File name: Pandora103s1_Downsview_20210515_L2Fit_fout2c10d20181123p1-8.txt File generation date: 20241101T132917.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v10d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20200901.txt Level 1 file used: Pandora103s1_Downsview_20210515_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20210515 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 201 343 Nominal wavelengths inside fitting window [nm]: 305.1310 305.2711 305.4113 305.5515 305.6916 305.8318 305.9719 306.1121 306.2522 306.3924 306.5325 306.6726 306.8128 306.9529 307.0930 307.2331 307.3733 307.5134 307.6535 307.7936 307.9337 308.0738 308.2139 308.3540 308.4941 308.6341 308.7742 308.9143 309.0544 309.1944 309.3345 309.4746 309.6146 309.7546 309.8947 310.0347 310.1748 310.3148 310.4548 310.5948 310.7348 310.8749 311.0149 311.1549 311.2948 311.4348 311.5748 311.7148 311.8548 311.9947 312.1347 312.2746 312.4146 312.5545 312.6945 312.8344 312.9743 313.1142 313.2541 313.3940 313.5339 313.6738 313.8137 313.9536 314.0935 314.2333 314.3732 314.5131 314.6529 314.7927 314.9326 315.0724 315.2122 315.3520 315.4918 315.6316 315.7714 315.9112 316.0510 316.1908 316.3305 316.4703 316.6100 316.7498 316.8895 317.0292 317.1689 317.3086 317.4483 317.5880 317.7277 317.8674 318.0071 318.1467 318.2864 318.4260 318.5657 318.7053 318.8449 318.9845 319.1242 319.2638 319.4033 319.5429 319.6825 319.8221 319.9616 320.1012 320.2407 320.3802 320.5198 320.6593 320.7988 320.9383 321.0778 321.2172 321.3567 321.4962 321.6356 321.7751 321.9145 322.0539 322.1933 322.3327 322.4721 322.6115 322.7509 322.8903 323.0296 323.1690 323.3083 323.4477 323.5870 323.7263 323.8656 324.0049 324.1442 324.2834 324.4227 324.5620 324.7012 324.8404 324.9797 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210515T103958.8Z 7805.444430 59 1 50.57 2 82.92 70.44 102.98 35.40 0.00 1 0.00 1 0 25 7.239e-01 3.295e-02 4.699e-01 2.694e-02 1.103992e+00 1.645926e-02 1.208039e-02 -6.000000e+00 4.445789e-01 230.87 -2.00 3.57 -2.00 322.53 0.00e+00 1.366836e-04 8.966053e-03 4.632501e-03 -6.000000e+00 1.957164e-02 280.81 -2.00 20.00 -2.00 322.09 0.00e+00 7.461 0.008 302.00 328.00 3 1.6583e+00 6.4163e-02 9.9202e-02 -6.0000e+00 1.1194e+00 1.7323e+00 7.6938e-02 6.9158e-02 -6.0000e+00 1.2167e+00 -2.1956e+00 5.2661e-02 3.1183e-02 -6.0000e+00 7.1382e-01 8.5286e-01 2.6916e-02 9.0660e-03 -6.0000e+00 2.9247e-01 1.8439e-05 -2.9601e-03 7.2106e-04 1.5483e-04 -6.0000e+00 2.2666e-02 -8.9963e-03 0.0000e+00 12 8 8 10 0 0 91.09 15.00 0.31 -0.00900 -0.03124 44 8 1 5 0 1149.240 21.98 15.00 18.81 23252 86489 -55694 -31158 -33444 -68385 -42215 900000 900000 -86530 -65164 -8337 -77111 54949 