File name: Pandora103s1_Downsview_20210501_L2Fit_fout2c10d20181123p1-8.txt File generation date: 20241101T132913.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v10d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20200901.txt Level 1 file used: Pandora103s1_Downsview_20210501_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20210501 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 201 343 Nominal wavelengths inside fitting window [nm]: 305.1310 305.2711 305.4113 305.5515 305.6916 305.8318 305.9719 306.1121 306.2522 306.3924 306.5325 306.6726 306.8128 306.9529 307.0930 307.2331 307.3733 307.5134 307.6535 307.7936 307.9337 308.0738 308.2139 308.3540 308.4941 308.6341 308.7742 308.9143 309.0544 309.1944 309.3345 309.4746 309.6146 309.7546 309.8947 310.0347 310.1748 310.3148 310.4548 310.5948 310.7348 310.8749 311.0149 311.1549 311.2948 311.4348 311.5748 311.7148 311.8548 311.9947 312.1347 312.2746 312.4146 312.5545 312.6945 312.8344 312.9743 313.1142 313.2541 313.3940 313.5339 313.6738 313.8137 313.9536 314.0935 314.2333 314.3732 314.5131 314.6529 314.7927 314.9326 315.0724 315.2122 315.3520 315.4918 315.6316 315.7714 315.9112 316.0510 316.1908 316.3305 316.4703 316.6100 316.7498 316.8895 317.0292 317.1689 317.3086 317.4483 317.5880 317.7277 317.8674 318.0071 318.1467 318.2864 318.4260 318.5657 318.7053 318.8449 318.9845 319.1242 319.2638 319.4033 319.5429 319.6825 319.8221 319.9616 320.1012 320.2407 320.3802 320.5198 320.6593 320.7988 320.9383 321.0778 321.2172 321.3567 321.4962 321.6356 321.7751 321.9145 322.0539 322.1933 322.3327 322.4721 322.6115 322.7509 322.8903 323.0296 323.1690 323.3083 323.4477 323.5870 323.7263 323.8656 324.0049 324.1442 324.2834 324.4227 324.5620 324.7012 324.8404 324.9797 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210501T104358.5Z 7791.447205 193 1 51.02 2 84.97 73.70 72.43 197.94 0.00 1 0.00 1 0 52 7.056e-01 6.647e-02 4.856e-01 5.267e-02 1.123398e+00 3.125473e-02 1.280386e-02 -6.000000e+00 4.254378e-01 229.59 -2.00 3.57 -2.00 322.18 0.00e+00 -1.511223e-02 1.052777e-02 6.412707e-03 -6.000000e+00 1.897468e-02 279.20 -2.00 20.00 -2.00 321.59 0.00e+00 9.789 0.018 302.00 328.00 3 1.0480e-01 1.0219e-01 1.2526e-01 -6.0000e+00 1.0615e+00 2.4845e+00 1.1941e-01 9.5594e-02 -6.0000e+00 1.1518e+00 -2.6514e+00 6.7327e-02 3.0973e-02 -6.0000e+00 6.8367e-01 9.1478e-01 3.7938e-02 1.6511e-02 -6.0000e+00 2.8372e-01 8.5355e-06 -2.1723e-03 1.3486e-03 1.8258e-04 -6.0000e+00 2.1719e-02 -8.8572e-03 0.0000e+00 12 8 8 10 0 0 24.75 15.00 0.88 -0.00886 -0.02518 33 6 1 5 0 1545.710 21.69 15.00 18.52 249580 102781 59046 146688 -43233 -32916 -40140 22815 -14525 8528 -18602 900000 83774 84876 