File name: Pandora103s1_Downsview_20191120_L2Fit_fwvt1c10d20181123p1-8.txt File generation date: 20241101T063040.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c10p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20190801.txt Level 1 file used: Pandora103s1_Downsview_20191120_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20191120 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 1620 1769 Nominal wavelengths inside fitting window [nm]: 492.0103 492.1315 492.2527 492.3739 492.4950 492.6162 492.7373 492.8584 492.9795 493.1006 493.2216 493.3426 493.4637 493.5847 493.7057 493.8266 493.9476 494.0685 494.1894 494.3103 494.4312 494.5521 494.6730 494.7938 494.9146 495.0354 495.1562 495.2770 495.3977 495.5185 495.6392 495.7599 495.8806 496.0012 496.1219 496.2425 496.3631 496.4837 496.6043 496.7249 496.8454 496.9660 497.0865 497.2070 497.3275 497.4480 497.5684 497.6888 497.8093 497.9297 498.0500 498.1704 498.2907 498.4111 498.5314 498.6517 498.7720 498.8922 499.0125 499.1327 499.2529 499.3731 499.4933 499.6135 499.7336 499.8537 499.9739 500.0940 500.2140 500.3341 500.4541 500.5742 500.6942 500.8142 500.9341 501.0541 501.1740 501.2940 501.4139 501.5338 501.6536 501.7735 501.8933 502.0132 502.1330 502.2528 502.3725 502.4923 502.6120 502.7318 502.8515 502.9711 503.0908 503.2105 503.3301 503.4497 503.5693 503.6889 503.8085 503.9280 504.0476 504.1671 504.2866 504.4061 504.5255 504.6450 504.7644 504.8838 505.0032 505.1226 505.2420 505.3613 505.4807 505.6000 505.7193 505.8385 505.9578 506.0770 506.1963 506.3155 506.4347 506.5539 506.6730 506.7922 506.9113 507.0304 507.1495 507.2685 507.3876 507.5066 507.6257 507.7447 507.8637 507.9826 508.1016 508.2205 508.3394 508.4583 508.5772 508.6961 508.8149 508.9338 509.0526 509.1714 509.2902 509.4089 509.5277 509.6464 509.7651 509.8838 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20191120T122513.0Z 7263.517512 293 1 32.01 2 89.75 118.08 31.53 192.28 0.00 1 0.00 1 0 15 1.516e-01 1.344e-01 1.313e-01 1.244e-01 1.040214e+04 8.348672e+03 8.358335e+01 -6.000000e+00 7.670821e+03 276.58 -2.00 20.00 -2.00 505.14 0.00e+00 2.546766e-03 3.289806e-03 1.939878e-04 -6.000000e+00 4.095081e-03 276.58 -2.00 20.00 -2.00 499.80 0.00e+00 7.799159e-01 2.497908e+00 1.973440e-01 -6.000000e+00 2.913823e+00 222.50 -2.00 3.57 -2.00 501.44 0.00e+00 20.305 0.163 489.00 513.00 1 1.0377e+01 1.8936e-01 3.9550e-02 -6.0000e+00 2.2211e-01 1.7441e-01 5.0522e-02 3.5969e-03 -6.0000e+00 5.9129e-02 3.1458e-06 -1.0517e-02 9.1355e-03 4.1639e-05 -6.0000e+00 1.1825e-02 -4.9164e-02 4.0249e-04 12 8 8 10 0 0 12.03 15.00 7.77 -0.04916 -0.12212 8 1 1 4 0 4000.000 21.69 15.00 18.48 15219 -10564 7592 -7442 6721 -6129 19156 -13852 27939 9885 -68 -4968 -5798 -4948 -3657 -590 -6518 11843 -319 -8517 -4839 6433 -5517 30032 988 23845 -2306 42767 -2607 12800 -13414 -7112 5668 33615 -8365 3841 -4105 17952 -251 -9950 -7260 -20093 18249 -11875 11005 770 -5480 -7558 17829 -4584 17789 -9248 4914 2919 -2430 1173 3878 7763 4373 2063 7748 -1927 -17205 21247 13000 9324 7316 11355 -20589 28210 -17521 43829 -18407 16528 -19043 2685 -6857 -2730 4968 12600 20445 -8524 -961 4620 22067 10386 7624 -2059 -16489 -7553 10784 -19195 11630 -7589 -599 -16519 4535 -6233 11392 4569 6849 -13889 19668 4523 15845 -21302 3175 14467 -8073 7578 5734 -8773 9370 8444 13717 1860 16824 42610 -532 12745 5949 16533 -8345 3544 15192 15576 -20899 -5740 9639 2388 11879 2129 1798 -31839 21366 -289 40543 -18961 49459 -799 -7713 -16030 -13473 1303 -10164 352 29669 11301 