29286 50022 473483 -3522 435935 -79421 55671 -45674 150368 30785 27705 -16053 -10872 43 72485 900000 3302 4243 900000 48439 -18432 10005 -50146 166363 84530 112515 120481 85835 -1845 16795 131056 69429 15548 27677 31251 200945 14146 37339 52713 45514 80728 9806 97703 87238 13750 37312 13278 35888 35714 33077 37859 30890 82967 -199 51419 -799 40427 -768 38530 -4944 23224 -2558 -1651 -4175 -8728 11994 3317 13105 3551 8503 1692 4649 6200 12525 3342 3415 -13254 -650 -17695 -9420 -8633 -2591 -292 -963 -6386 -2100 -2220 -8943 741 -4935 -2906 167 4564 -2703 -3218 -2217 4244 -953 2074 -329 -1734 -626 -2532 -2031 423 763 1599 5391 1419 1326 518 3556 -71 2919 -3668 -179 -253 2520 0 1492 -123 58 -608 916 187 -1308 -435 442 -1829 768 2270 -3494 -1324 -1219 -3093 -1461 900000 900000 -4451 -2818 -237 -4980 1442 968 1493 12428 -184 11443 -7751 1461 -2800 3947 918 855 -717 -427 1 1903 900000 132 195 900000 1575 -1049 416 -3799 4367 2359 2953 3163 2871 -138 1022 3440 2436 907 1492 1726 5275 1088 2544 3361 3283 4361 1043 4553 4283 1246 2565 1140 2699 3023 3196 3733 3322 5642 -31 5576 -156 5738 -162 5389 -945 3038 -383 -237 -657 -1661 2256 799 3296 1078 2631 585 1629 2212 4253 1212 1184 -5112 -216 -7026 -3802 -4047 -1371 -178 -681 -5215 -1678 -1670 -6426 443 -3052 -1836 109 3038 -2118 -2899 -2307 4753 -1233 2734 -447 -2360 -835 -3500 -2913 617 1120 2255 6930 1806 1645 634 4131 -86 3748 -5852 -324 -520 5549 -1 3903 -350 171 -1844 2739 551 -3719 -1130 1047 -4280 SS 20210515T105133.3Z 7805.452469 62 1 29.84 2 80.94 72.35 101.78 37.67 0.00 1 0.00 1 0 17 5.601e-01 1.540e-02 4.339e-01 1.105e-02 9.427652e-01 6.752599e-03 1.057171e-02 -6.000000e+00 3.474066e-01 230.87 -2.00 3.57 -2.00 322.25 0.00e+00 1.522401e-02 4.232549e-03 1.545045e-03 -6.000000e+00 1.668517e-02 280.81 -2.00 20.00 -2.00 321.80 0.00e+00 6.023 0.004 302.00 328.00 3 2.2768e+00 2.7440e-02 8.3356e-02 -6.0000e+00 8.7568e-01 5.5578e-01 4.2677e-02 6.8528e-02 -6.0000e+00 9.5302e-01 -7.7103e-01 4.4794e-02 3.0867e-02 -6.0000e+00 5.5412e-01 3.1266e-01 1.9682e-02 1.7866e-02 -6.0000e+00 2.2777e-01 5.3131e-05 -1.7993e-03 3.1760e-04 2.8296e-04 -6.0000e+00 1.8087e-02 -9.9010e-03 0.0000e+00 12 9 9 12 1 1 93.55 15.00 0.45 -0.00990 -0.02342 25 8 1 5 0 1140.620 21.98 15.00 18.82 -212384 900000 29832 -201698 900000 -264546 900000 900000 900000 -120957 900000 -291530 -60668 -140384 -78703 -92518 -62260 -30723 -60220 -53746 -107318 22631 -78934 -27361 -32177 -76419 -86118 900000 -106602 -8366 -78845 900000 20636 84245 -58196 -57928 -21764 27284 -59445 13364 22125 -6005 54829 -22880 8247 2155 25222 7083 88293 27735 20238 65694 50385 11133 10346 10578 13227 -8429 7818 11773 17023 14242 28620 25429 