File name: Pandora103s1_Downsview_20200821_L2Fit_fout2c9d20181123p1-8.txt File generation date: 20241101T100343.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v10d20171016.txt Instrument calibration file used: Pandora103s1_CF_v9d20200521.txt Level 1 file used: Pandora103s1_Downsview_20200821_L1_smca1c9d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20200821 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 201 343 Nominal wavelengths inside fitting window [nm]: 305.0757 305.2165 305.3573 305.4981 305.6389 305.7797 305.9205 306.0612 306.2020 306.3427 306.4834 306.6241 306.7649 306.9055 307.0462 307.1869 307.3276 307.4682 307.6089 307.7495 307.8901 308.0307 308.1713 308.3119 308.4525 308.5930 308.7336 308.8741 309.0147 309.1552 309.2957 309.4362 309.5767 309.7172 309.8576 309.9981 310.1385 310.2790 310.4194 310.5598 310.7002 310.8406 310.9810 311.1214 311.2617 311.4021 311.5424 311.6827 311.8231 311.9634 312.1037 312.2439 312.3842 312.5245 312.6647 312.8050 312.9452 313.0854 313.2256 313.3658 313.5060 313.6462 313.7863 313.9265 314.0666 314.2068 314.3469 314.4870 314.6271 314.7672 314.9073 315.0473 315.1874 315.3274 315.4675 315.6075 315.7475 315.8875 316.0275 316.1675 316.3074 316.4474 316.5873 316.7273 316.8672 317.0071 317.1470 317.2869 317.4268 317.5666 317.7065 317.8463 317.9862 318.1260 318.2658 318.4056 318.5454 318.6852 318.8250 318.9647 319.1045 319.2442 319.3839 319.5236 319.6633 319.8030 319.9427 320.0824 320.2220 320.3617 320.5013 320.6409 320.7806 320.9202 321.0598 321.1993 321.3389 321.4785 321.6180 321.7575 321.8971 322.0366 322.1761 322.3156 322.4551 322.5945 322.7340 322.8734 323.0129 323.1523 323.2917 323.4311 323.5705 323.7099 323.8492 323.9886 324.1279 324.2673 324.4066 324.5459 324.6852 324.8245 324.9638 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200821T124225.3Z 7538.529460 93 1 18.69 2 67.17 95.45 97.34 78.56 0.00 1 0.00 1 0 17 1.675e-02 6.718e-03 7.377e-03 1.302e-03 3.349733e-01 6.900432e-04 3.985587e-03 -6.000000e+00 1.017616e-02 231.28 -2.00 3.57 -2.00 318.38 0.00e+00 1.199635e-03 1.357546e-04 4.510042e-04 -6.000000e+00 4.526162e-04 286.90 -2.00 20.00 -2.00 317.55 0.00e+00 2.556 0.000 302.00 328.00 3 2.8765e+00 1.8799e-03 3.0773e-02 -6.0000e+00 2.5431e-02 6.9965e-03 2.1374e-03 1.7780e-02 -6.0000e+00 2.7499e-02 -1.9102e-02 1.3683e-03 8.6783e-03 -6.0000e+00 1.6383e-02 3.9357e-03 6.9060e-04 2.4949e-03 -6.0000e+00 6.8053e-03 1.6314e-03 2.7500e-04 4.1982e-05 2.9886e-05 -6.0000e+00 5.1524e-04 -1.0764e-03 0.0000e+00 12 9 1 12 1 1 98.89 15.00 0.13 -0.00108 0.00099 53 27 1 5 0 342.820 21.88 15.00 18.71 -6792 3102 -984 1822 -6658 242 -3557 -3331 -6300 -5228 -4733 -3341 -3360 -2356 -1321 201 2222 740 1679 -60 2018 