File name: Pandora103s1_Downsview_20191029_L2Fit_fwvt1c10d20181123p1-8.txt File generation date: 20241101T060445.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c10p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20190801.txt Level 1 file used: Pandora103s1_Downsview_20191029_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20191029 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 1620 1769 Nominal wavelengths inside fitting window [nm]: 492.0103 492.1315 492.2527 492.3739 492.4950 492.6162 492.7373 492.8584 492.9795 493.1006 493.2216 493.3426 493.4637 493.5847 493.7057 493.8266 493.9476 494.0685 494.1894 494.3103 494.4312 494.5521 494.6730 494.7938 494.9146 495.0354 495.1562 495.2770 495.3977 495.5185 495.6392 495.7599 495.8806 496.0012 496.1219 496.2425 496.3631 496.4837 496.6043 496.7249 496.8454 496.9660 497.0865 497.2070 497.3275 497.4480 497.5684 497.6888 497.8093 497.9297 498.0500 498.1704 498.2907 498.4111 498.5314 498.6517 498.7720 498.8922 499.0125 499.1327 499.2529 499.3731 499.4933 499.6135 499.7336 499.8537 499.9739 500.0940 500.2140 500.3341 500.4541 500.5742 500.6942 500.8142 500.9341 501.0541 501.1740 501.2940 501.4139 501.5338 501.6536 501.7735 501.8933 502.0132 502.1330 502.2528 502.3725 502.4923 502.6120 502.7318 502.8515 502.9711 503.0908 503.2105 503.3301 503.4497 503.5693 503.6889 503.8085 503.9280 504.0476 504.1671 504.2866 504.4061 504.5255 504.6450 504.7644 504.8838 505.0032 505.1226 505.2420 505.3613 505.4807 505.6000 505.7193 505.8385 505.9578 506.0770 506.1963 506.3155 506.4347 506.5539 506.6730 506.7922 506.9113 507.0304 507.1495 507.2685 507.3876 507.5066 507.6257 507.7447 507.8637 507.9826 508.1016 508.2205 508.3394 508.4583 508.5772 508.6961 508.8149 508.9338 509.0526 509.1714 509.2902 509.4089 509.5277 509.6464 509.7651 509.8838 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20191029T115609.0Z 7241.497326 473 1 32.01 2 89.74 109.05 105.30 97.43 0.00 1 0.00 1 0 22 7.160e-02 6.966e-02 6.760e-02 6.665e-02 8.171563e+03 4.242778e+03 4.538722e+02 -6.000000e+00 3.662328e+03 279.33 -2.00 20.00 -2.00 505.27 0.00e+00 -4.596571e-04 1.757566e-03 4.294603e-05 -6.000000e+00 1.946657e-03 279.33 -2.00 20.00 -2.00 500.20 0.00e+00 9.368047e-02 1.291111e+00 7.393071e-02 -6.000000e+00 1.376715e+00 224.13 -2.00 3.57 -2.00 501.83 0.00e+00 20.200 0.161 489.00 513.00 1 9.8407e+00 9.8047e-02 3.6638e-02 -6.0000e+00 1.0502e-01 1.4241e-01 2.5878e-02 2.5061e-03 -6.0000e+00 2.7951e-02 6.1195e-06 -2.4541e-03 4.8934e-03 5.7151e-05 -6.0000e+00 5.5850e-03 -2.3976e-02 2.4276e-04 12 8 8 10 0 0 0.31 15.00 2.44 -0.02398 -0.04100 8 1 1 4 0 4000.000 21.88 15.00 18.70 -9536 -9530 -6894 55 -1006 4843 -1554 -47 9222 2646 6403 -3328 -7395 -1350 516 -8736 -4504 1725 2763 -10452 900 11193 2674 -1531 13378 10142 2937 7019 4235 -11087 2753 -1714 1167 -3604 -1251 7519 2845 811 1489 5060 -7115 -603 -5155 13751 3936 7536 -6213 5688 -10905 5976 15351 -553 -9373 3756 2885 6180 -708 -7898 2126 -3327 5895 760 -2449 -11293 2292 2197 5355 -1301 4067 -5048 13016 -4310 5148 -10010 11301 -3856 -4490 9074 4518 -510 -4400 63 16340 11195 -7260 6412 1502 1791 -13861 905 -3499 260 10121 -3464 -4462 13673 7067 -498 -4900 -6095 1743 -3532 4814 -3705 11310 -4940 -3880 -11217 1074 7360 3046 2363 -1871 -5106 9534 11304 7454 7422 17807 1228 2524 -637 -24 -16086 -2073 -3143 -7462 6671 -4803 -10842 -1170 9828 6465 -2559 -1366 13056 -5886 5563 -7596 21358 13205 -560 -5643 4964 -9861 -48 -584 4162 -3865 -9647 -9716 -9789 -7112 55 -1054 