File name: Pandora103s1_Downsview_20200531_L2Fit_fout2c9d20181123p1-8.txt File generation date: 20241101T083058.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v9d20171016.txt Instrument calibration file used: Pandora103s1_CF_v9d20200521.txt Level 1 file used: Pandora103s1_Downsview_20200531_L1_smca1c9d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20200531 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 201 343 Nominal wavelengths inside fitting window [nm]: 305.0757 305.2165 305.3573 305.4981 305.6389 305.7797 305.9205 306.0612 306.2020 306.3427 306.4834 306.6241 306.7649 306.9055 307.0462 307.1869 307.3276 307.4682 307.6089 307.7495 307.8901 308.0307 308.1713 308.3119 308.4525 308.5930 308.7336 308.8741 309.0147 309.1552 309.2957 309.4362 309.5767 309.7172 309.8576 309.9981 310.1385 310.2790 310.4194 310.5598 310.7002 310.8406 310.9810 311.1214 311.2617 311.4021 311.5424 311.6827 311.8231 311.9634 312.1037 312.2439 312.3842 312.5245 312.6647 312.8050 312.9452 313.0854 313.2256 313.3658 313.5060 313.6462 313.7863 313.9265 314.0666 314.2068 314.3469 314.4870 314.6271 314.7672 314.9073 315.0473 315.1874 315.3274 315.4675 315.6075 315.7475 315.8875 316.0275 316.1675 316.3074 316.4474 316.5873 316.7273 316.8672 317.0071 317.1470 317.2869 317.4268 317.5666 317.7065 317.8463 317.9862 318.1260 318.2658 318.4056 318.5454 318.6852 318.8250 318.9647 319.1045 319.2442 319.3839 319.5236 319.6633 319.8030 319.9427 320.0824 320.2220 320.3617 320.5013 320.6409 320.7806 320.9202 321.0598 321.1993 321.3389 321.4785 321.6180 321.7575 321.8971 322.0366 322.1761 322.3156 322.4551 322.5945 322.7340 322.8734 323.0129 323.1523 323.2917 323.4311 323.5705 323.7099 323.8492 323.9886 324.1279 324.2673 324.4066 324.5459 324.6852 324.8245 324.9638 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200531T101410.0Z 7456.426505 203 1 49.98 2 85.31 63.76 121.44 316.91 0.00 1 0.00 1 0 25 6.791e-01 7.472e-02 5.278e-01 7.598e-02 1.086832e+00 4.585907e-02 1.194569e-02 -6.000000e+00 4.252235e-01 231.98 -2.00 3.57 -2.00 322.10 0.00e+00 -7.621869e-04 1.591873e-02 9.373176e-03 -6.000000e+00 2.003556e-02 282.59 -2.00 20.00 -2.00 321.43 0.00e+00 10.272 0.021 302.00 328.00 3 -6.3191e-02 1.5488e-01 1.2815e-01 -6.0000e+00 1.0700e+00 2.6835e+00 1.7935e-01 8.4670e-02 -6.0000e+00 1.1605e+00 -2.4700e+00 9.6573e-02 3.0131e-02 -6.0000e+00 6.8030e-01 7.5771e-01 5.4132e-02 9.3578e-03 -6.0000e+00 2.8299e-01 5.4137e-06 2.6858e-03 2.0481e-03 1.2208e-04 -6.0000e+00 2.2184e-02 1.0663e-02 0.0000e+00 12 8 8 10 0 0 93.42 15.00 1.16 0.01066 0.03085 23 4 1 5 0 2172.710 21.88 15.00 18.73 12190 326706 -8053 900000 -9842 900000 -79564 900000 253172 900000 140714 12310 -17029 900000 -16189 92738 