File name: Pandora103s1_Downsview_20191126_L2Fit_fwvt1c10d20181123p1-8.txt File generation date: 20241101T063018.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c10p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20190801.txt Level 1 file used: Pandora103s1_Downsview_20191126_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20191126 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 1620 1769 Nominal wavelengths inside fitting window [nm]: 492.0103 492.1315 492.2527 492.3739 492.4950 492.6162 492.7373 492.8584 492.9795 493.1006 493.2216 493.3426 493.4637 493.5847 493.7057 493.8266 493.9476 494.0685 494.1894 494.3103 494.4312 494.5521 494.6730 494.7938 494.9146 495.0354 495.1562 495.2770 495.3977 495.5185 495.6392 495.7599 495.8806 496.0012 496.1219 496.2425 496.3631 496.4837 496.6043 496.7249 496.8454 496.9660 497.0865 497.2070 497.3275 497.4480 497.5684 497.6888 497.8093 497.9297 498.0500 498.1704 498.2907 498.4111 498.5314 498.6517 498.7720 498.8922 499.0125 499.1327 499.2529 499.3731 499.4933 499.6135 499.7336 499.8537 499.9739 500.0940 500.2140 500.3341 500.4541 500.5742 500.6942 500.8142 500.9341 501.0541 501.1740 501.2940 501.4139 501.5338 501.6536 501.7735 501.8933 502.0132 502.1330 502.2528 502.3725 502.4923 502.6120 502.7318 502.8515 502.9711 503.0908 503.2105 503.3301 503.4497 503.5693 503.6889 503.8085 503.9280 504.0476 504.1671 504.2866 504.4061 504.5255 504.6450 504.7644 504.8838 505.0032 505.1226 505.2420 505.3613 505.4807 505.6000 505.7193 505.8385 505.9578 506.0770 506.1963 506.3155 506.4347 506.5539 506.6730 506.7922 506.9113 507.0304 507.1495 507.2685 507.3876 507.5066 507.6257 507.7447 507.8637 507.9826 508.1016 508.2205 508.3394 508.4583 508.5772 508.6961 508.8149 508.9338 509.0526 509.1714 509.2902 509.4089 509.5277 509.6464 509.7651 509.8838 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20191126T123237.0Z 7269.522651 512 1 32.01 2 89.77 119.92 87.75 118.30 0.00 1 0.00 1 0 29 7.594e-02 7.712e-02 7.772e-02 7.614e-02 1.049169e+04 5.127672e+03 4.300763e+02 -6.000000e+00 3.831377e+03 275.90 -2.00 20.00 -2.00 505.26 0.00e+00 3.924402e-03 2.006590e-03 2.474615e-04 -6.000000e+00 2.046388e-03 275.90 -2.00 20.00 -2.00 500.09 0.00e+00 6.161402e-01 1.508712e+00 1.231597e-01 -6.000000e+00 1.457164e+00 222.42 -2.00 3.57 -2.00 501.71 0.00e+00 20.346 0.164 489.00 513.00 1 9.8678e+00 1.1484e-01 3.8240e-02 -6.0000e+00 1.1108e-01 1.5211e-01 3.0045e-02 2.9963e-03 -6.0000e+00 2.9523e-02 5.2574e-06 -4.0998e-03 5.5272e-03 8.9601e-05 -6.0000e+00 5.9218e-03 -7.5794e-03 2.6707e-04 12 8 8 10 0 0 18.74 14.99 4.18 -0.00758 -0.03602 8 1 1 4 0 4000.000 21.69 14.99 18.52 -11912 8270 -19825 8565 -7587 937 -6257 8451 4337 2300 8338 7829 2581 7855 -2090 6529 10631 10621 2145 9618 3380 -1419 -6819 -10725 3954 -7539 16496 549 -12060 -2952 -1804 -9738 -12783 347 6191 5442 -7577 9587 16813 895 7168 9632 -11403 -387 3542 1327 -1678 6470 -9379 9276 -8738 6854 -11591 8909 -479 1407 -500 2539 -4346 -7032 4515 -6089 4568 10571 543 2945 -515 -7032 2213 3459 8935 5711 7522 2101 -312 2594 7881 -1435 10765 -9192 14299 -8418 -4199 10096 -10985 9483 5112 -7040 12205 5015 -4906 2147 5968 -3932 -16330 -2383 -512 6486 14309 4185 6659 1297 -466 5111 5901 2760 -3911 3577 -6831 2910 2590 3814 7437 4368 -179 -5138 -7483 -3072 8353 -11754 -6814 4118 9402 -23248 465 -3761 6052 6533 -11959 7367 8936 7213 -1134 7747 -3265 11867 -1864 14891 -1445 -1851 -6328 -1669 9882 -2104 -3389 -3536 767 1071 936 -796 -12714 7335 -23852 8170 -8712 