File name: Pandora103s1_Downsview_20200721_L2Fit_fout2c9d20181123p1-8.txt File generation date: 20241101T092958.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v10d20171016.txt Instrument calibration file used: Pandora103s1_CF_v9d20200521.txt Level 1 file used: Pandora103s1_Downsview_20200721_L1_smca1c9d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20200721 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 201 343 Nominal wavelengths inside fitting window [nm]: 305.0757 305.2165 305.3573 305.4981 305.6389 305.7797 305.9205 306.0612 306.2020 306.3427 306.4834 306.6241 306.7649 306.9055 307.0462 307.1869 307.3276 307.4682 307.6089 307.7495 307.8901 308.0307 308.1713 308.3119 308.4525 308.5930 308.7336 308.8741 309.0147 309.1552 309.2957 309.4362 309.5767 309.7172 309.8576 309.9981 310.1385 310.2790 310.4194 310.5598 310.7002 310.8406 310.9810 311.1214 311.2617 311.4021 311.5424 311.6827 311.8231 311.9634 312.1037 312.2439 312.3842 312.5245 312.6647 312.8050 312.9452 313.0854 313.2256 313.3658 313.5060 313.6462 313.7863 313.9265 314.0666 314.2068 314.3469 314.4870 314.6271 314.7672 314.9073 315.0473 315.1874 315.3274 315.4675 315.6075 315.7475 315.8875 316.0275 316.1675 316.3074 316.4474 316.5873 316.7273 316.8672 317.0071 317.1470 317.2869 317.4268 317.5666 317.7065 317.8463 317.9862 318.1260 318.2658 318.4056 318.5454 318.6852 318.8250 318.9647 319.1045 319.2442 319.3839 319.5236 319.6633 319.8030 319.9427 320.0824 320.2220 320.3617 320.5013 320.6409 320.7806 320.9202 321.0598 321.1993 321.3389 321.4785 321.6180 321.7575 321.8971 322.0366 322.1761 322.3156 322.4551 322.5945 322.7340 322.8734 323.0129 323.1523 323.2917 323.4311 323.5705 323.7099 323.8492 323.9886 324.1279 324.2673 324.4066 324.5459 324.6852 324.8245 324.9638 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200721T103148.7Z 7507.438759 50 1 49.49 2 85.04 66.44 91.81 58.68 0.00 1 0.00 1 0 25 5.498e-01 6.614e-02 4.723e-01 5.989e-02 8.487622e-01 3.600236e-02 9.747454e-03 -6.000000e+00 3.408666e-01 232.81 -2.00 3.57 -2.00 321.92 0.00e+00 -1.653662e-02 1.406536e-02 1.824886e-02 -6.000000e+00 1.640562e-02 286.97 -2.00 20.00 -2.00 321.20 0.00e+00 9.855 0.018 302.00 328.00 3 7.3696e-01 1.2288e-01 1.6319e-01 -6.0000e+00 8.5696e-01 1.7806e+00 1.4809e-01 1.7983e-01 -6.0000e+00 9.2850e-01 -1.9490e+00 8.6893e-02 4.9913e-02 -6.0000e+00 5.5022e-01 6.8236e-01 4.3631e-02 1.8796e-02 -6.0000e+00 2.2756e-01 6.8829e-06 -2.9689e-04 1.8245e-03 8.4624e-05 -6.0000e+00 1.7574e-02 -3.0894e-03 0.0000e+00 12 8 8 10 0 0 92.00 15.00 0.98 -0.00309 -0.00532 21 4 1 5 0 2355.930 21.88 15.00 18.75 77579 110915 48539 900000 214611 900000 -64624 10936 -31486 116570 900000 20242 3775 -53025 317091 -12915 