1430 2073 -1004 -192 -2244 -1120 -2454 886 -1552 -713 -1270 -1780 -3599 -1850 -1677 -1927 -482 -1437 -1235 -1111 121 -200 262 406 778 45 334 -261 1557 794 835 842 1503 985 1170 623 -342 671 1371 1969 1946 1745 673 -493 800 874 913 1698 -126 -42 -817 -319 -504 -801 -1230 -845 -1011 -555 -1914 -1795 -1967 -1927 -813 -398 -139 80 351 184 246 181 75 175 810 -17 260 333 -66 -891 -1058 -571 22 703 443 -1198 -643 -83 477 1220 1262 796 52 362 226 712 846 780 457 -14 -735 -325 -102 -28 -338 -269 -594 82 465 -442 -677 -786 -412 23 471 26 -90 333 117 -238 18 -190 45 330 -373 170 -57 99 -366 12 -197 -206 -439 -377 -349 -259 -296 -240 -153 25 292 104 245 -9 311 224 331 -174 -35 -430 -210 -452 154 -278 -136 -267 -404 -847 -421 -382 -477 -137 -480 -464 -452 51 -88 115 180 345 20 147 -116 696 377 422 449 831 564 686 372 -206 397 809 1193 1253 1201 489 -362 562 588 616 1209 -99 -35 -705 -274 -421 -636 -912 -588 -694 -398 -1519 -1558 -1837 -1896 -829 -423 -155 93 412 215 281 197 77 172 793 -18 288 398 -85 -1184 -1401 -723 27 819 528 -1509 -840 -111 662 1754 1898 1242 82 561 338 1014 1170 1082 654 -21 -1138 -509 -158 -42 -503 -389 -835 112 645 -643 -1038 -1250 -667 39 799 45 -163 614 218 -445 34 -343 79 578 SS 20200821T130830.3Z 7538.547573 109 1 50.68 2 62.51 100.27 92.94 83.05 0.00 1 0.00 1 0 17 1.220e-02 6.452e-03 7.426e-03 1.508e-03 2.869872e-01 8.013005e-04 3.438947e-03 -6.000000e+00 7.411248e-03 231.28 -2.00 3.57 -2.00 318.34 0.00e+00 1.037594e-03 1.512086e-04 3.601619e-04 -6.000000e+00 3.296398e-04 286.89 -2.00 20.00 -2.00 317.48 0.00e+00 2.155 0.000 302.00 328.00 3 3.9929e+00 2.1808e-03 2.6105e-02 -6.0000e+00 1.8521e-02 2.6100e-02 2.4781e-03 1.5233e-02 -6.0000e+00 2.0027e-02 -1.2411e-02 1.5546e-03 7.4355e-03 -6.0000e+00 1.1932e-02 7.7696e-04 7.7265e-04 2.1424e-03 -6.0000e+00 4.9562e-03 8.2929e-04 2.2716e-04 4.9849e-05 2.6738e-05 -6.0000e+00 3.7526e-04 -9.6312e-04 0.0000e+00 11 8 0 10 0 0 99.81 14.99 0.24 -0.00096 0.00074 115 21 1 5 0 440.570 21.88 14.99 18.72 346 -194 -1569 849 -1827 317 -4136 -788 -3757 -1342 -4675 -1580 -2467 1002 982 575 762 1329 778 2346 536 1549 1921 -296 -1452 -2762 -1799 -1111 566 -1211 -698 -741 -1302 -4637 -1426 -2043 -1093 -1176 -402 -1803 -1211 -375 189 6 615 259 65 56 1 1259 872 1013 1277 944 920 935 615 85 615 1721 1802 2045 1438 711 -574 253 592 912 1320 -94 -619 -657 -485 -825 -775 -652 -880 -980 -785 -1895 -2001 -1947 -1823 -811 -157 -47 267 174 603 201 286 -67 345 734 177 191 217 6 -818 -727 -698 -190 546 225 -1359 -609 -15 402 1112 1145 579 279 199 363 478 964 688 328 71 -582 -500 -93 -14 -370 -311 -647 298 409 -409 -715 -814 -532 82 572 31 -108 346 268 -222 -142 -131 -49 376 21 -13 -108 54 -110 20 -284 -58 -314 -114 -417 -144 -255 