348301 -17675 189432 63175 6355 35483 209220 -41359 55052 156516 -22766 32431 72895 -11213 14778 -93650 900000 61814 49260 -27885 28576 176586 -13534 194741 89607 -27105 157578 58859 73946 81955 8276 41852 -50434 108098 -30131 30026 33187 331095 -14314 34792 48530 32693 2801 21238 -312 5250 25118 -30642 1852 22574 5959 -36946 121695 54518 33408 9144 46137 30892 -16410 39938 2928 -37473 1875 -33737 -12230 -16200 22305 -11599 18381 12649 34989 -7739 -2741 2355 8756 172 14669 2748 -32196 18486 7065 26106 207 4089 -918 -3804 -12060 -5896 -4145 9622 -18815 -7061 8195 9911 -1530 10408 -1898 -577 6370 -251 -4996 1621 20993 -6329 12916 -9343 7907 1126 1130 -599 -1409 -6962 5016 -4401 -973 4088 2503 -2678 -693 -1660 -1366 -689 2893 -144 -2646 364 2175 3450 -1696 12814 7036 5305 7532 -7029 -4366 -5839 1855 -1740 803 -2308 900000 4692 5150 17883 -3025 9726 5013 831 3147 10742 -6564 3341 8036 -3294 2573 3743 -1047 966 -18359 900000 3174 2989 -3514 1867 9067 -1327 9999 4601 -4555 8091 4396 4487 4629 811 3008 -8004 5550 -4079 2621 3067 17000 -2272 3930 4983 4029 418 2726 -45 647 2450 -5506 266 2898 948 -8278 6248 5878 4974 1925 7107 5551 -4465 5537 511 -8658 279 -7622 -2574 -4242 4695 -3930 5096 3962 9162 -3219 -1112 907 3057 62 4293 875 -14878 5695 2866 10455 127 2750 -707 -3047 -9783 -3996 -2511 4990 -13525 -4786 5091 6666 -1328 9405 -2231 -670 7980 -339 -6978 2098 22743 -9391 16446 -14968 10271 1474 1410 -742 -1721 -8794 5692 -6034 -1518 7179 5102 -6366 -1769 -4246 -3750 -1972 8157 -461 -8505 1078 5808 8361 -4205 SS 20210501T105651.2Z 7791.456148 196 1 50.43 2 82.73 75.86 73.17 200.77 0.00 1 0.00 1 0 17 4.981e-01 1.670e-02 3.482e-01 8.163e-03 1.010117e+00 4.986851e-03 1.068464e-02 -6.000000e+00 3.021504e-01 229.60 -2.00 3.57 -2.00 322.52 0.00e+00 8.197726e-03 3.210511e-03 3.687004e-03 -6.000000e+00 1.314631e-02 279.21 -2.00 20.00 -2.00 322.10 0.00e+00 7.294 0.007 302.00 328.00 3 4.3816e-01 2.0993e-02 9.7382e-02 -6.0000e+00 7.5349e-01 9.0860e-01 3.0793e-02 7.6316e-02 -6.0000e+00 8.1753e-01 -1.2825e+00 3.0224e-02 3.4754e-02 -6.0000e+00 4.8404e-01 5.2183e-01 1.3399e-02 1.2342e-02 -6.0000e+00 1.9967e-01 9.7934e-05 -1.8367e-03 2.3197e-04 1.7737e-04 -6.0000e+00 1.5367e-02 -8.8870e-03 0.0000e+00 12 8 8 10 0 0 27.79 15.00 0.24 -0.00889 -0.02269 149 28 1 5 0 338.440 21.69 15.00 18.52 62365 -130837 -22882 -148951 46950 900000 -120033 -252362 -197230 -42356 -219678 -110066 -147677 -107392 -128237 -23003 -87801 -4312 -66758 22398 -45950 14898 -85438 -36570 -61853 -45569 35700 14150 -50256 -3366 7222 12070 2564 -2417 -25428 16644 -30411 -12310 18604 25588 6660 -18132 40291 22990 6264 10330 18599 14908 27123 25915 49082 21539 48852 43902 31821 