File name: Pandora103s1_Downsview_20191209_L2Fit_fwvt1c10d20181123p1-8.txt File generation date: 20241101T065418.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c10p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20190801.txt Level 1 file used: Pandora103s1_Downsview_20191209_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20191209 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 1620 1769 Nominal wavelengths inside fitting window [nm]: 492.0103 492.1315 492.2527 492.3739 492.4950 492.6162 492.7373 492.8584 492.9795 493.1006 493.2216 493.3426 493.4637 493.5847 493.7057 493.8266 493.9476 494.0685 494.1894 494.3103 494.4312 494.5521 494.6730 494.7938 494.9146 495.0354 495.1562 495.2770 495.3977 495.5185 495.6392 495.7599 495.8806 496.0012 496.1219 496.2425 496.3631 496.4837 496.6043 496.7249 496.8454 496.9660 497.0865 497.2070 497.3275 497.4480 497.5684 497.6888 497.8093 497.9297 498.0500 498.1704 498.2907 498.4111 498.5314 498.6517 498.7720 498.8922 499.0125 499.1327 499.2529 499.3731 499.4933 499.6135 499.7336 499.8537 499.9739 500.0940 500.2140 500.3341 500.4541 500.5742 500.6942 500.8142 500.9341 501.0541 501.1740 501.2940 501.4139 501.5338 501.6536 501.7735 501.8933 502.0132 502.1330 502.2528 502.3725 502.4923 502.6120 502.7318 502.8515 502.9711 503.0908 503.2105 503.3301 503.4497 503.5693 503.6889 503.8085 503.9280 504.0476 504.1671 504.2866 504.4061 504.5255 504.6450 504.7644 504.8838 505.0032 505.1226 505.2420 505.3613 505.4807 505.6000 505.7193 505.8385 505.9578 506.0770 506.1963 506.3155 506.4347 506.5539 506.6730 506.7922 506.9113 507.0304 507.1495 507.2685 507.3876 507.5066 507.6257 507.7447 507.8637 507.9826 508.1016 508.2205 508.3394 508.4583 508.5772 508.6961 508.8149 508.9338 509.0526 509.1714 509.2902 509.4089 509.5277 509.6464 509.7651 509.8838 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20191209T124643.0Z 7282.532442 376 1 32.01 2 89.77 122.75 116.84 322.84 0.00 1 0.00 1 0 33 1.256e-01 1.129e-01 1.118e-01 1.072e-01 7.117954e+03 6.814749e+03 2.268100e+01 -6.000000e+00 6.299654e+03 274.43 -2.00 20.00 -2.00 505.25 0.00e+00 5.270279e-03 2.822742e-03 1.994991e-04 -6.000000e+00 3.376925e-03 274.43 -2.00 20.00 -2.00 499.95 0.00e+00 3.668402e+00 2.136826e+00 1.662861e-01 -6.000000e+00 2.427047e+00 222.26 -2.00 3.57 -2.00 501.59 0.00e+00 20.384 0.165 489.00 513.00 1 9.9781e+00 1.6348e-01 3.9010e-02 -6.0000e+00 1.8463e-01 1.0515e-01 4.2570e-02 3.3339e-03 -6.0000e+00 4.9624e-02 3.6568e-06 3.0481e-03 7.9792e-03 6.0532e-05 -6.0000e+00 9.8089e-03 1.1504e-02 -1.8510e-04 12 8 8 10 0 0 -10.76 15.00 4.35 0.01150 0.03265 8 1 1 4 0 4000.000 21.69 15.00 18.43 900000 -9545 8179 -3029 -12853 1542 -9533 7541 -3311 14123 2641 14714 -6029 21458 -14412 10554 7923 9881 -447 -4180 -5392 -6047 -2154 6127 3612 3605 8939 -1337 -1408 1350 13450 231 4149 -20623 16815 4562 11624 -9339 -4796 -6059 9321 -1923 -16268 -4981 10528 1187 -1519 10864 1981 9379 -4378 6333 3956 43072 -2368 16995 -12057 14572 -17903 837 -3362 -5311 -2572 12288 -5257 8090 20963 -1061 -1466 -18562 14881 385 27376 -9466 11826 2141 29574 -9607 3524 1554 -224 -10396 -1260 -19033 8311 13293 -1342 11765 -7169 11841 17661 25563 -2735 19284 -22604 32784 -23677 11193 -6430 11917 -2687 -9227 16419 42135 -1454 6474 11250 3565 -9673 16412 -21146 -5553 1396 -10468 8997 6326 9952 -2580 -6908 -13042 9907 -8027 536 10422 28420 -10170 -5413 -1381 35627 -1105 7837 6954 9356 3111 -6921 1476 -9378 12999 -2244 3764 4234 11713 2391 -8248 5577 11680 -11881 -7900 -12479 2902 900000 -10188 7611 -3281 -15758 1676 -11780 8005 -3905 13871 2834 13862 -6833 18328 -17216 9890 7682 9611 -496 -4891 -6357 -7170 -2458 6470 3948 3964 9305 -1530 -1582 1411 12092 236 4136 -27157 16108 4976 11683 -11313 -5489 -6940 9206 -2137 -21055 -5866 10825 1343 -1760 11027 2155 9296 -4789 6054 3795 28391 -2481 15368 -14835 14008 -23500 909 -3788 -6138 -2911 12028 -6047 8038 17999 -1106 -1518 -22285 12704 377 20830 -10399 10735 2122 21937 -10112 3226 1438 -210 -10829 -1205 -21619 7326 11256 -1305 9990 -7231 9895 13980 19014 -2733 15716 -27110 22433 -27109 8881 -5884 8903 -2269 -8356 11980 25282 -1376 5699 9333 3121 -9477 12606 -23870 -5500 1311 -11126 7956 5756 8847 -2620 -7297 -14364 8566 -8077 491 8767 20384 -10593 -5404 -1326 23853 -1058 6881 6018 7747 2709 -6601 1317 -9564 10889 -2200 3528 3980 10263 2303 -8845 5243 10305 -12908 -8004 -12866 2566 SO 20191209T125037.0Z 7282.535151 380 1 32.02 2 89.18 123.42 117.24 323.77 0.00 1 0.00 1 0 15 9.101e-02 8.864e-02 8.184e-02 7.935e-02 4.323895e+02 4.223816e+03 1.214167e+02 -6.000000e+00 4.566654e+03 274.43 -2.00 20.00 -2.00 505.19 0.00e+00 2.375080e-03 2.075099e-03 1.097635e-04 -6.000000e+00 2.443961e-03 274.43 -2.00 20.00 -2.00 499.77 0.00e+00 3.834242e+00 1.568888e+00 2.783317e-02 -6.000000e+00 1.746864e+00 222.26 -2.00 3.57 -2.00 501.43 0.00e+00 19.271 0.139 489.00 513.00 1 9.8704e+00 1.2006e-01 3.3392e-02 -6.0000e+00 1.3312e-01 1.2689e-01 3.1715e-02 1.8942e-03 -6.0000e+00 3.5363e-02 5.0015e-06 -2.7306e-03 5.9647e-03 3.4735e-05 -6.0000e+00 7.0963e-03 -6.5692e-02 6.6134e-04 12 8 8 10 0 0 98.04 15.00 5.41 -0.06569 -0.08463 8 1 1 4 0 4000.000 21.69 15.00 18.45 13618 -12566 -3431 -18985 10109 -4992 10249 852 -1787 -1984 13137 -3318 -4867 9616 8772 10814 -1299 -2240 22159 -882 -7686 6960 2298 5032 3602 2873 5365 11835 -8878 -1663 5392 3986 554 -984 1957 -9084 -9995 -6889 -5584 -6661 12516 165 5844 1446 3884 -1046 18845 -8935 2295 6618 12339 -15726 2795 -5239 -1119 -6864 -2175 5789 -3652 -612 856 6726 10425 5552 -13637 17901 -5049 4476 -6719 12806 -12149 5035 11188 6217 -9696 15408 -14505 2218 -1972 20754 1020 -7565 189 -540 7177 -16211 17270 -5739 16712 -20556 -3719 -8531 11584 6285 11755 14448 4238 -4759 -12126 -2737 -5042 3978 3099 815 3347 8785 3246 4721 -10508 -987 -8152 7819 -524 18838 184 -6474 -4860 4448 3553 -994 7852 9359 2937 1567 -6449 -9604 -2179 10107 -465 -12680 15189 4363 10492 -7993 6067 8244 15390 6956 14415 -11839 8123 10356 10574 -7545 -11262 -5114 -8327 10935 7889 -13344 11778 -14174 -3659 -24589 10149 -5904 10690 987 -2125 -2330 13049 -3816 -5596 9434 8588 10369 -1414 -2520 20346 -1029 -9550 7499 2585 5522 4040 3256 5903 12166 -10925 -1822 5340 4000 584 -1095 2207 -11511 -12588 -8281 -6533 -7772 12104 181 6135 1603 4257 -1206 17821 -10902 2467 6659 11333 -18350 2671 -5413 -1142 -7700 -2392 5941 -4092 -659 904 6755 10143 5648 -16558 15705 -5411 4299 -7114 11021 -13080 4586 9679 5724 -10565 13070 -15994 2026 -1855 15568 926 -7534 175 -505 6287 -17949 13803 -5700 13291 -23452 -3614 -8803 10050 5789 10150 11944 3796 -4525 -12014 -2408 -4474 3265 2644 743 3054 7549 2883 4039 -10264 -886 -8008 6710 -496 14954 176 -6618 -4922 4125 3286 -942 6715 7760 2576 1411 -6330 -9702 -2050 8413 -427 -13200 12020 3749 8320 -7474 4914 6639 11924 5966 11634 -12449 7061 8810 9028 -7735 -12008 -5108 -8383 8821 6379 -13210 SO 20191209T125427.0Z 7282.537813 384 1 32.03 2 88.61 124.09 117.62 324.69 0.00 1 0.00 1 0 32 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