900000 78578 900000 52687 900000 900000 159866 11548 41807 2798 -30379 -5135 69593 900000 -9021 -63554 5194 21620 146939 32714 -56544 -11739 900000 61180 39815 132748 19346 100329 18802 77163 -9141 22308 24069 40829 131309 -29344 42176 58556 30499 -17823 108162 9579 115411 -14336 2665 84251 35845 35145 20024 -24054 14597 7331 -2705 -14392 8783 35293 23936 10755 -18443 934 -27610 115 -20300 -415 -19768 25351 -19590 25998 41183 84834 -19141 12128 -11790 21385 -2025 -4271 -18877 -4847 -10631 15876 -1880 8589 5850 4426 -5481 -18117 -12904 2045 3968 -5124 9752 -6637 10099 -3400 12096 5229 -3613 -5102 5893 340 8473 5902 2584 -1372 137 2177 253 8899 1733 7305 -9832 -5717 -4565 215 -5570 1750 -2914 571 1692 148 1077 -50 1195 -5368 -615 4174 3022 4900 6467 3538 900000 12513 900000 -9734 850 -3978 6797 900000 1574 367 -9791 18489 -1757 900000 4582 900000 3631 900000 900000 9321 1163 3324 326 -4509 -517 4058 900000 -861 -11454 496 1719 8568 2081 -9291 -1431 900000 4864 4221 7740 2461 5850 2093 4949 -1211 2128 2526 3809 7656 -5911 4918 6146 4446 -3968 7568 1731 6729 -2842 435 6386 4807 5123 3503 -6452 2639 1496 -678 -4531 2356 7408 5443 2571 -5269 196 -7244 23 -5681 -111 -7492 6947 -9252 8337 12007 16818 -11161 5233 -6324 7856 -886 -1818 -9246 -2204 -5827 7776 -1272 5909 4468 3458 -4442 -15106 -9556 1312 2637 -3974 6937 -6037 8715 -3826 13048 6494 -5034 -7139 7182 431 10029 7502 3571 -2024 197 2946 336 10586 2162 8390 -13415 -8033 -7239 374 -11431 3622 -6814 1396 4391 409 3046 -143 3371 -15555 -1593 9661 6960 SS 20200721T104446.3Z 7507.447759 53 1 50.69 2 82.88 68.58 89.88 60.85 0.00 1 0.00 1 0 17 4.363e-01 1.876e-02 3.684e-01 1.308e-02 7.642502e-01 7.749469e-03 1.004870e-02 -6.000000e+00 2.675676e-01 232.81 -2.00 3.57 -2.00 322.17 0.00e+00 1.341351e-02 4.852446e-03 1.091501e-02 -6.000000e+00 1.276819e-02 286.97 -2.00 20.00 -2.00 321.65 0.00e+00 7.412 0.008 302.00 328.00 3 1.3894e+00 3.2527e-02 9.8518e-02 -6.0000e+00 6.7315e-01 6.8451e-01 4.3538e-02 7.5141e-02 -6.0000e+00 7.2778e-01 -9.8226e-01 3.6336e-02 3.6968e-02 -6.0000e+00 4.3094e-01 4.0144e-01 1.6462e-02 1.0181e-02 -6.0000e+00 1.7898e-01 4.5211e-05 -8.7250e-04 4.1147e-04 3.3272e-04 -6.0000e+00 1.3648e-02 -4.6809e-03 0.0000e+00 12 9 8 11 8 0 91.71 14.99 0.38 -0.00468 -0.01124 55 10 1 5 0 921.510 21.88 14.99 18.76 -56827 -34209 26328 900000 -140745 -171266 -5767 -176305 900000 -82307 900000 -75370 -139825 -109843 37970 -37158 94560 212149 -27551 -17337 -32838 101591 29407 83287 -43557 13217 -43554 77909 -88676 -28046 55171 -36131 16606 -2269 -17950 -23357 -8831 1746 373 647 41293 24965 28941 33893 46580 7383 33652 20222 29630 30763 42154 24416 45786 31605 18670 37544 32162 -11750 1594 1813 7176 28513 23936 26303 