1008 -7374 8752 4677 2496 8347 7764 2652 7529 -2180 6251 9861 10072 2281 9688 3603 -1583 -8004 -13092 4223 -9050 15617 604 -14707 -3151 -1839 -10702 -14680 364 6424 5761 -8978 9468 15281 938 7065 9343 -13749 -425 3800 1465 -1900 6687 -11126 8986 -9747 6368 -12634 7964 -482 1448 -539 2689 -4913 -8100 4633 -6976 4750 10371 583 3038 -538 -7698 2193 3334 8028 5291 6910 2063 -319 2567 7222 -1402 9229 -9488 11729 -8673 -4171 8762 -11848 8474 4758 -7313 10417 4564 -4928 2042 5595 -4078 -18671 -2301 -469 5377 10732 3379 5171 1071 -406 4465 5345 2602 -3890 3243 -6744 2631 2401 3553 6753 4104 -176 -5302 -8001 -3196 7781 -13071 -7052 3736 7978 -27292 439 -3703 5429 5823 -12668 6496 7736 6186 -1032 6414 -2994 9537 -1761 12151 -1394 -1817 -6537 -1652 8782 -2105 -3429 -3560 727 981 836 -719 SO 20191126T123629.0Z 7269.525336 516 1 32.01 2 89.17 120.59 87.16 118.97 0.00 1 0.00 1 0 22 4.129e-02 4.061e-02 4.400e-02 4.352e-02 1.636930e+03 2.435138e+03 2.213543e+02 -6.000000e+00 2.083474e+03 275.90 -2.00 20.00 -2.00 505.25 0.00e+00 5.673280e-03 1.149640e-03 2.541306e-04 -6.000000e+00 1.113535e-03 275.90 -2.00 20.00 -2.00 500.06 0.00e+00 1.658567e+00 8.532928e-01 3.504840e-02 -6.000000e+00 7.946668e-01 222.42 -2.00 3.57 -2.00 501.70 0.00e+00 19.207 0.138 489.00 513.00 1 9.3682e+00 6.5091e-02 3.3736e-02 -6.0000e+00 6.0541e-02 1.3566e-01 1.7185e-02 1.8559e-03 -6.0000e+00 1.6151e-02 9.3752e-06 9.5910e-03 3.3064e-03 6.8237e-05 -6.0000e+00 3.2199e-03 7.9805e-03 -5.7558e-05 12 8 8 10 0 0 -11.02 15.00 4.50 0.00798 0.07451 8 1 1 4 0 4000.000 21.79 15.00 18.53 -11764 806 869 -716 -214 -756 1623 3759 -1734 -3290 -350 228 -697 -5215 -835 -1850 -1696 2681 10180 368 807 -1805 6272 -1191 -890 40 2899 -1047 3407 -3048 -1859 -4056 281 -904 1848 -359 -315 1552 1799 3426 -5079 -3106 -5902 5374 -4654 4481 1652 6682 -523 5938 -3481 2895 -6018 2415 2067 -1602 -7575 -1186 1962 3618 -416 3885 9179 -2795 6547 1467 2541 405 1438 -4340 6197 -1452 2283 -4052 2730 655 -1318 -89 5670 -884 -6775 16 4026 3911 -5841 6227 977 311 -3645 3615 290 4729 -83 3225 -3631 3725 -3382 3740 3995 8488 -3056 217 2777 -1043 1729 -43 2987 -4246 9860 -2837 724 -4149 1628 -3920 -2169 987 4721 1219 -4380 -1097 -6196 6378 -1102 -1760 3901 -5429 -4945 372 1534 -9837 -6311 -1156 -3287 4155 -2042 -702 1767 4841 -1818 6853 7020 -3324 -964 946 5337 3931 -2339 -12491 10333 -406 -12523 777 872 -759 -230 -834 1783 4066 -1965 -3703 -376 240 -726 -5587 -851 -1911 -1773 2764 10023 400 869 -1994 6402 -1317 -990 44 3096 -1151 3464 -3152 -1868 -4194 286 -976 2000 -395 -341 1627 1857 3460 -5608 -3405 -6754 5597 -5406 4768 1793 6805 -561 5818 -3610 2752 -6171 2317 2066 -1720 -8791 -1297 2072 3735 -448 4045 9100 -3101 6548 1511 2539 408 1417 -4435 5653 -1435 2199 -4220 2682 646 -1287 -84 5045 -835 -6803 15 3666 3582 -5947 5652 928 295 -3581 3313 277 4417 -83 3131 -3710 3482 -3313 3320 3434 6808 -2724 191 2464 -1001 1631 -41 2687 -4016 8097 -2686 678 -4159 1570 -4031 -2201 977 4535 1210 -4517 -1074 -6267 5620 -1047 -1709 3598 -5483 -4974 353 1442 -10379 -6346 -1077 -3072 3562 -1857 -645 1625 4380 -1771 6183 6318 -3310 -944 914 4933 3635 -2230 -12681 8239 -362 SO 20191126T124014.0Z 7269.527940 520 1 32.01 2 88.59 121.25 86.60 119.63 0.00 1 0.00 1 0 15 2.957e-02 2.935e-02 2.853e-02 2.827e-02 1.717296e+03 1.572810e+03 2.588157e+02 -6.000000e+00 1.491560e+03 275.90 -2.00 20.00 -2.00 505.24 0.00e+00 3.608571e-03 7.452300e-04 1.752530e-04 -6.000000e+00 7.972273e-04 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