10276 42580 51707 900000 -28991 210348 900000 12703 164826 -62100 117718 -17636 900000 20836 900000 -10035 35033 -70634 269600 -94277 900000 119991 63167 7597 -3185 -12398 -28123 156829 900000 66013 146092 67021 900000 900000 -2388 900000 -40486 900000 -31876 900000 5004 900000 -7238 91462 5350 -5751 -7119 27932 13371 123287 -10430 -12 156168 -11697 74549 44009 21078 -21668 14348 -41555 -56851 103244 17145 -25967 25881 47757 3467 6618 4491 3904 477 3028 16439 14611 -18680 30156 -6372 1070 -784 1150 -5340 30725 2745 9136 -13356 -2615 -15077 4965 -2716 19374 5275 14577 -4348 3993 7189 1698 4706 -6929 2263 640 2100 2752 10185 -42 1967 -10411 -71 -3620 -1072 -4177 2054 -9348 2678 -2995 920 -2255 1459 -1912 1249 -1920 -1297 1747 -1561 3043 -588 3173 -4 1662 24124 -1144 900000 -1030 900000 -13106 900000 18694 900000 10390 909 -1991 900000 -2490 6848 1328 3930 4136 900000 -4281 15532 900000 1094 12171 -10317 8692 -1519 900000 1539 900000 -1111 2822 -14343 19907 -20884 900000 8860 4664 969 -470 -1997 -5097 11580 900000 4874 10787 4949 900000 900000 -353 900000 -10055 900000 -7703 900000 806 900000 -1118 6754 682 -888 -1242 3750 2154 9103 -2170 -2 11531 -3219 9008 7090 3962 -5527 2215 -10042 -15647 7623 2877 -8018 5559 10226 1140 2221 1598 1441 186 1138 5186 4855 -7398 7793 -2446 427 -342 587 -3405 15469 1953 6010 -10041 -1562 -9412 2786 -1725 10443 3506 9795 -3706 3646 7190 1938 5370 -8837 2582 738 2453 3344 11896 -54 2376 -13418 -87 -4490 -1267 -4997 2381 -13667 4114 -5188 1730 -4814 3280 -4839 3277 -5427 -3708 4844 -4370 8448 -1558 7567 -10 SS 20200531T102719.4Z 7456.435641 206 1 50.77 2 83.16 65.94 122.99 320.13 0.00 1 0.00 1 0 25 5.100e-01 1.915e-02 3.546e-01 9.905e-03 9.755269e-01 6.030471e-03 1.102675e-02 -6.000000e+00 3.102471e-01 231.98 -2.00 3.57 -2.00 322.58 0.00e+00 1.273755e-02 4.078739e-03 2.976228e-03 -6.000000e+00 1.366594e-02 282.59 -2.00 20.00 -2.00 322.16 0.00e+00 7.669 0.009 302.00 328.00 3 4.0235e-01 2.6735e-02 9.4688e-02 -6.0000e+00 7.7778e-01 1.0871e+00 3.7069e-02 6.1259e-02 -6.0000e+00 8.4168e-01 -1.5134e+00 3.2689e-02 3.1000e-02 -6.0000e+00 4.9990e-01 6.0812e-01 1.4527e-02 1.5479e-02 -6.0000e+00 2.0623e-01 7.2527e-05 -7.0424e-04 2.8462e-04 3.1870e-04 -6.0000e+00 1.5732e-02 1.0033e-02 0.0000e+00 12 8 8 10 0 0 40.34 15.00 0.34 0.01003 0.00474 129 24 1 5 0 393.450 21.88 15.00 18.73 -75519 -45892 -62071 -131523 -36564 -142291 -104260 -183775 -14810 -167084 -12645 -135292 900000 -77358 18996 -80714 124454 -7788 37635 -21146 287151 -65809 -52561 -60370 35640 -5081 -62079 -5682 -116050 -50591 -21698 75241 5542 59634 2563 15275 4590 29667 3640 -2742 31539 108788 17272 11096 26388 39265 69622 79048 41743 50664 53943 27226 59755 23864 59588 