00 1.2387e-02 1.3906e-05 5.1300e-04 2.2964e-03 7.3729e-05 -6.0000e+00 2.4382e-03 1.0113e-02 -2.2827e-04 12 8 8 10 0 0 -6.33 15.00 3.29 0.01011 0.01367 8 1 1 4 0 4000.000 22.09 15.00 19.02 900000 -3921 -1205 -2431 2715 -4409 -1065 100 3479 -2236 2364 -788 64 163 2918 1377 2415 1846 935 722 4077 325 3831 -5883 -3818 826 -5278 4051 -63 -2377 922 41 -2337 -5778 473 -86 2290 778 -1177 50 1985 1750 1764 986 2540 497 -803 7542 3494 -1839 -2826 -4391 3263 -819 1014 -2677 -557 -291 -440 -955 6777 1088 957 1220 1923 -2859 3253 -21 -822 166 5168 -598 -2952 2369 -1374 3114 -3805 2092 -6040 2301 -12378 -2317 -754 2680 -934 -356 -4857 450 10671 -2369 5804 3019 1829 -460 557 -1868 1095 -1703 4050 -3385 -2046 -2192 1227 281 -1805 2417 -4344 -2304 -5071 4001 -609 3446 2293 -2277 -1893 5429 6734 -131 159 1735 3899 3790 -896 1423 32 -977 2624 3521 -2553 1106 -1585 -1897 -2444 -5108 -3127 -1863 371 855 5166 2835 -4195 -1561 -1838 -1907 3656 2070 1409 -2382 1536 -2928 900000 -3677 -1135 -2424 2663 -4725 -1130 107 3603 -2423 2398 -813 65 162 2779 1328 2322 1820 961 761 4157 343 3911 -6611 -4246 886 -5997 4192 -67 -2478 894 40 -2356 -6234 503 -94 2421 821 -1251 52 2019 1799 1839 1052 2711 546 -893 7654 3633 -1976 -2972 -4536 3064 -797 991 -2824 -595 -314 -477 -1032 6763 1154 1024 1303 2030 -3114 3270 -21 -835 165 4791 -583 -2968 2290 -1401 3045 -3891 1965 -6049 2108 -13032 -2227 -718 2469 -900 -344 -4917 430 9146 -2292 5197 2809 1763 -460 545 -1825 1012 -1571 3439 -3010 -1761 -1894 1053 256 -1749 2273 -4311 -2199 -4887 3541 -576 3208 2193 -2304 -1919 5141 6357 -134 162 1719 3709 3537 -862 1349 31 -966 2513 3347 -2563 1076 -1588 -1871 -2368 -5023 -2994 -1777 356 836 4907 2791 -4465 -1624 -1925 -2012 3666 2104 1420 -2417 1457 -2871 SO 20190925T111845.0Z 7207.471354 309 1 32.01 2 88.95 92.18 45.70 109.38 0.00 1 0.00 1 0 22 1.806e-02 1.790e-02 1.507e-02 1.500e-02 1.261212e+04 1.014947e+03 7.241078e+02 -6.000000e+00 9.398468e+02 283.63 -2.00 20.00 -2.00 505.39 0.00e+00 3.391691e-03 4.044687e-04 1.998179e-04 -6.000000e+00 4.964974e-04 283.63 -2.00 20.00 -2.00 500.62 0.00e+00 1.709373e+00 2.887447e-01 1.081429e-01 -6.000000e+00 3.494299e-01 227.86 -2.00 3.57 -2.00 502.19 0.00e+00 18.493 0.123 489.00 513.00 1 8.3394e+00 2.2008e-02 3.2708e-02 -6.0000e+00 2.6653e-02 3.9560e-02 5.7126e-03 2.8543e-03 -6.0000e+00 7.1477e-03 2.9165e-05 1.7305e-03 1.0902e-03 8.7847e-05 -6.0000e+00 1.4106e-03 -2.1214e-02 6.6310e-05 12 8 8 10 0 0 -6.82 15.00 2.24 -0.02121 -0.00921 8 1 1 4 0 4000.000 22.09 15.00 19.02 900000 -1337 -2342 -1434 1912 -252 1057 -1658 835 -436 -475 -937 321 -2815 263 -3389 2325 -2485 1215 -1219 1170 -150 1331 -1115 1585 544 1236 23 34 -660 4313 -4365 533 321 642 2322 2546 -339 -1465 71 -118 -407 187 2624 543 3821 88 976 -2 2849 -2138 -1330 -624 -3548 -3143 -1253 2176 1695 1563 617 2443 -1354 1673 765 578 -698 1917 -1047 531 289 -2217 1079 -618 -1866 -2485 600 164 -615 131 504 -2712 -156 -986 3567 -2845 58 -311 -69 -638 -423 -2480 -871 -1622 2213 1123 520 -3077 -980 -349 -1095 -2107 1891 742 2233 2224 -2446 120 -783 1321 -3221 5296 -273 -42 1873 -1058 -1059 4096 1576 1597 1549 -1332 782 164 392 -82 1682 -232 2208 -1080 2248 -1497 1909 -1391 638 -2826 -278 -2862 -1159 398 2027 683 968 -311 1842 1261 -534 1692 -1072 -3899 -4399 900000 -1184 -2165 -1373 1827 -250 1062 -1738 857 -448 -478 -936 313 -2778 250 -3329 2182 -2500 1220 -1279 1198 -156 1361 -1170 1637 571 1285 24 35 -656 3955 -4347 514 323 673 2432 2629 -355 -1531 73 -121 -420 195 2707 579 3984 95 1033 -2 2859 -2178 -1304 -596 -3489 -3165 -1292 2235 1771 1634 647 2508 -1453 1758 812 611 -735 1930 -1068 529 284 -2198 1037 -609 -1889 -2575 602 161 -594 124 473 -2616 -148 -949 3300 -2840 57 -307 -67 -621 -409 -2450 -860 -1649 2177 1090 490 -2897 -875 -303 -938 -1797 1570 647 2039 2133 -2489 118 -764 1245 -3190 4943 -274 -42 1863 -1083 -1087 4059 1631 1660 1587 -1371 769 159 383 -82 1656 -234 2171 -1090 2210 -1524 1837 -1354 605 -2768 -270 -2939 -1192 407 2076 717 1018 -333 1941 1337 -573 1750 -1108 -4043 -4564 SO 20190925T112257.0Z 7207.474271 313 1 32.01 2 88.19 92.91 45.02 110.34 0.00 1 0.00 1 0 22 1.403e-02 1.353e-02 2.306e-03 2.286e-03 1.495401e+04 1.534133e+02 9.727280e+02 -6.000000e+00 7.299150e+02 283.63 -2.00 20.00 -2.00 505.50 0.00e+00 5.237574e-03 6.214779e-05 2.744282e-04 -6.000000e+00 3.855620e-04 283.63 -2.00 20.00 -2.00 501.11 0.00e+00 1.247693e+00 4.271092e-02 1.122418e-01 -6.000000e+00 2.708273e-01 227.86 -2.00 3.57 -2.00 502.62 0.00e+00 16.533 0.088 489.00 513.00 1 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