File name: Pandora103s1_Downsview_20200819_L2Fit_fout2c9d20181123p1-8.txt File generation date: 20241101T100421.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v10d20171016.txt Instrument calibration file used: Pandora103s1_CF_v9d20200521.txt Level 1 file used: Pandora103s1_Downsview_20200819_L1_smca1c9d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20200819 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 201 343 Nominal wavelengths inside fitting window [nm]: 305.0757 305.2165 305.3573 305.4981 305.6389 305.7797 305.9205 306.0612 306.2020 306.3427 306.4834 306.6241 306.7649 306.9055 307.0462 307.1869 307.3276 307.4682 307.6089 307.7495 307.8901 308.0307 308.1713 308.3119 308.4525 308.5930 308.7336 308.8741 309.0147 309.1552 309.2957 309.4362 309.5767 309.7172 309.8576 309.9981 310.1385 310.2790 310.4194 310.5598 310.7002 310.8406 310.9810 311.1214 311.2617 311.4021 311.5424 311.6827 311.8231 311.9634 312.1037 312.2439 312.3842 312.5245 312.6647 312.8050 312.9452 313.0854 313.2256 313.3658 313.5060 313.6462 313.7863 313.9265 314.0666 314.2068 314.3469 314.4870 314.6271 314.7672 314.9073 315.0473 315.1874 315.3274 315.4675 315.6075 315.7475 315.8875 316.0275 316.1675 316.3074 316.4474 316.5873 316.7273 316.8672 317.0071 317.1470 317.2869 317.4268 317.5666 317.7065 317.8463 317.9862 318.1260 318.2658 318.4056 318.5454 318.6852 318.8250 318.9647 319.1045 319.2442 319.3839 319.5236 319.6633 319.8030 319.9427 320.0824 320.2220 320.3617 320.5013 320.6409 320.7806 320.9202 321.0598 321.1993 321.3389 321.4785 321.6180 321.7575 321.8971 322.0366 322.1761 322.3156 322.4551 322.5945 322.7340 322.8734 323.0129 323.1523 323.2917 323.4311 323.5705 323.7099 323.8492 323.9886 324.1279 324.2673 324.4066 324.5459 324.6852 324.8245 324.9638 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200819T110127.2Z 7536.459343 51 1 50.42 2 84.91 77.51 88.38 71.41 0.00 1 0.00 1 0 17 6.628e-01 5.932e-02 4.730e-01 4.669e-02 9.990617e-01 2.833683e-02 1.107904e-02 -6.000000e+00 4.101146e-01 231.47 -2.00 3.57 -2.00 322.18 0.00e+00 -3.586084e-03 1.208608e-02 5.891414e-03 -6.000000e+00 2.059369e-02 287.07 -2.00 20.00 -2.00 321.60 0.00e+00 9.668 0.017 302.00 328.00 3 2.7756e-01 1.0470e-01 1.1598e-01 -6.0000e+00 1.0285e+00 2.1676e+00 1.2155e-01 7.2186e-02 -6.0000e+00 1.1158e+00 -2.3260e+00 6.1425e-02 2.6028e-02 -6.0000e+00 6.5931e-01 8.2473e-01 3.4907e-02 1.0481e-02 -6.0000e+00 2.7611e-01 9.3004e-06 -4.9632e-04 1.2999e-03 1.0171e-04 -6.0000e+00 2.1282e-02 -9.9428e-04 0.0000e+00 12 8 8 10 0 0 40.72 14.99 0.91 -0.00099 -0.00472 29 5 1 5 0 1738.310 21.79 14.99 18.56 17720 900000 -3800 159343 -35126 192945 -62476 900000 137099 900000 22291 900000 116969 12192 -21287 49183 