29220 17811 13138 -11606 7150 -8422 6892 -7261 18130 -18382 24960 10456 -77 -5843 -6785 -5638 -4050 -630 -7379 11395 -355 -10573 -5830 6927 -6655 25686 1121 21909 -2722 32558 -3045 12475 -16069 -7868 5579 25882 -10095 4257 -4899 17024 -280 -12003 -8458 -26551 16828 -14809 11156 870 -6589 -9189 16710 -5237 15929 -10370 4679 2798 -2477 1200 4002 7873 4601 2205 7778 -2126 -22164 18937 12511 9190 7205 10537 -25669 21751 -20571 28255 -21677 14057 -23199 2678 -7382 -2743 4543 10602 15853 -8757 -925 4227 17208 9195 6966 -2056 -18746 -7810 9331 -22304 10226 -8160 -596 -18578 4022 -5925 8881 3717 5332 -13147 13798 3850 12803 -25322 2975 11968 -8119 6499 5078 -9112 8265 7556 11681 1772 13952 28057 -535 11172 5447 13336 -8345 3144 12204 12538 -23880 -5674 8165 2162 9860 1911 1575 -38034 15194 -254 24654 -20909 28610 -756 -7896 -17856 -14686 1237 -10784 336 21161 9374 19797 13217 SO 20191120T122932.0Z 7263.520509 297 1 32.01 2 89.07 118.83 31.72 194.21 0.00 1 0.00 1 0 15 7.665e-02 7.339e-02 7.279e-02 7.126e-02 2.796339e+03 4.106845e+03 2.992972e+01 -6.000000e+00 3.876929e+03 276.58 -2.00 20.00 -2.00 505.21 0.00e+00 1.190950e-03 1.882774e-03 4.298522e-05 -6.000000e+00 2.070065e-03 276.58 -2.00 20.00 -2.00 499.93 0.00e+00 2.397329e+00 1.389975e+00 7.870855e-02 -6.000000e+00 1.474294e+00 222.50 -2.00 3.57 -2.00 501.59 0.00e+00 18.963 0.133 489.00 513.00 1 9.9106e+00 1.0639e-01 3.2932e-02 -6.0000e+00 1.1234e-01 1.2302e-01 2.7846e-02 2.1619e-03 -6.0000e+00 2.9966e-02 5.6428e-06 6.7516e-03 5.3980e-03 9.5010e-06 -6.0000e+00 5.9772e-03 2.8469e-02 -1.7497e-04 12 8 8 10 0 0 -4.93 15.00 6.70 0.02847 0.07530 8 1 1 4 0 4000.000 21.69 15.00 18.49 -2775 7251 -7328 -4345 -4726 -3800 8673 2245 1399 -6188 1217 -6395 587 -2568 17690 -2325 2995 1614 1737 -6639 13419 -6042 -483 -2034 -7932 -6570 8941 -4599 -829 321 646 7363 696 2022 1446 14934 -881 9336 -1698 4282 263 13572 -3120 -7015 -11133 -8552 4518 3822 2848 10342 17044 1746 9823 -7688 7288 -9529 15334 149 16189 -5009 -2724 5581 13601 213 -3556 -2544 3041 1269 -3705 9867 -4353 784 4783 1052 -4047 -2516 -18301 -4899 1916 1810 -10519 5354 -7114 -4769 336 10160 -10112 1946 5367 6467 -3204 -1625 -2008 4172 10353 -4672 -2516 -4610 18990 -11805 -7304 -5820 12575 4257 6472 -10105 572 -6160 7630 9806 5577 2552 -614 -9977 19949 8806 2532 584 231 11824 1044 1896 -7160 14119 4949 -57 -7333 7876 -9663 14299 -9192 8580 9222 -1503 -1038 -2991 4942 -3319 -186 9938 11322 284 -13395 -11011 6719 -9079 3104 -7200 11660 -6112 -2733 6606 -7991 -4791 -5347 -4342 8970 2494 1563 -7312 1314 -7354 619 -2751 15456 -2474 3070 1727 1917 -8019 13286 -7232 -547 -2345 -9759 -7967 9276 -5402 -911 333 655 7027 725 2177 1619 14660 -992 9378 -1870 4404 282 12864 -3517 -8315 -13879 -10402 4799 4023 2972 9761 14535 1678 8597 -8052 6834 -10915 14089 159 14728 -5549 -2949 5617 12696 225 -3864 -2683 2976 1247 -3776 8654 -4326 745 4419 1026 -4191 -2532 -20869 -4799 1742 1639 -10783 4752 -7142 -4710 320 8858 -10714 1825 4850 5786 -3165 -1608 -2032 3975 9118 -4656 -2397 -4355 13889 -11361 -6692 -5353 10068 3879 5899 -10728 537 -6037 6468 8237 4980 2385 -599 -10739 16093 7944 2448 577 227 10147 976 1726 -7099 11542 4446 -54 -7412 6829 -9913 11696 -9348 7163 7517 -1344 -921 -2767 4360 -3225 -178 8680 9783 274 -14840 -11989 6164 -9621 2849 -7058 9313 -5811 SO 20191120T123340.0Z 7263.523380 301 1 32.01 2 88.42 119.56 31.93 196.04 0.00 1 0.00 1 0 15 5.140e-02 5.076e-02 5.155e-02 5.070e-02 4.374432e+03 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