File name: Pandora103s1_Downsview_20200823_L2Fit_fout2c9d20181123p1-8.txt File generation date: 20241101T100414.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v10d20171016.txt Instrument calibration file used: Pandora103s1_CF_v9d20200521.txt Level 1 file used: Pandora103s1_Downsview_20200823_L1_smca1c9d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20200823 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 201 343 Nominal wavelengths inside fitting window [nm]: 305.0757 305.2165 305.3573 305.4981 305.6389 305.7797 305.9205 306.0612 306.2020 306.3427 306.4834 306.6241 306.7649 306.9055 307.0462 307.1869 307.3276 307.4682 307.6089 307.7495 307.8901 308.0307 308.1713 308.3119 308.4525 308.5930 308.7336 308.8741 309.0147 309.1552 309.2957 309.4362 309.5767 309.7172 309.8576 309.9981 310.1385 310.2790 310.4194 310.5598 310.7002 310.8406 310.9810 311.1214 311.2617 311.4021 311.5424 311.6827 311.8231 311.9634 312.1037 312.2439 312.3842 312.5245 312.6647 312.8050 312.9452 313.0854 313.2256 313.3658 313.5060 313.6462 313.7863 313.9265 314.0666 314.2068 314.3469 314.4870 314.6271 314.7672 314.9073 315.0473 315.1874 315.3274 315.4675 315.6075 315.7475 315.8875 316.0275 316.1675 316.3074 316.4474 316.5873 316.7273 316.8672 317.0071 317.1470 317.2869 317.4268 317.5666 317.7065 317.8463 317.9862 318.1260 318.2658 318.4056 318.5454 318.6852 318.8250 318.9647 319.1045 319.2442 319.3839 319.5236 319.6633 319.8030 319.9427 320.0824 320.2220 320.3617 320.5013 320.6409 320.7806 320.9202 321.0598 321.1993 321.3389 321.4785 321.6180 321.7575 321.8971 322.0366 322.1761 322.3156 322.4551 322.5945 322.7340 322.8734 323.0129 323.1523 323.2917 323.4311 323.5705 323.7099 323.8492 323.9886 324.1279 324.2673 324.4066 324.5459 324.6852 324.8245 324.9638 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200823T111826.7Z 7540.471142 54 1 51.33 2 82.64 81.54 134.94 47.75 0.00 1 0.00 1 0 17 4.178e-01 1.975e-02 4.476e-01 1.803e-02 8.056829e-01 1.068814e-02 1.110761e-02 -6.000000e+00 2.557834e-01 231.10 -2.00 3.57 -2.00 322.15 0.00e+00 1.367315e-02 6.545858e-03 1.516933e-02 -6.000000e+00 1.181574e-02 286.73 -2.00 20.00 -2.00 321.62 0.00e+00 7.207 0.007 302.00 328.00 3 1.9195e+00 4.3847e-02 1.1280e-01 -6.0000e+00 6.4004e-01 8.8913e-01 5.7820e-02 1.0371e-01 -6.0000e+00 6.9300e-01 -1.1033e+00 4.8062e-02 4.3673e-02 -6.0000e+00 4.1034e-01 4.1611e-01 2.2091e-02 8.3145e-03 -6.0000e+00 1.7075e-01 2.8398e-05 -1.2127e-04 5.4940e-04 3.6229e-04 -6.0000e+00 1.2926e-02 -9.8031e-04 0.0000e+00 12 8 8 10 0 0 17.66 15.00 0.52 -0.00098 -0.00189 42 8 1 5 0 1217.880 21.88 15.00 18.71 -37697 900000 71858 -34407 -110082 900000 -32509 -141393 900000 -93097 149817 -140658 900000 -89454 -11206 