34638 24431 36630 7508 12162 7713 30150 19378 40081 15547 35241 18860 17868 12049 21535 10832 16951 8216 6291 8007 6963 -3217 -809 1505 4150 5678 1262 5042 1274 5233 3337 2924 47 1536 1151 -313 -4110 -2102 -4756 -2078 -2509 93 -2647 -2787 -2725 -3057 -2579 -2244 -875 -3324 -2146 -1267 -340 -747 717 -914 -181 -1041 380 -1331 119 -443 -171 -416 -497 1599 3112 2602 261 1025 440 1426 943 -703 -669 698 336 761 165 -143 -403 903 310 -52 -306 -153 -1047 -874 496 -1420 -182 -1724 374 900000 -955 -7122 -3282 -337 -5087 -1035 -2671 -1710 -3155 -256 -1906 -48 -1304 196 -698 130 -1855 -553 -1231 -762 284 124 -880 -43 103 202 53 -54 -688 291 -920 -363 474 692 239 -800 1122 769 249 403 696 617 1079 1155 1953 1153 2411 2224 1911 2080 1626 2094 549 827 569 1985 1641 3132 1676 3213 2088 2159 1744 3194 1928 2895 1474 1056 1182 942 -470 -125 269 880 1417 380 1620 456 1905 1301 1193 18 636 459 -120 -1582 -806 -2061 -1031 -1380 59 -1998 -2307 -2287 -2409 -1807 -1435 -595 -2225 -1510 -946 -277 -699 769 -1134 -242 -1462 526 -1833 160 -608 -245 -623 -754 2305 4183 3355 335 1273 535 1730 1253 -1107 -1231 1432 756 1848 436 -406 -1197 2696 930 -153 -864 -398 -2535 -2054 SS 20210501T110720.3Z 7791.463429 199 1 50.55 2 80.89 77.61 73.85 203.04 0.00 1 0.00 1 0 17 7.220e-01 9.804e-03 2.235e-01 3.078e-03 8.742406e-01 1.815391e-03 1.019318e-02 -6.000000e+00 4.352606e-01 229.60 -2.00 3.57 -2.00 322.15 0.00e+00 1.404754e-02 1.097916e-03 3.403939e-03 -6.000000e+00 1.889416e-02 279.21 -2.00 20.00 -2.00 321.68 0.00e+00 5.991 0.004 302.00 328.00 3 4.1222e-01 7.1057e-03 7.7365e-02 -6.0000e+00 1.0860e+00 3.1270e-01 1.1163e-02 5.2704e-02 -6.0000e+00 1.1779e+00 -4.5121e-01 1.2293e-02 3.1172e-02 -6.0000e+00 6.9939e-01 1.8529e-01 5.4632e-03 1.6177e-02 -6.0000e+00 2.8939e-01 4.0132e-04 -1.4432e-03 8.8988e-05 2.9488e-04 -6.0000e+00 2.2220e-02 -9.4462e-03 0.0000e+00 12 8 8 10 0 0 20.90 15.00 0.25 -0.00945 -0.02029 328 61 1 5 0 154.080 21.69 15.00 18.53 2786 -245577 -247342 -204810 -95956 -290972 -259097 -230722 -264322 -146192 -241338 -187511 -154205 -104430 -136442 -98956 -123460 62014 -86288 -27803 -114572 -55241 -67551 -49210 -64611 -43493 -78008 -63411 -81149 -35985 -15862 -24204 -1005 -2855 -16343 -43466 -17795 -10721 22364 -5656 20984 -10650 19585 -2825 13961 5027 16119 12178 18562 18481 21213 20618 17480 16167 10627 11984 6229 9048 -725 6730 4413 9512 6432 12973 7109 13197 4162 9735 5432 4522 6217 3116 -389 283 -1024 -3044 -3132 -1141 -1456 -1555 1198 108 -350 -1509 159 -864 807 -1192 838 -656 173 -1765 -1462 -2885 -1550 -1297 9 11 -974 -1166 -733 -761 -34 -195 -2346 -1743 -1227 777 682 1275 301 307 -329 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