4879 -1704 -52 9289 2812 6434 -3631 -8280 -1400 519 -9606 -4796 1770 2907 -12783 985 11080 2871 -1712 13025 10221 3157 7217 4401 -12808 2683 -1740 1167 -3918 -1391 7799 3052 873 1571 5084 -8008 -640 -5773 12957 4129 7672 -7202 5797 -12847 5851 13265 -540 -9743 3430 2725 5888 -742 -8993 2193 -3590 5790 789 -2642 -13278 2349 2219 5140 -1311 3854 -5154 10973 -4297 4732 -10834 10135 -4003 -4580 7905 4063 -478 -4285 60 13252 9599 -7561 5934 1461 1732 -15510 876 -3543 257 9269 -3639 -4634 11541 6167 -453 -4543 -5591 1464 -3162 4125 -3654 10110 -5230 -4023 -12234 1019 6581 2891 2291 -1906 -5383 8717 10157 7024 7097 15391 1225 2431 -617 -23 -17920 -2038 -3120 -7721 6003 -4794 -11508 -1129 8324 5533 -2368 -1243 10469 -5847 5043 -7908 17027 11490 -559 -5948 4741 -10885 -48 -576 3806 -3718 -9738 SO 20191029T120023.0Z 7241.500266 477 1 32.01 2 89.02 109.79 104.58 98.12 0.00 1 0.00 1 0 15 4.828e-02 4.729e-02 4.572e-02 4.519e-02 2.794070e+03 2.646188e+03 2.478735e+02 -6.000000e+00 2.468769e+03 279.33 -2.00 20.00 -2.00 505.25 0.00e+00 6.556872e-04 1.200627e-03 7.236922e-05 -6.000000e+00 1.312581e-03 279.33 -2.00 20.00 -2.00 500.10 0.00e+00 1.247030e+00 8.831521e-01 1.473961e-02 -6.000000e+00 9.286623e-01 224.13 -2.00 3.57 -2.00 501.74 0.00e+00 18.775 0.129 489.00 513.00 1 9.5504e+00 6.7291e-02 3.1951e-02 -6.0000e+00 7.0828e-02 1.2941e-01 1.7851e-02 1.7863e-03 -6.0000e+00 1.8871e-02 9.1390e-06 -2.7206e-03 3.4433e-03 3.3449e-05 -6.0000e+00 3.7662e-03 3.7563e-02 -1.8102e-04 12 8 8 10 0 0 -5.56 15.01 5.56 0.03756 0.01869 8 1 1 4 0 4000.000 21.88 15.01 18.71 -7560 -6238 5549 4784 393 581 6502 1375 -3486 2410 1671 2145 -8797 1078 -1845 -4699 -8142 462 -277 -1637 1383 8127 3951 -1067 63 721 -3198 3754 -896 5546 -2487 3977 -4938 6736 4170 -4381 2529 -2711 3642 -2101 2657 -5877 2438 -3532 4759 -4940 1260 4790 5755 6934 -4166 190 7499 -632 -4085 919 -4027 519 4312 2544 -936 1097 -1371 3800 4798 756 -11812 5005 -7482 -671 -2958 -6473 3956 -6179 9790 1518 3850 -5945 7414 3628 14652 -7171 744 971 6267 -5968 10800 -3917 -1979 -8839 -2616 207 -4112 3773 1048 2100 4263 -283 4958 6994 -6863 4786 -4366 1842 -3879 3769 -1379 3544 -3860 2638 -974 5471 2486 406 -5572 -7205 5188 5293 4213 -2531 6216 -4175 6310 -1303 71 8530 3304 -8851 6116 -3545 -5445 -2250 -4705 -2342 9284 -4839 390 2130 3392 -5420 -210 2474 5407 1990 -5631 1449 -4598 1613 -4221 6516 -7651 -6283 5136 4657 411 617 6675 1507 -4020 2595 1777 2241 -10083 1101 -1917 -5012 -9057 483 -302 -1849 1515 8330 4211 -1194 70 801 -3675 4012 -985 5487 -2565 3837 -5264 6647 4416 -5123 2733 -3032 3776 -2271 2730 -6591 2548 -3956 4980 -5711 1366 4953 5798 6760 -4375 185 6649 -604 -4138 923 -4373 546 4365 2599 -984 1137 -1465 3859 4797 774 -13380 4732 -7911 -655 -2897 -6552 3651 -6390 8822 1483 3592 -5940 6419 3240 11752 -7185 695 908 5640 -6126 9434 -3937 -1944 -9279 -2592 202 -4271 3669 1034 2007 3902 -264 4267 5750 -6358 3993 -4103 1712 -3965 3590 -1360 3259 -3742 2402 -936 5027 2384 401 -5855 -7704 4950 5084 4069 -2564 5667 -4131 5564 -1247 68 7494 3052 -9178 5445 -3479 -5444 -2135 -4470 -2145 7520 -4541 358 1969 3135 -5521 -205 2350 5015 1921 -5874 1406 -4649 1487 -3993 5497 SO 20191029T120431.0Z 7241.503137 481 1 32.01 2 88.32 110.51 103.88 98.79 0.00 1 0.00 1 0 22 2.911e-02 2.894e-02 3.031e-02 3.009e-02 1.603161e+03 1.674982e+03 1.267572e+02 -6.000000e+00 1.488880e+03 279.33 -2.00 20.00 -2.00 505.24 0.00e+00 2.328110e-03 8.017052e-04 1.345320e-04 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