45404 44481 -81299 44809 18728 1177 36724 -100069 84068 -26002 12534 147688 117008 -18654 30083 49014 112654 54802 43938 -58829 43694 15582 93655 39088 30265 50211 -4988 54933 12300 33479 20898 67116 4027 39002 4854 -6086 54791 34077 1740 23909 40875 26498 -3001 -12440 32883 9734 -284 1539 8245 29914 18353 10456 8882 1381 7579 11511 17175 -5196 10223 15960 -3753 -9573 -4359 -4051 -124 2968 3289 2987 919 -1045 -2727 -1131 -4093 1567 288 -1293 -1554 -3632 -2585 1992 -597 -836 -3056 553 -3793 -1833 -394 -5068 -2761 -5066 -3480 -1513 -631 1516 858 1543 573 1013 -872 -83 -468 1998 -14 44 172 975 2705 2045 59 1399 -314 -279 -704 -928 -183 1221 188 359 22 -1558 -71 1197 375 -389 -886 -142 -33 64 -662 900000 1263 -605 -2418 900000 -571 -4066 900000 -1636 2633 -4719 900000 -3001 -215 798 782 -4416 787 389 28 645 -6075 1477 -748 240 2595 2056 -477 529 861 1980 1226 1123 -4041 1047 523 1810 1374 1305 1925 -351 2194 766 1712 1235 2831 302 2181 411 -632 3414 2831 211 2406 3526 2625 -388 -1709 2837 1104 -40 239 1330 4110 2844 1754 1589 296 1707 2685 3869 -1420 2221 2958 -767 -1988 -905 -964 -34 925 1161 1160 389 -477 -1338 -571 -2171 776 139 -599 -685 -1619 -1218 1028 -373 -613 -2612 494 -3575 -1587 -303 -3805 -2029 -4014 -2891 -1315 -592 1562 1011 2012 805 1442 -1241 -113 -631 2672 -20 66 265 1467 3842 2809 80 1827 -404 -358 -975 -1468 -329 2400 402 822 54 -4161 -196 3337 1062 -1097 -2414 -359 -77 149 SS 20200823T112913.3Z 7540.478627 57 1 50.69 2 80.71 83.37 133.57 50.75 0.00 1 0.00 1 0 17 4.641e-01 1.109e-02 2.563e-01 5.505e-03 6.909977e-01 3.159308e-03 9.025159e-03 -6.000000e+00 2.818372e-01 231.10 -2.00 3.57 -2.00 321.81 0.00e+00 1.116148e-02 1.875015e-03 7.447968e-03 -6.000000e+00 1.253513e-02 286.73 -2.00 20.00 -2.00 321.24 0.00e+00 5.885 0.004 302.00 328.00 3 1.7654e+00 1.2422e-02 7.5747e-02 -6.0000e+00 7.0407e-01 2.0594e-01 1.7482e-02 5.4236e-02 -6.0000e+00 7.6143e-01 -3.7192e-01 1.6566e-02 3.0851e-02 -6.0000e+00 4.5367e-01 1.5640e-01 7.4938e-03 1.0747e-02 -6.0000e+00 1.8849e-01 1.4765e-04 -1.6224e-04 1.7027e-04 2.6186e-04 -6.0000e+00 1.4278e-02 -1.2284e-03 0.0000e+00 12 8 8 10 0 0 -15.62 15.00 0.28 -0.00123 -0.00245 118 22 1 5 0 429.460 21.88 15.00 18.72 -120759 -112628 -62778 -134818 -152474 -207112 -74400 -210919 -162694 -186301 -24415 -153884 -18192 -30616 -65076 -69612 -2909 -33087 -59201 -44708 -68747 -43757 -61798 3085 -39692 -21269 -42360 -17650 -37466 -25987 -53805 -9167 -8462 -6762 14131 -744 -11289 3615 1783 -9674 19897 14168 13106 5063 24810 16693 30317 17250 13591 13393 5332 12997 9990 12877 11341 5828 7139 1470 1747 5202 6469 11604 12051 8495 9551 6058 5460 6737 3799 3320 3772 5529 183 -483 -2635 -590 -3970 -5068 -3620 -4317 -2961 -1491 -2916 -2368 -221 127 195 962 1094 -181 176 -1182 -1024 -2463 -1088 -2245 -65 -507 -1521 -1176 -33 -991 479 -392 -2412 -1755 -27 674 891 1344 666 707 -11 -65 -125 950 250 321 102 -496 -186 977 1266 47 -428 -910 324 1107 -339 -720 -481 -118 467 268 -83 -165 247 141 -122 -150 -282 -48 55 -766 -770 -337 -1184 -1488 -3336 -399 -3911 -1985 -3000 -131 -2253 -98 -247 -943 -1271 -31 -533 -1213 -912 -1644 -893 -1526 41 -852 -388 -955 -313 -845 -586 -1759 -256 -268 -221 372 -23 -418 136 81 -519 884 719 710 309 1283 969 1758 1086 942 1007 481 1211 1053 1414 1328 745 913 197 230 665 862 1637 1923 1563 1836 1209 1092 1394 901 893 1099 1638 56 -141 -720 -144 -959 -1289 -1030 -1464 -1160 -654 -1421 -1231 -120 73 117 591 667 -108 99 -636 -538 -1384 -681 -1656 -54 -482 -1579 -1225 -32 -880 394 -328 -2176 -1676 -27 722 1056 1776 974 1089 -17 -99 -182 1338 359 483 162 -818 -303 1523 1894 68 -611 -1261 440 1576 -549 -1323 -966 -251 1052 646 -214 -408 625 361 -309 -401 -714 -114 130 SS 20200823T114003.3Z 7540.486149 62 1 50.55 2 78.77 85.21 132.13 53.64 0.00 1 0.00 1 0 17 2.916e-01 7.447e-03 1.302e-01 2.563e-03 6.051424e-01 1.439612e-03 7.681231e-03 -6.000000e+00 1.770887e-01 231.10 -2.00 3.57 -2.00 321.33 0.00e+00 7.012740e-03 7.454838e-04 5.671633e-03 -6.000000e+00 7.876322e-03 286.73 -2.00 20.00 -2.00 320.70 0.00e+00 4.954 0.002 302.00 328.00 3 1.5959e+00 5.1467e-03 6.3351e-02 -6.0000e+00 4.4239e-01 2.6747e-02 6.9934e-03 4.5513e-02 -6.0000e+00 4.7844e-01 -1.2071e-01 6.6264e-03 2.4647e-02 -6.0000e+00 2.8506e-01 4.8503e-02 3.1030e-03 7.5900e-03 -6.0000e+00 1.1843e-01 4.6362e-04 1.6963e-04 8.1495e-05 1.5882e-04 -6.0000e+00 8.9718e-03 -1.1262e-03 0.0000e+00 11 8 0 10 0 0 7.66 15.00 0.25 -0.00113 0.00015 230 43 1 5 0 219.730 21.88 15.00 18.72 -134355 -64417 2252 -94428 -96663 -122367 -121426 -59407 -98667 -81696 -79831 -12928 -77393 -53509 -39780 -24133 -39982 -25982 -25544 -16374 -4419 -12282 -16438 -22317 -19960 -15233 -31129 -15454 -27334 -13735 -9796 -1867 -1952 -13663 -2296 -10211 -9320 -5784 -207 -3490 1760 -4183 2163 1349 4785 2518 7076 2596 4291 6202 9622 3656 7115 3318 1063 4354 327 1884 1441 1524 2346 2735 5886 4171 3413 4543 1222 2801 833 1463 -65 333 -1056 -652 -1315 -1958 -3230 -2896 -1986 -2877 -1219 -2605 -1663 -1262 158 -85 513 208 264 516 469 -618 -470 -1448 -1000 -537 174 -227 -699 -812 -496 -692 687 -445 -1784 -782 -48 999 1557 1306 967 361 317 361 147 820 449 323 -59 -452 36 926 324 -504 -464 -899 470 117 -756 -903 -604 -224 156 307 -96 -239 477 156 -201 -220 -272 -34 736 -1160 -354 7 -732 -725 -1162 -1214 -356 -962 -715 -738 -71 -1025 -722 -587 -362 -727 -455 -482 -298 -81 -246 -353 -492 -458 -346 -835 -390 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