File name: Pandora103s1_Downsview_20210109_L2Fit_fout2c10d20181123p1-8.txt File generation date: 20241101T113056.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v10d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20200901.txt Level 1 file used: Pandora103s1_Downsview_20210109_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20210109 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 201 343 Nominal wavelengths inside fitting window [nm]: 305.1310 305.2711 305.4113 305.5515 305.6916 305.8318 305.9719 306.1121 306.2522 306.3924 306.5325 306.6726 306.8128 306.9529 307.0930 307.2331 307.3733 307.5134 307.6535 307.7936 307.9337 308.0738 308.2139 308.3540 308.4941 308.6341 308.7742 308.9143 309.0544 309.1944 309.3345 309.4746 309.6146 309.7546 309.8947 310.0347 310.1748 310.3148 310.4548 310.5948 310.7348 310.8749 311.0149 311.1549 311.2948 311.4348 311.5748 311.7148 311.8548 311.9947 312.1347 312.2746 312.4146 312.5545 312.6945 312.8344 312.9743 313.1142 313.2541 313.3940 313.5339 313.6738 313.8137 313.9536 314.0935 314.2333 314.3732 314.5131 314.6529 314.7927 314.9326 315.0724 315.2122 315.3520 315.4918 315.6316 315.7714 315.9112 316.0510 316.1908 316.3305 316.4703 316.6100 316.7498 316.8895 317.0292 317.1689 317.3086 317.4483 317.5880 317.7277 317.8674 318.0071 318.1467 318.2864 318.4260 318.5657 318.7053 318.8449 318.9845 319.1242 319.2638 319.4033 319.5429 319.6825 319.8221 319.9616 320.1012 320.2407 320.3802 320.5198 320.6593 320.7988 320.9383 321.0778 321.2172 321.3567 321.4962 321.6356 321.7751 321.9145 322.0539 322.1933 322.3327 322.4721 322.6115 322.7509 322.8903 323.0296 323.1690 323.3083 323.4477 323.5870 323.7263 323.8656 324.0049 324.1442 324.2834 324.4227 324.5620 324.7012 324.8404 324.9797 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210109T135626.1Z 7679.580857 177 1 50.17 2 81.31 132.20 63.56 179.09 0.00 1 0.00 1 0 17 4.776e-01 1.796e-02 3.234e-01 1.015e-02 7.944417e-01 5.820892e-03 9.333897e-03 -6.000000e+00 2.842862e-01 223.16 -2.00 3.57 -2.00 321.94 0.00e+00 2.188555e-02 3.036192e-03 1.335669e-03 -6.000000e+00 1.281665e-02 272.16 -2.00 20.00 -2.00 321.51 0.00e+00 6.256 0.005 302.00 328.00 3 2.2566e+00 2.0176e-02 7.8645e-02 -6.0000e+00 7.0006e-01 6.1899e-01 2.7697e-02 6.1028e-02 -6.0000e+00 7.6553e-01 -7.7810e-01 2.8598e-02 2.3910e-02 -6.0000e+00 4.5143e-01 3.2217e-01 1.3444e-02 2.1115e-02 -6.0000e+00 1.8912e-01 5.0802e-05 -2.2577e-03 3.0710e-04 2.9237e-04 -6.0000e+00 1.5077e-02 2.9469e-03 0.0000e+00 12 8 8 10 0 0 79.94 15.00 0.26 0.00295 -0.01402 41 8 1 5 0 1223.420 21.58 15.00 18.34 900000 -148536 900000 -213330 900000 -198671 900000 -190634 15685 41895 -157148 -91476 -54966 -89701 51914 -14272 9308 -58271 -50694 43694 -70859 -44745 -70065 33412 -57631 23449 -79960 -1770 -72162 138364 -42524 107537 -11912 75501 3346 96582 6286 31612 13416 2097 49430 29575 60432 24666 59321 11210 55862 11953 10118 4301 31923 24102 40493 17605 23935 13740 23014 333 20550 31099 15841 1866 19232 12522 11330 20765 18369 12344 4861 12020 7168 4690 -26 6950 -3919 4821 -3235 7082 -8966 2212 484 -206 -301 -5879 -900 212 -3031 -4480 1326 624 691 -4659 -177 -5812 -1138 -4447 -835 -1494 -1330 -1500 -56 1017 111 219 -1613 -2790 -755 682 734 360 -2 -251 -534 -343 -788 894 -156 1259 -44 -382 762 2702 1181 673 -468 345 577 576 -12 -404 148 155 883 908 134 -359 172 -551 -92 -1017 -18 192 -380 900000 -2940 900000 -7339 900000 -4918 900000 -4182 155 414 -2673 -1039 -606 -1860 514 -223 133 -1703 -1451 523 -2411 -1141 -2179 386 -1536 288 -2558 -28 -2417 1369 -1590 1200 -455 1309 110 1318 213 960 548 105 1729 1324 2140 1269 2303 712 2470 843 776 377 2381 2127 3308 1872 2462 1566 2379 42 2079 2880 1805 273 2728 2111 2046 3462 3154 2369 1109 2848 1901 1295 -7 1690 -962 999 -705 1496 -2557 676 176 -85 -135 -2961 -456 112 -1723 -2632 729 333 349 -2358 -85 -3172 -681 -3235 -685 -1397 -1339 -1519 -52 848 87 171 -1350 -2503 -706 683 821 457 -3 -374 -809 -507 -1131 1241 -222 1851 -68 -607 1177 3931 1678 935 -639 454 759 814 -19 -739 295 330 1988 2172 340 -953 463 -1498 -246 -2634 -43 435 -853 SS 20210109T141246.3Z 7679.592202 183 1 50.58 2 79.18 135.37 63.67 183.27 0.00 1 0.00 1 0 25 3.809e-01 8.422e-03 3.107e-01 5.543e-03 6.861732e-01 3.081548e-03 8.004493e-03 -6.000000e+00 2.252863e-01 223.16 -2.00 3.57 -2.00 321.47 0.00e+00 1.153979e-02 1.476202e-03 1.627364e-03 -6.000000e+00 9.756510e-03 272.16 -2.00 20.00 -2.00 321.02 0.00e+00 5.134 0.003 302.00 328.00 3 2.6777e+00 1.0102e-02 6.1893e-02 -6.0000e+00 5.5486e-01 1.8568e-01 1.4321e-02 3.8154e-02 -6.0000e+00 6.0589e-01 -1.8644e-01 1.5866e-02 2.4568e-02 -6.0000e+00 3.5892e-01 6.8388e-02 7.5602e-03 1.5033e-02 -6.0000e+00 1.4878e-01 1.1426e-04 -1.3871e-03 1.7108e-04 1.9425e-04 -6.0000e+00 1.1741e-02 2.0255e-03 0.0000e+00 11 8 0 10 0 0 84.21 15.00 0.21 0.00203 -0.00840 51 9 1 5 0 991.500 21.58 15.00 18.32 -89976 62488 -143107 255691 -82373 900000 -95080 -3423 -88788 -64534 -108568 -109638 127230 -93438 23881 -37137 59613 -59011 8624 2598 -21545 -36786 4759 -70094 -9627 -22691 -7555 -35636 -35818 -16143 12382 -5267 -10220 -14943 20312 -8788 -4978 -5295 3321 5653 2534 -7069 -3830 2731 -473 4295 9862 -725 2434 7693 18173 1263 4613 4154 6437 1519 -2138 -4170 561 1570 6173 128 8011 3477 5833 1541 4511 53 3121 3394 -420 465 -647 -2574 -5453 -2616 -838 -2674 -2685 -973 -1084 -854 -1203 -653 -509 1326 -628 -192 -370 -697 572 278 -1666 -468 324 -277 309 -427 -224 -380 -1282 43 2596 453 -2538 -1356 -294 392 1175 731 219 31 -20 -50 654 1425 772 552 -234 -741 202 817 49 -373 -532 -279 362 935 -840 -197 -913 -172 370 10 -106 -346 682 -419 -617 22 -43 540 471 -486 338 -1294 1382 -445 900000 -525 -19 -534 -349 -917 -1144 688 -1452 156 -510 378 -1247 105 35 -366 -722 65 -2004 -164 -447 -130 -816 -876 -377 269 -161 -368 -583 567 -327 -198 -249 169 321 163 -536 -297 207 -38 347 791 -68 235 768 1819 165 635 613 971 247 -363 -716 91 255 1020 25 1647 825 1417 390 1112 15 916 1111 -154 173 -237 -903 -1805 -775 -236 -806 -923 -387 -500 -441 -678 -389 -321 868 -438 -136 -259 -472 362 167 -1006 -295 229 -228 289 -450 -251 -425 -1352 41 2273 409 -2480 -1386 -315 448 1467 1016 332 49 -33 -77 962 2036 1123 838 -373 -1215 325 1261 73 -546 -757 -383 493 1341 -1361 -354 -1788 -354 796 23 -255 -867 1726 -1077 -1572 53 -101 1192 1030 SS 20210109T141906.2Z 7679.596600 186 1 50.49 2 78.39 136.63 63.76 184.89 0.00 1 0.00 1 0 17 2.686e-01 7.469e-03 2.016e-01 3.210e-03 6.494805e-01 1.761427e-03 7.515312e-03 -6.000000e+00 1.578518e-01 223.16 -2.00 3.57 -2.00 321.28 0.00e+00 9.944727e-03 8.064758e-04 1.284914e-03 -6.000000e+00 6.828107e-03 272.16 -2.00 20.00 -2.00 320.82 0.00e+00 4.810 0.002 302.00 328.00 3 2.1831e+00 5.6463e-03 5.8062e-02 -6.0000e+00 3.8894e-01 1.2884e-01 7.7933e-03 3.5677e-02 -6.0000e+00 4.2455e-01 -1.3522e-01 8.4822e-03 2.2432e-02 -6.0000e+00 2.5230e-01 4.8265e-02 4.0883e-03 1.3320e-02 -6.0000e+00 1.0492e-01 2.6766e-04 -1.1915e-03 9.9802e-05 1.6335e-04 -6.0000e+00 8.2544e-03 2.1531e-03 0.0000e+00 11 9 0 11 8 0 87.16 15.00 0.16 0.00215 -0.00680 109 20 1 5 0 463.060 21.58 15.00 18.33 -172184 -63705 -2221 30562 -97101 4262 -84494 -86387 -101281 -79109 -82025 -31833 -36213 -70738 -10825 -27810 19763 -37143 7362 -10871 41371 -23611 11341 -23459 1698 -26370 354 -37261 -3113 -6221 -4068 1849 8958 -7121 -5388 7392 -4220 2530 -5391 1646 -4053 8430 -2395 3126 -298 6688 1384 8693 5809 10448 3676 7563 5382 4247 2411 2499 2 -3208 -900 -1825 5005 2898 3907 -325 2210 1526 2751 2537 3796 -695 1278 -1909 -1035 -2986 -2893 -3169 -820 -2553 -945 128 -1204 -1087 -2111 -988 -480 -265 -87 32 -308 369 416 443 -725 489 -881 226 111 253 -805 -557 -385 237 1507 504 -1735 -1301 -230 390 1561 594 277 0 288 113 729 879 985 577 -187 -823 130 633 -30 -651 -665 -758 783 849 -752 -605 -616 -117 38 323 -447 -258 261 137 -611 171 -268 540 580 -2171 -333 -7 96 -665 13 -546 -620 -892 -599 -702 -207 -318 -1105 -121 -427 222 -772 109 -199 476 -497 178 -533 32 -661 7 -1059 -68 -159 -122 62 315 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