File name: Pandora103s1_Downsview_20210314_L2Fit_fout2c10d20181123p1-8.txt File generation date: 20241101T122254.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v10d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20200901.txt Level 1 file used: Pandora103s1_Downsview_20210314_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20210314 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 201 343 Nominal wavelengths inside fitting window [nm]: 305.1310 305.2711 305.4113 305.5515 305.6916 305.8318 305.9719 306.1121 306.2522 306.3924 306.5325 306.6726 306.8128 306.9529 307.0930 307.2331 307.3733 307.5134 307.6535 307.7936 307.9337 308.0738 308.2139 308.3540 308.4941 308.6341 308.7742 308.9143 309.0544 309.1944 309.3345 309.4746 309.6146 309.7546 309.8947 310.0347 310.1748 310.3148 310.4548 310.5948 310.7348 310.8749 311.0149 311.1549 311.2948 311.4348 311.5748 311.7148 311.8548 311.9947 312.1347 312.2746 312.4146 312.5545 312.6945 312.8344 312.9743 313.1142 313.2541 313.3940 313.5339 313.6738 313.8137 313.9536 314.0935 314.2333 314.3732 314.5131 314.6529 314.7927 314.9326 315.0724 315.2122 315.3520 315.4918 315.6316 315.7714 315.9112 316.0510 316.1908 316.3305 316.4703 316.6100 316.7498 316.8895 317.0292 317.1689 317.3086 317.4483 317.5880 317.7277 317.8674 318.0071 318.1467 318.2864 318.4260 318.5657 318.7053 318.8449 318.9845 319.1242 319.2638 319.4033 319.5429 319.6825 319.8221 319.9616 320.1012 320.2407 320.3802 320.5198 320.6593 320.7988 320.9383 321.0778 321.2172 321.3567 321.4962 321.6356 321.7751 321.9145 322.0539 322.1933 322.3327 322.4721 322.6115 322.7509 322.8903 323.0296 323.1690 323.3083 323.4477 323.5870 323.7263 323.8656 324.0049 324.1442 324.2834 324.4227 324.5620 324.7012 324.8404 324.9797 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210314T120425.6Z 7743.503074 42 1 49.25 2 84.89 98.18 94.77 88.69 0.00 1 0.00 1 0 17 6.593e-01 8.112e-02 4.761e-01 7.150e-02 1.096913e+00 4.220427e-02 1.226301e-02 -6.000000e+00 3.933756e-01 225.72 -2.00 3.57 -2.00 321.56 0.00e+00 -2.169751e-02 1.151141e-02 8.041504e-03 -6.000000e+00 1.808831e-02 273.80 -2.00 20.00 -2.00 320.90 0.00e+00 9.685 0.018 302.00 328.00 3 4.6175e-01 1.2426e-01 1.2632e-01 -6.0000e+00 9.7296e-01 2.6610e+00 1.4458e-01 1.0601e-01 -6.0000e+00 1.0605e+00 -2.3339e+00 8.8734e-02 3.1373e-02 -6.0000e+00 6.3038e-01 7.0248e-01 4.8840e-02 1.8909e-02 -6.0000e+00 2.6353e-01 5.6803e-06 -1.0078e-03 1.8543e-03 1.8878e-04 -6.0000e+00 2.0664e-02 -2.7218e-03 0.0000e+00 12 8 8 10 0 0 33.18 15.00 1.17 -0.00272 -0.01030 17 3 1 5 0 2896.210 21.69 15.00 18.45 9367 900000 180337 900000 4803 21819 38531 136538 55119 -23149 20188 19960 183130 121310 