File name: Pandora103s1_Downsview_20210207_L2Fit_fout2c10d20181123p1-8.txt File generation date: 20241101T115526.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v10d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20200901.txt Level 1 file used: Pandora103s1_Downsview_20210207_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20210207 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 201 343 Nominal wavelengths inside fitting window [nm]: 305.1310 305.2711 305.4113 305.5515 305.6916 305.8318 305.9719 306.1121 306.2522 306.3924 306.5325 306.6726 306.8128 306.9529 307.0930 307.2331 307.3733 307.5134 307.6535 307.7936 307.9337 308.0738 308.2139 308.3540 308.4941 308.6341 308.7742 308.9143 309.0544 309.1944 309.3345 309.4746 309.6146 309.7546 309.8947 310.0347 310.1748 310.3148 310.4548 310.5948 310.7348 310.8749 311.0149 311.1549 311.2948 311.4348 311.5748 311.7148 311.8548 311.9947 312.1347 312.2746 312.4146 312.5545 312.6945 312.8344 312.9743 313.1142 313.2541 313.3940 313.5339 313.6738 313.8137 313.9536 314.0935 314.2333 314.3732 314.5131 314.6529 314.7927 314.9326 315.0724 315.2122 315.3520 315.4918 315.6316 315.7714 315.9112 316.0510 316.1908 316.3305 316.4703 316.6100 316.7498 316.8895 317.0292 317.1689 317.3086 317.4483 317.5880 317.7277 317.8674 318.0071 318.1467 318.2864 318.4260 318.5657 318.7053 318.8449 318.9845 319.1242 319.2638 319.4033 319.5429 319.6825 319.8221 319.9616 320.1012 320.2407 320.3802 320.5198 320.6593 320.7988 320.9383 321.0778 321.2172 321.3567 321.4962 321.6356 321.7751 321.9145 322.0539 322.1933 322.3327 322.4721 322.6115 322.7509 322.8903 323.0296 323.1690 323.3083 323.4477 323.5870 323.7263 323.8656 324.0049 324.1442 324.2834 324.4227 324.5620 324.7012 324.8404 324.9797 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210207T134713.7Z 7708.574464 163 1 21.41 2 78.04 124.92 68.74 179.75 0.00 1 0.00 1 0 25 5.639e-01 1.522e-02 3.266e-01 8.404e-03 8.043664e-01 4.713685e-03 9.094793e-03 -6.000000e+00 3.327986e-01 224.32 -2.00 3.57 -2.00 321.56 0.00e+00 1.175327e-02 2.271733e-03 1.278066e-03 -6.000000e+00 1.495922e-02 271.77 -2.00 20.00 -2.00 321.12 0.00e+00 4.681 0.002 302.00 328.00 3 3.3344e+00 1.5473e-02 6.3126e-02 -6.0000e+00 8.2210e-01 3.4964e-01 2.2149e-02 4.5488e-02 -6.0000e+00 8.9688e-01 -4.3976e-01 2.4104e-02 2.6273e-02 -6.0000e+00 5.3243e-01 1.7914e-01 1.1374e-02 1.4947e-02 -6.0000e+00 2.2123e-01 7.5271e-05 -1.4643e-03 2.4096e-04 1.9479e-04 -6.0000e+00 1.7385e-02 3.9798e-03 0.0000e+00 12 9 9 12 1 1 99.92 14.99 0.08 0.00398 -0.00702 12 6 1 5 0 1633.080 21.38 14.99 18.09 -181550 -194640 -2641 -145573 -140031 -142544 -221382 -257674 -137323 -211569 900000 -151929 -58339 -129029 -60522 -104419 -24478 -10341 110811 -28189 -56808 54811 -40401 42947 -89985 91772 -78385 21736 -35707 20631 -15235 33296 -21561 42048 10711 34617 -17576 6506 15883 10895 15416 5257 31801 25983 20281 14721 23913 25942 19789 13698 19091 993 20184 2306 21308 10801 1651 -3574 -3691 9078 9445 6191 9705 5550 7202 9337 9688 8472 11600 3671 699 2096 -581 46 -5092 1470 -3740 -1459 -1826 -43 -1729 -440 -1090 -1427 -1195 1089 -621 1233 542 -2309 -244 -2267 -1836 -2285 -1297 -2732 1072 -1184 -1542 -1780 63 -531 2058 -229 -2880 -1797 613 344 497 667 -622 477 285 -216 930 1348 178 -325 -178 -191 -387 1725 373 158 -17 205 1231 1769 -160 -282 -752 205 532 -237 -66 -416 1545 -151 -900 -619 32 26 -186 -2116 -2868 -22 -1364 -1173 -1194 -3915 -6743 -1280 -4022 900000 -2300 -504 -2759 -876 -2659 -345 -141 908 -493 -1286 453 -799 418 -2998 752 -2389 275 -810 327 -409 692 -826 935 312 822 -737 256 670 545 813 326 1619 1444 1226 974 1524 1723 1496 1199 1768 121 2247 324 2617 1504 252 -563 -570 1246 1370 1037 1792 1187 1602 2057 2156 2031 3013 1146 241 725 -200 15 -1554 388 -1010 -412 -596 -16 -778 -220 -597 -832 -732 686 -414 819 357 -1504 -148 -1338 -1077 -1444 -924 -2289 997 -1256 -1750 -2020 66 -507 1798 -205 -2762 -1799 635 385 614 918 -944 752 455 -339 1397 1982 268 -509 -289 -313 -624 2627 554 229 -24 280 1672 2550 -261 -516 -1497 429 1169 -553 -160 -1049 3891 -385 -2283 -1511 73 57 -400 SS 20210207T135337.4Z 7708.578905 166 1 50.70 2 77.10 126.17 68.75 181.27 0.00 1 0.00 1 0 25 4.704e-01 8.600e-03 1.393e-01 1.669e-03 7.707429e-01 9.377675e-04 8.595200e-03 -6.000000e+00 2.775547e-01 224.32 -2.00 3.57 -2.00 321.51 0.00e+00 1.092394e-02 4.549241e-04 9.769006e-04 -6.000000e+00 1.193640e-02 271.77 -2.00 20.00 -2.00 321.06 0.00e+00 4.364 0.002 302.00 328.00 3 1.2807e+00 3.0975e-03 6.0570e-02 -6.0000e+00 6.8573e-01 1.3302e-01 4.5801e-03 4.5828e-02 -6.0000e+00 7.4802e-01 -1.7334e-01 5.2402e-03 2.4919e-02 -6.0000e+00 4.4404e-01 6.5993e-02 2.4584e-03 1.4560e-02 -6.0000e+00 1.8412e-01 8.5669e-04 -1.1154e-03 4.9037e-05 1.7240e-04 -6.0000e+00 1.4458e-02 3.4186e-03 0.0000e+00 11 8 0 10 0 0 94.23 15.00 0.19 0.00342 -0.00496 374 70 1 5 0 135.170 21.48 15.00 18.10 -142598 -167329 -146243 -174803 -186391 -160039 -188039 35323 -163130 -54502 -166227 -48352 -122278 -43774 -83612 -29557 -46468 501 -46832 -26054 -51653 -18455 -38396 -16777 -39165 -43543 -35096 -45012 -29235 -17705 -1610 -19507 -952 -10645 3961 -7868 2524 -13165 655 -5728 -720 -5741 6020 1930 6935 1522 7329 10099 10468 7172 6444 9572 7778 6308 3064 3284 -1979 -594 -2066 5702 4048 6507 4042 4932 3524 4305 2253 4442 3920 398 -61 -997 -1106 -1597 -1377 -1902 -1095 -2108 -786 -1466 -373 -2402 -1808 -1388 -516 -385 -342 -365 -230 -351 373 -346 -294 245 -593 54 299 84 -1035 -305 -355 1266 1773 303 -2475 -1044 -491 935 982 852 -299 -159 -123 170 919 1585 1102 461 -625 -1226 63 773 317 -716 -646 -696 1465 843 -606 -768 -407 189 649 290 -414 -289 410 -289 -836 -306 -71 654 704 -570 -990 -736 -1138 -1296 -853 -1419 57 -1135 -151 -1451 -181 -1194 -266 -977 -245 -529 4 -651 -308 -803 -208 -545 -204 -626 -747 -561 -819 -493 -314 -30 -543 -25 -323 103 -236 77 -559 29 -286 -38 -346 341 119 422 102 491 703 785 613 623 1008 918 812 428 473 -303 -89 -307 790 609 1078 787 1063 815 996 539 1110 1107 131 -22 -365 -394 -532 -416 -529 -294 -610 -260 -582 -171 -1275 -1042 -849 -331 -261 -241 -262 -162 -238 236 -209 -177 157 -439 47 275 87 -1168 -340 -367 1157 1629 284 -2509 -1020 -506 1030 1208 1182 -462 -257 -201 269 1382 2311 1636 718 -1027 -2057 102 1186 468 -1034 -901 -937 1929 1198 -991 -1426 -825 407 1375 658 -1000 -727 1041 -742 -2120 -739 -159 1476 1569 SS 20210207T135954.3Z 7708.583268 169 1 50.64 2 76.19 127.42 68.80 182.75 0.00 1 0.00 1 0 25 3.827e-01 8.257e-03 7.740e-02 1.360e-03 7.287493e-01 7.580566e-04 8.242013e-03 -6.000000e+00 2.257895e-01 224.32 -2.00 3.57 -2.00 321.34 0.00e+00 1.083177e-02 3.522878e-04 8.356005e-04 -6.000000e+00 9.710129e-03 271.77 -2.00 20.00 -2.00 320.89 0.00e+00 4.095 0.001 302.00 328.00 3 1.2545e+00 2.4410e-03 5.6510e-02 -6.0000e+00 5.5784e-01 1.1439e-01 3.4922e-03 4.1892e-02 -6.0000e+00 6.0851e-01 -1.4113e-01 3.9197e-03 2.4225e-02 -6.0000e+00 3.6123e-01 5.0853e-02 1.8646e-03 1.4656e-02 -6.0000e+00 1.4978e-01 1.1743e-03 -9.8995e-04 4.0288e-05 1.6832e-04 -6.0000e+00 1.1761e-02 3.3257e-03 0.0000e+00 11 8 0 10 0 0 96.19 15.00 0.13 0.00333 -0.00411 444 83 1 5 0 113.780 21.48 15.00 18.10 -160132 -97896 -125735 -83809 -138017 -104818 -113911 -120400 -124991 -125644 -125078 -105419 -95167 -75608 -20065 -49800 -9394 -32296 4945 -18073 3487 -18262 -24691 -31978 -22194 -27663 -27172 -24429 -26150 -15070 -4188 2345 -8627 -951 -6007 2097 -2223 3723 -5393 -67 -2335 -2046 -3253 4164 1225 5653 5946 5483 6213 7687 7612 6281 6522 3952 3795 -149 -1084 -2794 1560 794 3807 3198 5120 2118 3408 3618 3913 3481 3279 90 -184 -1480 -1626 -2270 -2140 -1531 -2205 -531 -965 -598 -1192 -1692 -2180 -703 -677 -522 -606 -267 -155 172 450 -72 444 340 40 -6 668 -150 -946 -781 -38 801 1984 141 -2385 -1316 -276 663 1268 544 36 -211 51 198 940 1631 1141 486 -778 -972 -188 674 34 -424 -752 -574 1343 1049 -786 -708 -623 204 471 400 -503 -309 456 -280 -708 -315 -65 550 805 -1062 -442 -784 -334 -897 -487 -620 -767 -895 -967 -1079 -937 -941 -830 -178 -655 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