36666 234791 31332 93224 162367 119577 -7696 -2294 81448 7290 900000 -75800 168413 -65580 900000 -12059 900000 -23379 61739 -73993 900000 32251 52524 16042 13723 76509 33030 101759 -20540 252103 79490 900000 18941 109613 770 51445 -8408 93583 56165 252126 -38441 18355 21184 160626 20582 206203 50825 46873 64969 8495 48157 4230 36368 40912 47063 -9416 26985 3417 86606 -31338 25586 -56476 44654 -7104 18544 -13325 8057 14 16426 20580 -10663 42362 15170 22347 1513 17897 -16070 12921 -11255 20503 -13212 5986 -8864 4563 -8073 13355 -20134 3045 -10172 1919 -865 3955 -5217 -2816 3257 3947 -4269 -2799 4595 449 4026 -2536 5912 -5414 1866 -3960 6114 5772 8217 -2522 -179 1434 -1321 1903 -1096 -1851 -386 -2769 997 3243 672 2365 -1832 -836 -2888 2548 -984 2282 900000 -533 7242 -4523 8769 -8755 900000 6231 900000 1266 900000 5316 1062 -2903 3539 3055 10671 2848 4237 7380 5435 -763 -218 3702 602 900000 -11588 7654 -8671 900000 -1196 900000 -2705 2806 -12229 900000 2132 3255 1591 1474 4426 2866 4625 -2716 11458 3974 900000 1644 4982 92 4443 -1285 5955 5361 11459 -8577 2199 2503 7301 2245 9372 4851 5113 6201 1429 5472 788 5455 6508 7487 -2412 5029 730 7085 -7406 3256 -17198 5683 -1808 4298 -4845 2600 5 5450 6828 -4992 11745 5378 7008 550 5287 -6719 4405 -5678 8946 -9488 4054 -6885 3443 -6457 7709 -14916 1771 -7073 1256 -621 2966 -4885 -2982 3686 4825 -5879 -3791 5660 569 5013 -3526 7900 -8219 2562 -5471 7309 6742 9150 -3049 -213 1831 -2017 3287 -2202 -4105 -915 -7298 2714 9049 1966 6825 -5421 -2333 -7614 5894 -2303 SS 20200819T111418.3Z 7536.468267 54 1 50.58 2 82.63 79.68 86.27 73.54 0.00 1 0.00 1 0 17 5.842e-01 1.372e-02 3.364e-01 7.242e-03 8.886337e-01 4.366461e-03 1.127550e-02 -6.000000e+00 3.601221e-01 231.47 -2.00 3.57 -2.00 322.32 0.00e+00 1.163212e-02 3.009529e-03 1.370870e-02 -6.000000e+00 1.644167e-02 287.07 -2.00 20.00 -2.00 321.84 0.00e+00 7.204 0.007 302.00 328.00 3 5.5270e-01 1.9547e-02 1.1034e-01 -6.0000e+00 9.0194e-01 5.6266e-01 2.8972e-02 9.7772e-02 -6.0000e+00 9.7731e-01 -8.1163e-01 2.8204e-02 4.4401e-02 -6.0000e+00 5.7950e-01 3.3277e-01 1.2341e-02 1.0280e-02 -6.0000e+00 2.4115e-01 1.1304e-04 -5.7008e-04 2.1467e-04 3.7447e-04 -6.0000e+00 1.8403e-02 -1.6026e-03 0.0000e+00 12 8 8 10 0 0 11.38 14.99 0.28 -0.00160 -0.00589 150 28 1 5 0 337.090 21.79 14.99 18.56 900000 -230019 900000 -249758 -225170 -245644 900000 -174481 -116127 -28150 -188180 -156900 900000 -54162 -122047 101375 -83508 900000 -75126 66329 -76945 48264 -109682 -24557 -44887 -13411 -114373 -6951 -88620 38619 -42169 18272 -33955 18730 -18969 4053 7783 418 17715 -29751 14368 -178 81481 -5477 34588 -12681 57329 -4379 38205 11843 8830 18439 37799 16900 44750 16729 15156 3345 4264 7241 4153 