900000 24164 128946 7646 257894 -7096 900000 22386 900000 -39781 900000 -12632 201654 -47506 900000 -53932 -56725 -49848 256 -38182 7762 -11661 -43479 38586 -28322 125508 -12726 101443 43767 223693 -37476 177357 -13824 81899 6980 92783 -23449 341004 128648 49883 812 28883 24318 71057 54225 102424 24569 16333 -2980 8515 91678 -8109 62887 -37916 9242 2331 11655 8688 30066 -5364 -15111 -34568 17488 12040 -21635 17451 27659 32821 41901 18147 3598 12657 -2113 6721 -33183 21394 -10922 -1724 -15193 12527 -8521 42567 14706 7371 -4285 -3432 11830 -19453 -7854 -2962 27 -13081 8208 -3658 7545 -6678 11165 -1519 13091 7876 1344 -2809 -4145 -3050 2033 -651 11103 11168 2189 -2299 -14103 -7467 1676 5595 -584 4882 -6393 1209 -2286 1665 -4174 1456 2002 -3151 406 1315 -1054 5306 745 1522 900000 12557 900000 446 1646 2683 9507 3838 -3627 2109 2201 12752 8447 900000 3518 8979 1258 17958 -1168 900000 2409 900000 -9317 900000 -2319 14042 -9322 900000 -10242 -12209 -11044 36 -7493 884 -1550 -8532 3908 -6634 8739 -3061 7706 5541 15576 -8777 12350 -2275 5703 972 6461 -5195 23745 8958 7294 185 5119 4464 8411 6796 7132 3593 2729 -664 1838 8937 -2146 8320 -13441 2510 747 3571 2722 7118 -1606 -4314 -10591 3044 2347 -6779 4374 7318 9370 11962 6950 1654 5464 -1074 3089 -21720 7598 -5019 -696 -7194 4972 -4866 17191 9114 5543 -3879 -3059 8320 -16526 -5414 -1918 18 -10293 5544 -3057 6462 -7673 12205 -2052 15861 10035 1787 -3833 -5802 -4374 2859 -938 13607 12831 2621 -2802 -18855 -9099 1891 6700 -875 8125 -13489 2600 -5556 4232 -12061 4156 5785 -9565 1163 3526 -2656 11602 1676 SS 20210314T121655.4Z 7743.511752 45 1 50.78 2 82.66 100.38 92.55 90.76 0.00 1 0.00 1 0 17 5.790e-01 2.280e-02 3.416e-01 1.048e-02 9.773343e-01 6.316417e-03 1.055566e-02 -6.000000e+00 3.469985e-01 225.72 -2.00 3.57 -2.00 322.45 0.00e+00 1.589166e-02 3.653316e-03 4.319201e-03 -6.000000e+00 1.639577e-02 273.80 -2.00 20.00 -2.00 322.03 0.00e+00 7.243 0.007 302.00 328.00 3 9.3653e-01 2.4025e-02 9.7418e-02 -6.0000e+00 8.5869e-01 1.1748e+00 3.2198e-02 8.0661e-02 -6.0000e+00 9.3596e-01 -1.6077e+00 2.9993e-02 3.0831e-02 -6.0000e+00 5.5327e-01 6.5454e-01 1.4057e-02 1.5098e-02 -6.0000e+00 2.2972e-01 6.0999e-05 -2.4146e-03 3.0110e-04 2.0624e-04 -6.0000e+00 1.8479e-02 -4.5003e-03 0.0000e+00 12 8 8 10 0 0 9.11 15.00 0.34 -0.00450 -0.02264 96 18 1 5 0 528.870 21.69 15.00 18.46 -95462 76908 -53808 900000 -133088 900000 -105504 243242 -171842 900000 -95712 113912 -127806 900000 44783 38799 -70700 93262 18864 1408 -11170 -29391 163770 -33313 59176 -60996 900000 -76123 900000 -68365 81927 -17053 95126 -1745 92237 1298 262478 76560 153044 69638 18271 57504 84864 38653 31701 44838 22427 65750 14226 