File name: Pandora103s1_Downsview_20191221_L2Fit_fwvt1c10d20181123p1-8.txt File generation date: 20241101T065452.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c10p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v7d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20190801.txt Level 1 file used: Pandora103s1_Downsview_20191221_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20191221 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 1620 1769 Nominal wavelengths inside fitting window [nm]: 492.0103 492.1315 492.2527 492.3739 492.4950 492.6162 492.7373 492.8584 492.9795 493.1006 493.2216 493.3426 493.4637 493.5847 493.7057 493.8266 493.9476 494.0685 494.1894 494.3103 494.4312 494.5521 494.6730 494.7938 494.9146 495.0354 495.1562 495.2770 495.3977 495.5185 495.6392 495.7599 495.8806 496.0012 496.1219 496.2425 496.3631 496.4837 496.6043 496.7249 496.8454 496.9660 497.0865 497.2070 497.3275 497.4480 497.5684 497.6888 497.8093 497.9297 498.0500 498.1704 498.2907 498.4111 498.5314 498.6517 498.7720 498.8922 499.0125 499.1327 499.2529 499.3731 499.4933 499.6135 499.7336 499.8537 499.9739 500.0940 500.2140 500.3341 500.4541 500.5742 500.6942 500.8142 500.9341 501.0541 501.1740 501.2940 501.4139 501.5338 501.6536 501.7735 501.8933 502.0132 502.1330 502.2528 502.3725 502.4923 502.6120 502.7318 502.8515 502.9711 503.0908 503.2105 503.3301 503.4497 503.5693 503.6889 503.8085 503.9280 504.0476 504.1671 504.2866 504.4061 504.5255 504.6450 504.7644 504.8838 505.0032 505.1226 505.2420 505.3613 505.4807 505.6000 505.7193 505.8385 505.9578 506.0770 506.1963 506.3155 506.4347 506.5539 506.6730 506.7922 506.9113 507.0304 507.1495 507.2685 507.3876 507.5066 507.6257 507.7447 507.8637 507.9826 508.1016 508.2205 508.3394 508.4583 508.5772 508.6961 508.8149 508.9338 509.0526 509.1714 509.2902 509.4089 509.5277 509.6464 509.7651 509.8838 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20191221T125531.0Z 7294.538553 393 1 32.01 2 89.78 123.68 51.64 173.12 0.00 1 0.00 1 0 29 1.064e-01 1.007e-01 9.318e-02 8.978e-02 8.565780e+02 4.903415e+03 5.817417e+02 -6.000000e+00 5.315944e+03 273.35 -2.00 20.00 -2.00 505.26 0.00e+00 -1.619668e-05 2.344162e-03 6.286707e-05 -6.000000e+00 2.852002e-03 273.35 -2.00 20.00 -2.00 499.73 0.00e+00 4.401645e+00 1.796236e+00 1.039771e-01 -6.000000e+00 2.051435e+00 222.40 -2.00 3.57 -2.00 501.44 0.00e+00 20.412 0.166 489.00 513.00 1 9.8329e+00 1.3682e-01 3.7418e-02 -6.0000e+00 1.5614e-01 1.1248e-01 3.6538e-02 2.3321e-03 -6.0000e+00 4.1699e-02 4.3824e-06 1.0277e-03 6.7832e-03 5.7892e-05 -6.0000e+00 8.2983e-03 2.8970e-02 -2.0462e-04 12 8 8 10 0 0 2.79 15.00 2.88 0.02897 0.03610 8 1 1 4 0 4000.000 21.58 15.00 18.26 -10945 8296 6523 -9619 -4440 16022 8650 14840 1994 -4394 7991 13489 -16377 2996 -1930 9334 -12929 8638 -14225 9470 -10786 -4087 7517 -2263 -8546 8804 14238 2014 7008 7732 4054 -7760 8274 -5678 5048 -10655 1147 -4591 -8049 -4543 13140 7362 5494 -3560 5787 -7237 12636 -2264 8456 7941 -12238 3932 -2895 582 -6309 16165 -1540 -2702 -4070 26609 691 1664 -8813 -14342 -15832 -3683 3676 11672 7748 19476 -8784 2394 12371 19856 -15363 -2902 -10352 3892 5186 12474 19271 6038 25537 -10653 11255 -858 4480 1894 2478 11548 3863 4370 13176 2918 21327 -3578 -2514 3305 3302 -6552 -800 -864 8710 14297 -22197 21887 -7149 14419 -2407 23850 -15121 -8139 -1632 12852 6345 -2880 -2631 -614 -9238 -14294 -5668 8127 12499 -15623 23030 -12733 5916 -2672 8752 -7402 -2614 -14746 8679 -11737 7545 -3603 1950 -6519 -1792 -6772 -5722 19588 -9959 21644 