10473 38337 33257 48427 7493 12674 11784 19227 24261 39280 18045 19378 28014 17798 19614 13508 17804 18851 10130 -1611 3554 -9252 -8 4395 2406 3683 2600 55 3523 2381 4667 3225 8708 2805 5532 3119 -233 -5597 -5172 -3266 -4563 1285 -4190 -1626 -3642 -2242 -4988 -581 -3334 -3807 -5221 548 -1269 1344 20 258 840 -658 -1029 -2373 -236 -1106 -10 -939 1224 915 2920 1462 2868 445 -64 120 1246 -965 1246 310 770 -325 -325 -191 -167 819 855 577 79 -161 -1858 -1407 -1061 -524 -817 -3118 -353 -2873 -1373 -5325 -143 -3961 -122 -2851 900000 -1562 183 -2480 1202 -137 430 -427 2773 -1849 -1246 -1537 379 -79 -1472 -82 -4789 -1244 -545 872 145 922 67 339 120 688 127 -104 1005 1681 684 472 968 1289 1748 1909 1572 1908 2188 1604 2770 1530 3050 809 2444 2152 2572 586 979 931 1621 2194 3276 1901 2059 2927 2313 2807 2206 2829 2847 1530 -245 465 -1340 -1 710 482 867 710 17 1126 813 1639 1198 3112 1047 1928 1057 -79 -2020 -2043 -1488 -2532 799 -3168 -1308 -3019 -1711 -3504 -360 -2117 -2554 -3787 402 -1046 1236 22 315 1104 -906 -1415 -3236 -313 -1510 -14 -1408 1819 1325 3938 1917 3608 559 -79 149 1680 -1548 2277 643 1734 -801 -865 -542 -494 2449 2560 1700 222 -420 -4579 -3385 SS 20200531T103749.3Z 7456.442931 209 1 50.51 2 81.41 67.65 124.16 322.79 0.00 1 0.00 1 0 17 6.983e-01 1.318e-02 2.310e-01 3.724e-03 8.453760e-01 2.185877e-03 1.031741e-02 -6.000000e+00 4.247514e-01 231.98 -2.00 3.57 -2.00 322.17 0.00e+00 8.784600e-03 1.412814e-03 9.648832e-03 -6.000000e+00 1.852227e-02 282.59 -2.00 20.00 -2.00 321.69 0.00e+00 6.314 0.005 302.00 328.00 3 4.6548e-01 9.0988e-03 8.9762e-02 -6.0000e+00 1.0649e+00 3.1465e-01 1.3823e-02 7.2230e-02 -6.0000e+00 1.1523e+00 -5.6348e-01 1.4242e-02 3.8632e-02 -6.0000e+00 6.8430e-01 2.4197e-01 6.2527e-03 1.1996e-02 -6.0000e+00 2.8211e-01 3.1128e-04 -2.7220e-04 1.1057e-04 3.1766e-04 -6.0000e+00 2.1487e-02 9.2555e-03 0.0000e+00 12 8 8 10 0 0 54.79 15.00 0.26 0.00926 0.00721 292 54 1 5 0 172.930 21.88 15.00 18.74 -166370 -209361 -153389 -211817 -239702 -205680 -253296 -205604 -273727 -175801 -240414 -82553 -217025 -94057 -169011 29575 -84100 21154 -106408 25662 -89831 -16490 -50185 -44613 -29841 -40022 8016 -62861 -36694 -60166 -36423 -28504 11294 -31486 22492 -25753 21473 1243 43032 -2475 26552 21477 45688 26657 31643 12253 9595 23353 16990 18395 16409 27332 19417 17071 18494 20667 6073 7724 5009 14216 2712 11579 6507 16546 4826 16664 7879 10781 6416 11240 9550 6200 5439 1369 3029 -2860 -1612 -6273 -1198 -1594 1233 -458 70 -1570 674 -445 1806 1076 1696 -67 252 -2292 -2703 -2853 -3082 -1635 -631 -138 -1045 -738 -2444 -2538 -2066 -1446 -2640 -435 -1125 352 797 1820 818 1067 188 -431 -922 -883 -602 262 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