79568 38457 100161 15517 94677 10648 50186 21823 49933 12419 61563 30723 38914 30556 17725 39377 16155 44586 25812 44738 8888 31058 1534 21681 844 12105 -9168 17887 -14044 9992 -2879 10251 -1362 3591 -2546 4713 2720 5425 -69 -1619 -548 -4940 1151 -6131 3112 -9755 1099 -4428 1571 -5159 114 -4943 197 -3390 727 -5237 -2164 -2053 -766 823 -775 218 -2118 -1014 -208 344 -695 -553 -2013 2167 -413 2509 2081 3812 365 1564 -940 2079 1241 -21 -731 400 681 469 601 -428 284 575 538 -1156 228 -772 -170 -1261 -2831 785 -1099 900000 -4378 900000 -2225 2484 -6345 900000 -1747 1163 -4950 900000 543 579 -3281 955 400 34 -287 -834 1672 -910 647 -2018 900000 -2737 900000 -2788 986 -637 1346 -63 1283 41 2680 1405 1563 1706 777 1766 2059 1467 1296 1656 1061 2184 821 2702 2115 3392 1254 3833 974 3192 1780 3013 1019 3126 2164 2820 2732 2008 3896 2027 4380 3213 5181 1600 4839 319 3585 156 1807 -1524 2252 -2578 1710 -670 2486 -421 1160 -929 1686 1040 2100 -28 -672 -217 -1936 410 -2366 1203 -4971 605 -3029 1165 -4459 95 -4053 138 -2259 461 -3671 -1567 -1587 -642 772 -852 268 -2887 -1415 -287 463 -934 -756 -2923 3154 -625 3592 2848 4916 474 1965 -1179 2557 1674 -34 -1345 815 1504 1118 1537 -1173 805 1652 1550 -3320 617 -1963 -400 -2919 SS 20210314T122726.3Z 7743.519055 48 1 50.62 2 80.80 102.25 90.68 92.50 0.00 1 0.00 1 0 25 5.991e-01 1.282e-02 2.612e-01 4.210e-03 8.598422e-01 2.448481e-03 9.708365e-03 -6.000000e+00 3.580834e-01 225.72 -2.00 3.57 -2.00 322.07 0.00e+00 1.462076e-02 1.383334e-03 1.958995e-03 -6.000000e+00 1.568720e-02 273.80 -2.00 20.00 -2.00 321.64 0.00e+00 5.943 0.004 302.00 328.00 3 1.0735e+00 8.9645e-03 7.5557e-02 -6.0000e+00 8.8748e-01 3.9691e-01 1.3909e-02 5.2338e-02 -6.0000e+00 9.6802e-01 -5.8772e-01 1.5502e-02 2.9312e-02 -6.0000e+00 5.7377e-01 2.4584e-01 7.0069e-03 1.6918e-02 -6.0000e+00 2.3686e-01 2.2328e-04 -1.5612e-03 1.2352e-04 2.6775e-04 -6.0000e+00 1.8485e-02 -5.0542e-03 0.0000e+00 12 8 8 10 0 0 26.79 15.00 0.23 -0.00505 -0.01679 190 35 1 5 0 266.370 21.69 15.00 18.47 -191745 -137442 -8804 -152369 900000 -171222 -219111 -233613 -117020 -228815 -57126 -238141 -14662 -180701 900000 -135890 66865 -87707 900000 -88186 1900 -103193 529 -77239 -65886 -89772 -76153 -36001 -58323 -40715 -25290 -1577 -13695 39361 -51861 76058 -25990 66004 -13746 52794 -13223 36490 -1803 21725 5151 29096 13897 19426 15392 15572 31089 9548 29386 14381 19826 12156 20252 -1441 23018 2812 15121 3942 20260 7892 12936 7319 15703 5009 14774 6242 4705 6676 2294 588 8 -1094 -5804 1032 -5090 1931 -1539 2545 -2098 1815 -2017 1091 -1757 1090 -1377 735 -511 100 -3440 -1561 -1198 -1818 -593 -530 -614 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