23478 24055 11251 6515 5443 9698 -1304 10831 8682 3136 -4779 10001 -3533 8178 -1198 -3383 2483 -4166 -2478 1378 1195 -2992 2986 2234 -1812 2531 -1088 -4412 -2747 -3873 -2008 -3594 -524 -2865 -2058 -1270 -452 -5628 -1983 -1950 -1170 -3370 -1415 1160 -545 1782 1389 329 -235 -832 -216 -378 1644 -987 -15 33 1284 1996 1789 1538 1528 -121 -1348 270 -251 297 58 102 -232 -643 483 -59 521 -3 836 445 -1015 -988 -648 -725 -436 336 900000 -3589 -5360 -74 -5722 900000 -1049 900000 -1048 -4700 -3565 484 -861 1206 2705 -735 -422 -914 1295 450 1062 -1262 236 -1333 993 -3906 -823 844 -1508 508 -87 -778 -1042 -360 73 19 33 1685 1273 1476 1685 2079 499 1802 1289 1813 2000 2687 2055 3386 2861 1818 3399 3076 -1553 179 202 790 3090 2802 3354 3266 3346 1774 1125 1054 2024 -330 2498 2003 716 -1075 1762 -680 1460 -268 -922 751 -1536 -988 567 523 -1450 1433 1108 -930 1203 -508 -2020 -1216 -1836 -1064 -2275 -376 -2408 -1871 -1163 -387 -4606 -1459 -1438 -904 -2840 -1248 1083 -578 2093 1822 465 -340 -1190 -296 -510 2206 -1428 -23 52 1962 2922 2526 2114 2042 -159 -1786 373 -395 531 116 217 -531 -1586 1255 -162 1460 -10 2338 1207 -2625 -2398 -1536 SS 20200721T105523.3Z 7507.455131 56 1 50.56 2 81.09 70.33 88.27 62.60 0.00 1 0.00 1 0 17 4.876e-01 1.065e-02 2.108e-01 3.399e-03 6.814680e-01 1.967602e-03 8.345178e-03 -6.000000e+00 2.980841e-01 232.81 -2.00 3.57 -2.00 321.81 0.00e+00 5.752747e-03 1.147820e-03 7.039280e-03 -6.000000e+00 1.318679e-02 286.97 -2.00 20.00 -2.00 321.24 0.00e+00 6.104 0.004 302.00 328.00 3 8.2305e-01 7.7422e-03 7.8680e-02 -6.0000e+00 7.4779e-01 1.1017e-01 1.0886e-02 5.8481e-02 -6.0000e+00 8.0746e-01 -2.4373e-01 1.0482e-02 2.7925e-02 -6.0000e+00 4.8047e-01 1.0452e-01 4.7697e-03 6.7815e-03 -6.0000e+00 1.9912e-01 3.2125e-04 -5.8673e-04 1.0922e-04 1.8667e-04 -6.0000e+00 1.5004e-02 -5.4421e-03 0.0000e+00 12 8 8 10 0 0 92.50 15.00 0.23 -0.00544 -0.00985 218 41 1 5 0 231.900 21.88 15.00 18.77 -162786 -97193 -75284 -168462 -173977 -207406 -86415 -192376 -65193 -173218 -82962 -163731 84246 -137804 -9385 -96119 43664 -88583 -36952 -54632 -6839 -66317 -9849 -40150 -31281 -30515 -31452 -9194 -42731 -8609 -40076 -12910 -16100 11899 -35827 18178 -22105 1525 -22404 14565 -2449 13980 -3275 13493 4813 6842 4872 8826 10836 3300 12790 5343 14162 6827 12542 3375 8665 -1296 11723 1165 12810 6063 10421 5970 6418 2017 5168 1658 5419 2854 3762 1104 901 100 -2034 556 -2628 -1149 -4370 873 -2319 -35 -3837 70 -1711 452 -254 872 273 375 396 -1070 -4043 -2076 -1972 -1653 -346 -387 54 -876 -669 -2255 -695 -1570 -1237 -1356 310 138 1718 1759 1897 764 1011 176 -171 -629 -1235 -160 -222 318 485 1185 431 374 -28 -690 -837 -47 -606 230 -678 -160 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