File name: Pandora103s1_Downsview_20210411_L2Fit_fout2c10d20181123p1-8.txt File generation date: 20241101T125310.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v10d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20200901.txt Level 1 file used: Pandora103s1_Downsview_20210411_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20210411 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 201 343 Nominal wavelengths inside fitting window [nm]: 305.1310 305.2711 305.4113 305.5515 305.6916 305.8318 305.9719 306.1121 306.2522 306.3924 306.5325 306.6726 306.8128 306.9529 307.0930 307.2331 307.3733 307.5134 307.6535 307.7936 307.9337 308.0738 308.2139 308.3540 308.4941 308.6341 308.7742 308.9143 309.0544 309.1944 309.3345 309.4746 309.6146 309.7546 309.8947 310.0347 310.1748 310.3148 310.4548 310.5948 310.7348 310.8749 311.0149 311.1549 311.2948 311.4348 311.5748 311.7148 311.8548 311.9947 312.1347 312.2746 312.4146 312.5545 312.6945 312.8344 312.9743 313.1142 313.2541 313.3940 313.5339 313.6738 313.8137 313.9536 314.0935 314.2333 314.3732 314.5131 314.6529 314.7927 314.9326 315.0724 315.2122 315.3520 315.4918 315.6316 315.7714 315.9112 316.0510 316.1908 316.3305 316.4703 316.6100 316.7498 316.8895 317.0292 317.1689 317.3086 317.4483 317.5880 317.7277 317.8674 318.0071 318.1467 318.2864 318.4260 318.5657 318.7053 318.8449 318.9845 319.1242 319.2638 319.4033 319.5429 319.6825 319.8221 319.9616 320.1012 320.2407 320.3802 320.5198 320.6593 320.7988 320.9383 321.0778 321.2172 321.3567 321.4962 321.6356 321.7751 321.9145 322.0539 322.1933 322.3327 322.4721 322.6115 322.7509 322.8903 323.0296 323.1690 323.3083 323.4477 323.5870 323.7263 323.8656 324.0049 324.1442 324.2834 324.4227 324.5620 324.7012 324.8404 324.9797 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210411T180448.6Z 7771.753341 264 1 51.28 2 36.59 199.31 42.81 200.42 0.00 1 0.00 1 0 17 1.233e-02 7.898e-03 6.175e-03 2.687e-03 1.958869e-01 1.408880e-03 2.366835e-03 -6.000000e+00 7.386859e-03 227.85 -2.00 3.57 -2.00 316.72 0.00e+00 7.625598e-04 1.706838e-04 1.736272e-04 -6.000000e+00 3.195739e-04 276.95 -2.00 20.00 -2.00 316.09 0.00e+00 1.244 0.000 302.00 328.00 3 6.0922e+00 3.6797e-03 1.5886e-02 -6.0000e+00 1.8369e-02 4.4176e-02 4.1191e-03 1.0047e-02 -6.0000e+00 1.9952e-02 -1.0045e-02 2.3903e-03 4.9454e-03 -6.0000e+00 1.1847e-02 2.2227e-04 1.1005e-03 1.4212e-03 -6.0000e+00 4.9134e-03 2.8207e-04 -7.4482e-04 8.6871e-05 1.8061e-05 -6.0000e+00 3.7902e-04 -1.4401e-02 0.0000e+00 11 8 0 10 0 0 99.91 15.00 0.18 -0.01440 -0.02000 21 4 1 5 0 2441.660 21.98 15.00 18.88 -1174 614 -3364 -1921 921 2599 -1238 248 -4810 -2340 -3149 -2350 -440 737 432 -663 562 1090 