File name: Pandora103s1_Downsview_20191030_L2Fit_fwvt1c10d20181123p1-8.txt File generation date: 20241101T060457.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c10p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20190801.txt Level 1 file used: Pandora103s1_Downsview_20191030_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20191030 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 1620 1769 Nominal wavelengths inside fitting window [nm]: 492.0103 492.1315 492.2527 492.3739 492.4950 492.6162 492.7373 492.8584 492.9795 493.1006 493.2216 493.3426 493.4637 493.5847 493.7057 493.8266 493.9476 494.0685 494.1894 494.3103 494.4312 494.5521 494.6730 494.7938 494.9146 495.0354 495.1562 495.2770 495.3977 495.5185 495.6392 495.7599 495.8806 496.0012 496.1219 496.2425 496.3631 496.4837 496.6043 496.7249 496.8454 496.9660 497.0865 497.2070 497.3275 497.4480 497.5684 497.6888 497.8093 497.9297 498.0500 498.1704 498.2907 498.4111 498.5314 498.6517 498.7720 498.8922 499.0125 499.1327 499.2529 499.3731 499.4933 499.6135 499.7336 499.8537 499.9739 500.0940 500.2140 500.3341 500.4541 500.5742 500.6942 500.8142 500.9341 501.0541 501.1740 501.2940 501.4139 501.5338 501.6536 501.7735 501.8933 502.0132 502.1330 502.2528 502.3725 502.4923 502.6120 502.7318 502.8515 502.9711 503.0908 503.2105 503.3301 503.4497 503.5693 503.6889 503.8085 503.9280 504.0476 504.1671 504.2866 504.4061 504.5255 504.6450 504.7644 504.8838 505.0032 505.1226 505.2420 505.3613 505.4807 505.6000 505.7193 505.8385 505.9578 506.0770 506.1963 506.3155 506.4347 506.5539 506.6730 506.7922 506.9113 507.0304 507.1495 507.2685 507.3876 507.5066 507.6257 507.7447 507.8637 507.9826 508.1016 508.2205 508.3394 508.4583 508.5772 508.6961 508.8149 508.9338 509.0526 509.1714 509.2902 509.4089 509.5277 509.6464 509.7651 509.8838 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20191030T115725.0Z 7242.498206 474 1 32.01 2 89.75 109.52 117.04 91.74 0.00 1 0.00 1 0 56 3.022e-01 2.201e-01 2.626e-01 2.230e-01 3.483805e+03 1.436547e+04 1.521400e+03 -6.000000e+00 1.545299e+04 279.20 -2.00 20.00 -2.00 505.42 0.00e+00 1.534620e-02 5.971644e-03 7.706184e-04 -6.000000e+00 8.247592e-03 279.20 -2.00 20.00 -2.00 500.03 0.00e+00 1.106439e+01 4.546976e+00 2.251792e-01 -6.000000e+00 5.879320e+00 224.04 -2.00 3.57 -2.00 501.63 0.00e+00 20.217 0.161 489.00 513.00 1 1.0017e+01 3.4708e-01 4.3282e-02 -6.0000e+00 4.4706e-01 -6.5453e-02 8.9250e-02 2.9417e-03 -6.0000e+00 1.2131e-01 1.6994e-06 -5.0070e-03 1.5710e-02 2.3419e-04 -6.0000e+00 2.3598e-02 -6.4733e-02 -3.4649e-04 12 8 8 10 0 0 -3.33 15.00 22.19 -0.06473 -0.09946 8 1 1 4 0 4000.000 21.88 15.00 18.75 900000 8194 -15533 -19820 -22189 46834 52541 5232 -641 1841 26556 6557 3364 -26641 9483 7328 26576 22201 6109 24658 41722 1772 4058 14861 -14189 16755 -15677 30127 -39452 16072 -9704 85720 9373 28874 -6292 -13081 14980 4493 27528 45819 -7434 -8576 -7491 -14788 78151 43044 28553 -15992 22236 -18110 5902 -14906 27647 14792 -11672 -5615 21387 -17504 15130 8385 -19971 -7054 17776 19431 -20052 13059 3303 60400 -24417 13611 13020 7151 30086 10367 14577 66311 14445 11214 -8911 2719 -32414 102191 -11446 -319 9088 -5742 -9276 40878 -7273 5779 72892 -14108 9905 22143 60490 13311 31528 36918 19126 -22855 40928 -28188 56517 6863 23254 -19236 -16858 -10319 69000 26921 -25053 68814 463 -18682 -18420 33713 -21227 12119 12585 3442 -3380 22037 -17391 4193 66370 -7055 74242 4609 -383 30112 -2332 -38446 18006 -3520 25602 15572 47724 -6873 61659 60000 79661 357 -21024 12643 8342 38 6561 -10893 -8532 -6707 900000 7188 -17210 -23674 -28431 32248 35035 5594 -736 2068 23276 6790 3522 -36647 9078 7081 21269 18622 6067 21087 30965 1923 4285 14179 -17980 16049 -20824 25964 -66222 15646 -11609 39651 8873 22933 -7213 -16803 15061 4944 23940 33126 -8870 -10375 -9127 -19731 43918 34447 26631 -22929 21928 -25918 6591 -19758 23643 14022 -14150 -6556 20038 -24584 15805 9343 -29022 -9011 17978 19471 -29335 13808 3769 39054 -34733 13250 12524 7104 23714 9862 13378 37609 13409 10476 -9790 2623 -43323 37630 -12385 -310 7990 -5803 -9714 26334 -7308 5043 33238 -14678 8282 16929 32942 11377 22290 24343 14566 -25204 23800 -30691 27130 5324 15921 -20355 -17466 -9878 30522 17525 -27030 31372 418 -20819 -21007 23791 -25556 10728 11213 3349 -3463 17453 -19823 3858 34252 -7485 36752 4464 -392 23094 -2459 -57833 15574 -3661 19939 13239 30036 -7471 35805 35872 40032 386 -27882 12184 8451 42 6821 -13202 -9817 -7355 SO 20191030T120118.0Z 7242.500903 478 1 32.01 2 89.09 110.19 116.38 92.39 0.00 1 0.00 1 0 22 6.325e-02 6.146e-02 6.009e-02 5.937e-02 1.782818e+04 4.107899e+03 1.157942e+03 -6.000000e+00 3.233604e+03 279.20 -2.00 20.00 -2.00 505.37 0.00e+00 2.827961e-03 1.583190e-03 1.912987e-04 -6.000000e+00 1.719777e-03 279.20 -2.00 20.00 -2.00 500.57 0.00e+00 -2.766461e-01 1.133041e+00 1.079783e-01 -6.000000e+00 1.217973e+00 224.04 -2.00 3.57 -2.00 502.13 0.00e+00 18.944 0.132 489.00 513.00 1 9.8596e+00 8.6097e-02 3.3944e-02 -6.0000e+00 9.2868e-02 8.0192e-02 2.2570e-02 3.2227e-03 -6.0000e+00 2.4781e-02 6.9005e-06 -5.8638e-03 4.1434e-03 1.3245e-04 -6.0000e+00 4.9320e-03 -1.0497e-03 -5.0983e-05 12 8 8 10 0 0 -10.71 14.99 3.17 -0.00105 -0.04172 8 1 1 4 0 4000.000 21.88 14.99 18.76 3947 562 955 -187 8607 -10457 2483 -764 -4143 -4674 2084 -2394 -933 5475 2235 5303 -817 -5869 -3220 -3919 -7230 16805 -4414 3829 7931 3465 4382 -917 1112 1609 6773 -2774 -1074 3367 -3849 -4210 11178 -712 4758 -1798 6042 -8116 -4605 -4178 11875 3939 -5012 5015 89 -3122 -7255 -4193 1470 -3731 -2392 -3444 -8907 11975 -603 21106 -5600 -232 -1817 7293 -607 10341 -4233 -8613 -5985 5781 1944 5504 -6035 2385 245 13946 9828 5509 -3529 -4314 -3778 -3058 11122 -2887 5147 -5672 -6426 1778 -3325 -3281 7777 -4063 3677 6918 3301 3446 9694 -8047 -8035 4557 -3305 1653 -4525 6616 -3886 14119 -8965 4494 2087 -4888 -3808 3498 1871 -9259 -1100 -1176 4565 7547 -307 3533 -14825 1618 8309 -599 2149 478 9403 -6950 1678 2745 9288 -8258 6737 407 466 -4756 20208 -5568 2785 -1557 6986 -3418 7097 6368 -7751 -8709 2119 -1926 -2954 3199 3336 491 852 -175 7714 -11515 2464 -798 -4506 -5081 2080 -2457 -933 5056 2101 4815 -791 -6071 -3350 -4228 -8091 14864 -4798 3842 7700 3546 4440 -976 1150 1599 6128 -2717 -1045 3226 -4153 -4697 10698 -753 4714 -1875 5805 -8994 -4994 -4575 11305 4094 -5698 5132 94 -3353 -7888 -4278 1386 -3667 -2358 -3574 -10106 11321 -647 18252 -6243 -246 -1981 7301 -655 9929 -4595 -9578 -6421 5477 1879 5105 -6307 2328 249 12515 9028 5132 -3524 -4303 -3725 -3007 9612 -2873 4797 -5978 -6864 1745 -3391 -3307 7031 -4161 3566 6588 3196 3194 8088 -7659 -7452 3675 -2823 1347 -4041 5630 -3917 12395 -9901 4301 2005 -4999 -3924 3425 1876 -10351 -1134 -1209 4482 7379 -330 3634 -17831 1610 7534 -588 2086 475 8590 -7468 1649 2665 8503 -8808 6043 385 439 -4757 16325 -5910 2750 -1626 6829 -3728 7031 6373 -8888 -10036 2174 -2011 -3034 3054 SO 20191030T120508.0Z 7242.503565 482 1 32.01 2 88.44 110.86 115.73 93.02 0.00 1 0.00 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