5236 18732 -215 23090 918 678 -11875 7554 6242 -11227 -5071 15279 9061 14867 2267 -5254 8312 13160 -21031 3133 -2097 9087 -15778 8774 -18669 10069 -13929 -4948 8117 -2688 -10867 9482 14468 2291 7453 7812 4105 -8802 8153 -6659 5571 -13845 1312 -5457 -9748 -5239 12721 7563 5800 -4145 6222 -8852 12679 -2585 8548 7876 -14235 3781 -2909 564 -6709 14378 -1668 -2987 -4542 21853 724 1736 -10220 -17503 -19440 -3948 3588 10364 7069 15600 -9076 2217 10493 15892 -17553 -2926 -10923 3484 4525 10077 14585 5243 18460 -10945 9470 -820 4063 1755 2276 9716 3508 3991 11275 2779 16799 -3515 -2397 2898 2813 -5976 -681 -744 7047 11496 -26234 16856 -7150 11447 -2207 17029 -16014 -8204 -1567 10846 5724 -2848 -2612 -601 -9740 -15536 -5569 6872 10044 -16647 17073 -13308 5167 -2529 7380 -7340 -2472 -15364 7065 -11481 6078 -3277 1734 -6440 -1714 -6876 -5783 15532 -10572 17080 4861 15223 -206 17094 817 601 SO 20191221T125925.0Z 7294.541262 397 1 32.01 2 89.19 124.36 51.58 174.33 0.00 1 0.00 1 0 22 6.929e-02 6.736e-02 7.328e-02 7.156e-02 7.659332e+03 4.626097e+03 6.727785e+02 -6.000000e+00 3.461505e+03 273.35 -2.00 20.00 -2.00 505.23 0.00e+00 2.472204e-03 1.889178e-03 6.634445e-05 -6.000000e+00 1.858399e-03 273.35 -2.00 20.00 -2.00 499.85 0.00e+00 3.572656e+00 1.431899e+00 3.340146e-02 -6.000000e+00 1.341254e+00 222.40 -2.00 3.57 -2.00 501.49 0.00e+00 19.312 0.140 489.00 513.00 1 9.7690e+00 1.0922e-01 3.3503e-02 -6.0000e+00 1.0197e-01 1.0666e-01 2.8660e-02 2.1260e-03 -6.0000e+00 2.7447e-02 5.5598e-06 4.7600e-03 5.2583e-03 7.1859e-05 -6.0000e+00 5.4116e-03 2.0878e-02 -3.0870e-04 12 8 8 10 0 0 -9.79 15.00 2.67 0.02088 0.05390 8 1 1 4 0 4000.000 21.58 15.00 18.27 900000 6667 -635 2622 -7188 -5110 4281 -4852 3044 -4101 5552 1243 -5821 3431 16764 -5908 2401 14006 3496 1608 2908 2752 -562 8067 -5015 53 -5489 10482 -9333 -347 -6442 1850 -2967 3268 2705 20079 3194 1409 -8743 3997 -7720 -6733 -2945 139 -5186 -6655 9940 -3647 7428 4280 -2858 -9826 10548 -10765 6725 1130 8926 -7393 11015 -7169 4400 -10052 4538 18290 498 3827 -1030 716 6340 5006 1408 4088 -6762 2949 3309 -6943 -8197 -3490 -10880 310 -5840 7208 -2799 9066 -7835 8564 2130 4817 3049 -4213 -3847 -11047 9328 6714 -67 4228 5884 -4559 4473 -4854 3203 -10817 2183 -6189 2541 -5330 11539 -620 -2675 -5956 -7234 11299 4902 1190 5956 -5385 -1333 3234 -4176 3985 -2997 3786 -4659 9596 -5270 6768 -3429 11755 10694 7841 -2223 4828 12307 -244 7993 -11569 7801 -11554 209 -10375 654 8322 8804 -799 -7441 -5425 4319 -7129 14764 4057 900000 6111 -646 2699 -8371 -5937 4643 -5830 3391 -4832 5835 1345 -6644 3517 14949 -6559 2483 13259 3789 1807 3215 3048 -642 8487 -6041 61 -6637 10802 -11425 -372 -7091 1878 -3204 3455 3002 19032 3515 1553 -10486 4182 -9035 -7857 -3351 155 -6184 -8085 10228 -4222 7592 4406 -3044 -10840 9359 -11736 6358 1173 8822 -8642 10736 -8262 4509 -11923 4697 16533 530 3876 -1069 718 5957 4684 1340 3784 -7012 2821 3203 -7383 -8588 -3401 -11236 285 -5684 6228 -2675 7744 -7979 7510 1984 4340 2770 -4088 -3726 -11620 8220 6096 -64 3735 4960 -4119 3608 -4179 2513 -9823 1810 -5877 2310 -5261 9549 -565 -2446 -5654 -7099 9423 4397 1113 5326 -5385 -1297 3050 -4225 3660 -2883 3333 -4393 7956 -5110 5845 -3276 9679 8849 6707 -2093 4146 9632 -214 6437 -11433 6591 -12001 196 -10926 624 7393 7829 -784 -7798 -5549 3946 -7062 11522 3494 SO 20191221T130312.0Z 7294.543889 401 1 32.01 2 88.63 125.02 51.54 175.50 0.00 1 0.00 1 0 22 5.544e-02 5.414e-02 5.027e-02 4.937e-02 8.094617e+03 3.145038e+03 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