1773 809 382 879 1672 1576 777 -1897 -2211 -3078 -658 1216 1491 914 -165 -3982 -1961 -1118 569 1138 799 -407 23 171 -661 -233 975 98 -903 -613 -713 378 857 1016 1060 754 1099 956 542 638 555 1145 1466 2223 1757 233 -631 -29 -357 32 1166 -234 -79 -64 -56 -91 -1232 -2040 -1920 -1779 -2012 -2635 -1913 -2121 -1935 -604 311 513 771 668 726 322 477 -156 -423 -323 -451 -300 80 233 -100 -303 -539 -738 436 -210 -1326 -806 -137 608 1192 1162 1128 814 652 306 109 249 93 347 -259 -484 -63 599 139 175 -113 -500 170 -231 -793 -1249 -919 -565 -41 277 -142 42 586 495 -194 276 -143 -159 -69 -207 111 -622 -326 140 378 -199 44 -953 -461 -626 -482 -97 181 117 -193 167 332 552 260 125 286 548 539 280 -710 -808 -1079 -214 382 485 319 -61 -1514 -707 -400 218 504 412 -237 14 110 -438 -154 639 64 -584 -384 -439 232 543 677 739 544 809 717 411 481 416 856 1129 1803 1516 210 -564 -24 -280 25 942 -209 -75 -63 -55 -86 -1113 -1705 -1476 -1317 -1546 -2221 -1755 -2098 -2016 -652 351 612 960 849 918 396 554 -168 -425 -318 -461 -330 94 295 -131 -396 -672 -868 497 -248 -1666 -1059 -186 849 1721 1748 1746 1264 980 435 145 318 119 456 -360 -708 -94 884 201 246 -154 -651 213 -291 -1044 -1732 -1313 -818 -60 418 -224 69 979 838 -331 465 -235 -255 -111 SS 20210411T182028.4Z 7771.764217 273 1 30.70 2 37.66 205.48 43.85 205.82 0.00 1 0.00 1 0 17 1.231e-02 7.752e-03 6.381e-03 3.002e-03 1.941031e-01 1.578222e-03 2.350677e-03 -6.000000e+00 7.380338e-03 227.85 -2.00 3.57 -2.00 316.44 0.00e+00 8.253572e-04 1.796546e-04 1.346714e-04 -6.000000e+00 3.192915e-04 276.95 -2.00 20.00 -2.00 315.81 0.00e+00 1.262 0.000 302.00 328.00 3 6.0328e+00 4.1078e-03 1.5965e-02 -6.0000e+00 1.8353e-02 4.3340e-02 4.5924e-03 9.9820e-03 -6.0000e+00 1.9935e-02 -7.7240e-03 2.6506e-03 4.9040e-03 -6.0000e+00 1.1837e-02 -1.7790e-03 1.2070e-03 1.4231e-03 -6.0000e+00 4.9091e-03 2.9545e-04 -6.9445e-04 9.6455e-05 1.8212e-05 -6.0000e+00 3.7869e-04 -1.4419e-02 0.0000e+00 12 9 1 12 1 1 99.98 15.01 0.19 -0.01442 -0.01964 9 3 1 5 0 3051.910 21.98 15.01 18.88 2236 341 -3192 -3792 -1756 1962 86 -332 -274 -2369 -4655 1300 -73 263 1657 -232 2107 1619 2397 1577 -1190 1394 2218 1611 -1087 -1097 -2427 -2093 -206 -1978 1228 429 -1521 -3424 -2517 -1983 53 416 -20 -316 65 51 -145 -497 903 -270 -1121 -879 -188 516 466 750 954 1189 798 1184 502 296 704 410 1687 2441 1978 332 -854 -151 286 -103 774 580 211 -101 100 -681 -1297 -1224 -1618 -1586 -1794 -2118 -2095 -2317 -1246 -313 263 239 817 548 505 306 589 -243 -159 51 -344 -587 286 155 -799 -195 -382 -399 439 130 -1218 -577 -493 325 964 1381 1102 718 730 167 165 52 208 450 -338 -767 351 42 343 -74 310 -527 37 -58 -912 -1186 -779 -642 209 46 41 131 369 361 173 