20666 16999 3041 18786 1049 18064 12660 4676 7514 6872 3170 12706 -5023 8082 -7705 493 -1108 2054 2746 -1382 2249 1359 -1476 2737 2211 -2062 4608 -4563 1351 -5054 -2002 -2091 -1183 -1331 -49 -4074 -1272 88 -480 1605 -3084 -1387 -1829 1483 -1044 666 268 -317 -1016 -664 -822 1342 51 1060 -1253 -189 1390 2677 388 649 42 419 341 498 -17 -678 -107 126 716 108 55 -10 625 -26 100 -525 -53 -1132 5 -2286 900000 321 -2171 900000 -3183 900000 900000 900000 -1302 900000 -7200 -653 -1531 -847 -1014 -670 -331 -669 -579 -1916 244 -1053 -295 -346 -1047 -1293 900000 -2187 -90 -1889 900000 272 907 -1678 -1668 -483 440 -2582 331 555 -212 1143 -1037 288 83 832 299 1874 1162 1024 2427 2370 814 801 839 1027 -789 611 885 1283 1240 2514 2606 2389 2092 439 2504 186 3061 2436 992 1508 1289 559 1874 -858 1315 -1702 122 -329 677 990 -554 919 590 -687 1248 1002 -938 1873 -1948 548 -2365 -1057 -1313 -865 -1112 -44 -3860 -1101 68 -343 1114 -2341 -1099 -1550 1327 -1078 773 349 -447 -1480 -957 -1159 1826 72 1532 -1931 -292 2069 3760 533 864 55 531 433 681 -26 -1224 -213 271 1638 265 144 -26 1715 -71 273 -1383 -131 -2629 12 SS 20210515T110312.8Z 7805.460565 67 1 50.44 2 78.93 74.25 100.51 39.90 0.00 1 0.00 1 0 17 5.514e-01 8.340e-03 2.119e-01 2.398e-03 8.095774e-01 1.387766e-03 9.761602e-03 -6.000000e+00 3.348881e-01 230.87 -2.00 3.57 -2.00 321.85 0.00e+00 1.342445e-02 8.039624e-04 4.917622e-03 -6.000000e+00 1.476232e-02 280.81 -2.00 20.00 -2.00 321.37 0.00e+00 5.022 0.002 302.00 328.00 3 1.0608e+00 5.2302e-03 6.8459e-02 -6.0000e+00 8.3704e-01 1.6795e-01 8.1149e-03 4.8911e-02 -6.0000e+00 9.0683e-01 -2.5685e-01 8.8732e-03 3.3605e-02 -6.0000e+00 5.3769e-01 1.0153e-01 3.9779e-03 1.6863e-02 -6.0000e+00 2.2219e-01 5.4920e-04 -1.2333e-03 6.9722e-05 2.8071e-04 -6.0000e+00 1.7037e-02 -1.0688e-02 0.0000e+00 11 8 0 10 0 0 21.84 15.00 0.21 -0.01069 -0.01996 334 62 1 5 0 151.000 21.88 15.00 18.80 -111953 -271133 -210068 -171587 900000 -242669 -52844 -113889 -129400 -235243 -89009 -195514 -73697 -126000 -50652 -50349 -37342 -60361 -42718 -25182 -46743 -11807 -41690 -4405 -76209 -33716 -76224 -797 -49923 -8919 -33191 197 -28156 14788 -791 10111 -15984 13830 -15027 1987 6199 8117 -6271 -208 8618 -646 9187 2200 17061 3968 12136 8012 16920 7019 11540 3349 5838 -1856 1757 -996 4956 2507 7638 8100 4659 6566 4038 4491 3486 5070 1666 1456 -470 837 -3551 -2164 -4579 -2350 -1436 518 -1443 -796 -2100 -885 -986 22 -297 -760 -19 -366 -42 -871 -681 -1483 -837 -697 282 -251 -401 -656 -831 -520 1392 -443 -1958 -1797 -616 316 1470 1076 570 260 -27 39 249 1161 753 595 -409 -433 107 935 536 -239 -729 -593 221 838 -676 -542 -621 -45 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