11819 10807 14542 11392 20560 12662 18201 7845 7806 4506 13770 9636 10121 1556 -245 -2797 -1193 -2942 3090 550 2454 1857 374 2437 291 2878 -745 1907 -1209 285 -2629 -4083 -5498 -3288 -2812 -399 -2162 -628 -1862 -1468 -2933 -1203 -3130 -3059 -2569 -1813 1171 1078 1623 496 -219 -49 -233 -499 693 1082 496 46 203 596 2050 1479 744 400 -606 247 359 -92 -308 -325 -175 417 152 -133 -367 550 -183 237 -457 148 -675 58 900000 -3394 900000 -4486 -2889 -3624 900000 -1343 -819 -199 -1931 -1409 900000 -382 -1801 715 -1178 900000 -1157 468 -1234 341 -2392 -260 -602 -132 -2788 -64 -1762 272 -757 245 -806 304 -442 74 148 10 425 -1202 415 -6 1495 -225 1074 -594 1537 -211 1429 577 498 1064 1988 1182 2497 1277 1186 290 356 581 360 1061 1130 1660 1447 2440 1657 2405 1293 1457 945 2712 1928 1876 284 -41 -470 -210 -615 735 160 805 678 149 1010 119 1207 -331 892 -562 124 -1127 -1776 -2620 -1776 -1650 -270 -1708 -534 -1626 -1199 -2187 -889 -2347 -2409 -2146 -1472 1009 1051 1805 627 -300 -68 -324 -677 915 1447 699 68 307 879 2846 1978 973 557 -827 336 524 -142 -550 -648 -379 964 379 -355 -1029 1564 -527 670 -1247 374 -1602 134 SS 20200819T112453.4Z 7536.475618 57 1 50.74 2 80.75 81.47 84.52 75.28 0.00 1 0.00 1 0 17 5.751e-01 9.528e-03 1.327e-01 2.747e-03 7.594454e-01 1.586131e-03 1.003534e-02 -6.000000e+00 3.497169e-01 231.47 -2.00 3.57 -2.00 321.86 0.00e+00 1.132318e-02 9.775872e-04 1.006099e-02 -6.000000e+00 1.555439e-02 287.07 -2.00 20.00 -2.00 321.31 0.00e+00 5.908 0.004 302.00 328.00 3 4.7385e-01 6.3838e-03 8.5060e-02 -6.0000e+00 8.7434e-01 2.3613e-01 9.2382e-03 7.1271e-02 -6.0000e+00 9.4521e-01 -3.5828e-01 9.0870e-03 3.6455e-02 -6.0000e+00 5.6311e-01 1.4621e-01 4.0793e-03 1.0296e-02 -6.0000e+00 2.3390e-01 4.7240e-04 -1.5474e-04 8.2492e-05 2.8846e-04 -6.0000e+00 1.7693e-02 -2.1449e-03 0.0000e+00 12 8 8 10 0 0 20.14 15.00 0.22 -0.00214 -0.00331 338 63 1 5 0 149.620 21.79 15.00 18.56 -239009 -112212 -157744 -166688 -227452 -139587 -183062 -150206 -206251 -194456 -179055 -136278 -101904 -100596 -74522 -70539 -44251 -86653 -53182 -61548 -39023 -38999 -18263 -67887 -8746 -57621 -24533 -47052 -36927 -45085 -26804 -9606 -7591 -7975 -139 -11824 -14732 2040 -7968 5013 12436 21749 6494 10607 9745 14134 5332 17093 7322 14023 7625 14076 13401 10388 7109 10263 5012 3970 7653 259 8037 7933 7396 7585 7127 7232 8199 3917 5189 3014 3180 1939 1814 -197 -108 -3380 -2200 -4764 -2338 -1263 -1638 -1054 -2088 -1280 -1021 -135 25 -375 492 143 -710 -221 -1361 -1430 -1347 -1082 -71 -20 -900 -1026 -1312 -902 -430 -875 -2510 -1372 -319 481 1500 1379 984 555 127 -43 65 439 764 213 102 -236 674 1028 907 12 -256 -747 41 373 -579 -569 -285 -344 99 233 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