211 -310 30 -142 419 68 -648 -721 -302 317 15 -65 -57 -513 -1029 282 -18 71 485 -73 672 533 805 547 -428 489 784 596 -430 -439 -959 -785 -72 -695 434 163 -611 -1395 -984 -772 22 199 -11 -194 43 35 -100 -346 621 -186 -762 -581 -121 332 311 524 695 891 612 920 396 232 547 320 1346 2043 1753 307 -785 -130 231 -82 648 528 204 -101 100 -664 -1202 -1047 -1286 -1218 -1428 -1831 -1971 -2336 -1309 -341 300 287 1016 695 638 377 686 -265 -163 51 -358 -652 339 196 -1052 -254 -475 -470 503 154 -1526 -753 -665 449 1375 2038 1671 1091 1076 234 218 66 264 588 -466 -1107 513 62 489 -103 415 -684 46 -72 -1195 -1627 -1098 -917 302 69 63 209 600 595 286 345 -499 47 -222 SS 20210411T183030.4Z 7771.771185 276 1 12.79 2 38.49 209.27 44.64 209.16 0.00 1 0.00 1 0 17 1.156e-02 8.029e-03 5.326e-03 3.000e-03 1.946047e-01 1.588588e-03 2.360930e-03 -6.000000e+00 6.926087e-03 227.86 -2.00 3.57 -2.00 315.78 0.00e+00 9.104537e-04 1.572708e-04 9.928215e-05 -6.000000e+00 2.996064e-04 276.95 -2.00 20.00 -2.00 315.20 0.00e+00 1.276 0.000 302.00 328.00 3 5.4806e+00 4.1032e-03 1.6079e-02 -6.0000e+00 1.7223e-02 3.9088e-02 4.5730e-03 1.0011e-02 -6.0000e+00 1.8707e-02 -9.9791e-03 2.6173e-03 4.8990e-03 -6.0000e+00 1.1108e-02 -6.5719e-04 1.1608e-03 1.4307e-03 -6.0000e+00 4.6073e-03 5.0679e-04 -6.7390e-04 9.5237e-05 1.8954e-05 -6.0000e+00 3.5534e-04 -1.5191e-02 0.0000e+00 12 9 1 12 1 1 99.54 15.00 0.19 -0.01519 -0.02025 4 4 1 5 0 2525.110 21.98 15.00 18.90 611 -940 -1261 -3290 -1364 473 666 1220 -1674 -2684 -554 2541 -2184 1338 -198 214 -558 2660 1667 1084 -239 2827 1893 1746 324 329 -2374 -2617 -2523 224 1196 201 -411 -3724 -2872 -1562 -909 895 768 -1139 -704 -106 132 -482 801 -1078 -890 -590 -381 341 425 678 1213 1476 789 1097 154 748 643 649 2473 2114 973 1242 -680 108 -541 161 1037 461 -386 -180 -152 -292 -443 -1690 -1676 -1100 -469 -2057 -1834 -1564 -1485 -965 -48 -206 655 891 796 278 659 -1059 -425 -103 -240 410 -241 274 -378 -633 -663 258 109 -237 -1281 -1038 -282 18 1320 1282 907 719 413 727 244 703 258 313 101 -539 -150 251 341 379 249 -288 -91 -333 -609 -1175 -470 -333 15 127 -445 -289 616 127 -313 302 391 -69 -234 148 -240 -318 -791 -299 100 148 297 -444 -730 -148 685 -667 440 -72 82 -220 1046 677 452 -102 1174 802 767 149 153 -1105 -1170 -1081 93 506 91 -193 -1789 -1332 -717 -446 489 474 -780 -508 -78 99 -365 601 -814 -660 -427 -271 242 311 516 954 1188 649 913 129 626 535 542 2092 1875 909 1187 -650 98 -468 137 917 438 -388 -185 -156 -292 -425 -1531 -1424 -905 -395 -1873 -1788 -1610 -1592 -1069 -56 -246 806 1113 992 339 768 -1176 -446 -106 -255 458 -287 342 -487 -812 -818 303 125 -281 -1590 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