116 118 76 107 193 118 397 94 270 340 -56 -296 -585 -371 -218 105 -227 -138 -160 -302 -1128 -326 -469 -271 -343 -138 -716 -522 -169 87 3 286 121 30 25 1 567 415 516 689 535 538 560 374 52 368 1022 1109 1347 1028 493 -401 181 395 603 935 -75 -491 -542 -397 -652 -621 -474 -588 -636 -536 -1460 -1730 -1691 -1692 -790 -161 -51 307 206 705 228 301 -65 338 707 182 198 250 8 -1086 -955 -861 -217 597 255 -1661 -784 -20 563 1635 1789 951 462 319 545 666 1273 910 455 105 -911 -797 -146 -22 -543 -435 -865 382 529 -565 -1065 -1272 -853 135 975 57 -204 671 528 -439 -275 -246 -89 669 SS 20200821T131430.5Z 7538.551742 112 1 50.94 2 61.45 101.42 91.92 84.07 0.00 1 0.00 1 0 17 1.172e-02 6.681e-03 7.382e-04 1.921e-04 2.762916e-01 1.018044e-04 3.321421e-03 -6.000000e+00 7.120663e-03 231.28 -2.00 3.57 -2.00 317.85 0.00e+00 9.899322e-04 1.701171e-05 2.897680e-04 -6.000000e+00 3.167157e-04 286.89 -2.00 20.00 -2.00 317.02 0.00e+00 2.082 0.000 302.00 328.00 3 4.6459e-01 2.7318e-04 2.5175e-02 -6.0000e+00 1.7795e-02 5.6977e-05 3.0794e-04 1.4643e-02 -6.0000e+00 1.9242e-02 -1.3795e-02 1.8667e-04 7.1146e-03 -6.0000e+00 1.1464e-02 1.7860e-03 9.1451e-05 2.0188e-03 -6.0000e+00 4.7619e-03 3.1256e-02 2.9110e-04 6.1985e-06 2.4777e-05 -6.0000e+00 3.6055e-04 -9.2350e-04 0.0000e+00 11 8 0 10 0 0 99.76 14.99 0.20 -0.00092 0.00126 2153 401 1 5 0 23.340 21.88 14.99 18.73 -1683 -1021 -1197 -1974 -1303 -1963 -2764 -2812 -3303 -3939 -2986 -1939 -2234 -903 -389 -193 1184 1563 1484 1466 1007 1897 1633 361 -451 -1263 -2106 -1366 -574 -208 -522 -490 -1593 -3595 -2203 -1195 -1498 -611 -894 -1210 -867 -48 56 242 773 300 208 138 428 1157 1022 851 1351 1001 934 1090 478 210 776 1289 1817 1832 1328 361 -531 358 638 1021 1476 -147 -538 -523 -585 -591 -920 -816 -870 -771 -848 -1743 -1968 -2018 -1914 -656 -286 -109 227 156 198 109 347 30 371 814 353 167 326 -128 -894 -895 -638 -220 793 316 -1110 -700 -47 470 1169 1182 660 282 324 312 557 999 759 534 25 -630 -455 -67 -98 -337 -184 -511 210 450 -457 -694 -774 -521 186 425 20 -102 462 99 -245 -122 -152 -103 415 -145 -95 -112 -177 -107 -156 -233 -266 -343 -427 -325 -220 -284 -131 -64 -34 220 302 299 305 215 402 353 83 -111 -321 -529 -326 -130 -47 -124 -127 -446 -1039 -610 -327 -447 -213 -369 -521 -406 -24 28 122 390 152 103 68 207 564 525 468 786 611 589 703 314 138 500 829 1207 1305 1025 295 -435 275 457 722 1118 -125 -458 -462 -515 -500 -793 -638 -624 -535 -621 -1436 -1820 -1876 -1903 -682 -316 -128 280 182 230 132 392 31 357 770 355 185 400 -159 -1172 -1162 -840 -268 926 383 -1453 -894 -63 651 1702 1828 995 430 513 463 766 1302 991 730 37 -975 -718 -105 -148 -490 -256 -735 289 626 -628 -1025 -1198 -826 302 719 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