File name: Pandora103s1_Downsview_20210623_L2Fit_fout2c9d20181123p1-8.txt File generation date: 20241101T140422.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v10d20171016.txt Instrument calibration file used: Pandora103s1_CF_v9d20210521.txt Level 1 file used: Pandora103s1_Downsview_20210623_L1_smca1c9d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20210623 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 201 343 Nominal wavelengths inside fitting window [nm]: 305.0757 305.2165 305.3573 305.4981 305.6389 305.7797 305.9205 306.0612 306.2020 306.3427 306.4834 306.6241 306.7649 306.9055 307.0462 307.1869 307.3276 307.4682 307.6089 307.7495 307.8901 308.0307 308.1713 308.3119 308.4525 308.5930 308.7336 308.8741 309.0147 309.1552 309.2957 309.4362 309.5767 309.7172 309.8576 309.9981 310.1385 310.2790 310.4194 310.5598 310.7002 310.8406 310.9810 311.1214 311.2617 311.4021 311.5424 311.6827 311.8231 311.9634 312.1037 312.2439 312.3842 312.5245 312.6647 312.8050 312.9452 313.0854 313.2256 313.3658 313.5060 313.6462 313.7863 313.9265 314.0666 314.2068 314.3469 314.4870 314.6271 314.7672 314.9073 315.0473 315.1874 315.3274 315.4675 315.6075 315.7475 315.8875 316.0275 316.1675 316.3074 316.4474 316.5873 316.7273 316.8672 317.0071 317.1470 317.2869 317.4268 317.5666 317.7065 317.8463 317.9862 318.1260 318.2658 318.4056 318.5454 318.6852 318.8250 318.9647 319.1045 319.2442 319.3839 319.5236 319.6633 319.8030 319.9427 320.0824 320.2220 320.3617 320.5013 320.6409 320.7806 320.9202 321.0598 321.1993 321.3389 321.4785 321.6180 321.7575 321.8971 322.0366 322.1761 322.3156 322.4551 322.5945 322.7340 322.8734 323.0129 323.1523 323.2917 323.4311 323.5705 323.7099 323.8492 323.9886 324.1279 324.2673 324.4066 324.5459 324.6852 324.8245 324.9638 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210623T102656.2Z 7844.435372 161 1 50.75 2 82.97 64.13 111.33 257.70 0.00 1 0.00 1 0 25 7.881e-01 3.271e-02 4.905e-01 2.368e-02 1.006941e+00 1.452117e-02 1.082733e-02 -6.000000e+00 4.897196e-01 232.93 -2.00 3.57 -2.00 322.49 0.00e+00 -7.234365e-03 8.629466e-03 5.599987e-03 -6.000000e+00 2.261263e-02 284.78 -2.00 20.00 -2.00 322.02 0.00e+00 7.493 0.008 302.00 328.00 3 1.6934e+00 6.0545e-02 1.0063e-01 -6.0000e+00 1.2288e+00 1.3686e+00 7.7103e-02 7.8414e-02 -6.0000e+00 1.3284e+00 -1.8839e+00 5.5057e-02 3.1630e-02 -6.0000e+00 7.8437e-01 7.4621e-01 2.5862e-02 1.0165e-02 -6.0000e+00 3.2287e-01 2.2158e-05 -1.2067e-03 6.8105e-04 1.2456e-04 -6.0000e+00 2.5137e-02 -1.0028e-02 0.0000e+00 12 8 8 10 0 0 99.59 15.00 0.42 -0.01003 -0.01910 57 11 1 5 0 890.180 21.88 15.00 18.77 61322 196214 -13013 900000 -131346 900000 -60764 900000 -105521 -49193 -129774 -29025 20567 63103 14649 124165 106647 22625 192066 73691 -36727 -24904 26629 287156 48051 900000 447511 -28233 900000 -33719 -4529 -12536 118966 44837 35740 -57938 15366 -26598 53674 77623 17856 182941 61271 110256 80093 338088 123409 221277 42688 103722 92273 80794 9507 164564 30722 56317 53863 101283 4554 31417 6745 20440 27243 13554 21668 26480 35219 47297 64234 19959 28180 12957 41370 -7780 17698 -31054 13728 -22297 14721 -9545 12669 -3163 5045 2637 6821 -4199 13223 6439 3698 -3582 -852 -9835 -2333 1687 -6786 -2668 -3763 -2960 -1795 -1055 -8020 1739 -7582 -3263 -5020 -5260 689 -2228 399 -835 1394 -663 1024 -625 -688 -1319 -542 -1470 797 -1200 3060 1205 8309 3360 226 -3 2073 -1927 1336 -1585 289 -10 1261 -53 477 -141 -671 1638 -367 560 -1381 -793 -1077 1415 4528 -367 900000 -8453 900000 -1832 900000 -5404 -1505 -8679 -811 475 1456 415 2865 2461 703 4432 1700 -1815 -1045 684 6626 1117 900000 10327 -1163 900000 -1428 -165 -568 2745 1310 1084 -4077 568 -1668 1861 2453 1079 4222 2538 2772 2573 7802 2848 5106 2016 2961 3233 3488 871 3797 2605 3904 3860 4530 473 2400 642 1826 2543 1594 2516 2994 3730 4752 6146 3228 4554 2476 5902 -1627 2625 -6548 1824 -4334 2309 -2227 2828 -938 1535 883 2320 -1663 4626 2442 1419 -1416 -313 -3787 -843 635 -3193 -1428 -2386 -2132 -1401 -838 -6449 1154 -5063 -2066 -3383 -3777 499 -1807 358 -873 1624 -862 1367 -852 -923 -1757 -728 -2077 1154 -1802 4325 1654 10202 4218 287 -4 2525 -2623 2030 -2880 582 -22 2977 -136 1310 -408 -2002 4797 -1079 1564 -3654 -1931 -2552 SS 20210623T103855.0Z 7844.443692 164 1 50.61 2 81.01 66.07 113.37 259.50 0.00 1 0.00 1 0 17 8.794e-01 1.495e-02 2.816e-01 4.490e-03 8.466482e-01 2.665616e-03 1.066264e-02 -6.000000e+00 5.406894e-01 232.93 -2.00 3.57 -2.00 322.17 0.00e+00 1.483822e-02 1.718709e-03 8.351434e-03 -6.000000e+00 2.384480e-02 284.78 -2.00 20.00 -2.00 321.68 0.00e+00 6.058 0.004 302.00 328.00 3 9.5603e-01 1.1196e-02 8.2901e-02 -6.0000e+00 1.3568e+00 4.1940e-01 1.6373e-02 5.9539e-02 -6.0000e+00 1.4653e+00 -6.7226e-01 1.6105e-02 3.5191e-02 -6.0000e+00 8.6900e-01 2.8031e-01 7.1250e-03 1.4466e-02 -6.0000e+00 3.5888e-01 2.2674e-04 -1.0747e-03 1.3438e-04 3.6875e-04 -6.0000e+00 2.7057e-02 -1.1198e-02 0.0000e+00 12 8 8 10 0 0 99.39 15.00 0.17 -0.01120 -0.01927 222 41 1 5 0 227.910 21.88 15.00 18.77 -284927 -77912 -207238 325 -256064 900000 -240817 -104372 -203962 -18658 -167271 -139211 -160109 -112607 -95302 -125282 -67587 -50184 -13456 -64153 41248 -85488 16019 -88973 644534 -79898 350440 -94897 70981 -74566 58629 -38095 97203 3702 16667 -10291 32333 582 19657 35894 -750 33101 821 42769 6024 45860 4737 54940 9239 39485 6069 33920 22921 42736 7721 25087 7330 19526 8486 14592 8157 10413 12279 12431 19104 13159 13592 5636 11825 6374 14113 5700 9382 -596 6801 -5731 561 -7746 1661 -115 2099 1081 1915 -409 355 148 382 746 -282 1303 -2038 -194 -4335 -1537 -4797 -1379 -2131 33 -1724 -975 -2037 -1405 -2322 -1185 -2879 -1833 -850 -252 552 701 1136 301 442 -819 -517 -838 278 -1020 639 96 1811 1311 2169 264 876 -723 13 -101 42 31 87 264 -126 142 -315 96 365 435 -91 194 -419 -239 -980 -6026 -341 -2690 1 -4746 900000 -3627 -457 -2371 -82 -1510 -1136 -2088 -1273 -1189 -2519 -924 -651 -134 -1060 255 -1703 123 -1859 2822 -1592 1534 -2189 367 -1719 483 -950 800 77 306 -240 543 15 499 896 -29 1009 36 1313 267 1471 232 1803 495 1747 405 1954 1605 2678 701 2000 696 1639 773 1252 778 1079 1427 1628 2534 1888 1967 926 2036 1301 2914 1319 2062 -136 1322 -1148 102 -1599 359 -30 636 378 734 -172 157 70 188 376 -143 630 -971 -87 -1997 -733 -2687 -881 -1605 27 -1616 -927 -1856 -1156 -1786 -894 -2308 -1549 -757 -241 586 842 1515 433 653 -1211 -740 -1182 394 -1525 986 152 2800 1960 3089 372 1198 -974 17 -143 67 57 175 571 -291 350 -825 261 1019 1220 -254 524 -1072 -574 -2315 SS 20210623T105115.4Z 7844.452261 169 1 50.57 2 78.96 68.05 115.47 261.37 0.00 1 0.00 1 0 17 4.954e-01 7.281e-03 1.455e-01 1.936e-03 7.328426e-01 1.115857e-03 8.913260e-03 -6.000000e+00 3.032245e-01 232.93 -2.00 3.57 -2.00 321.71 0.00e+00 7.684785e-03 6.390602e-04 6.111600e-03 -6.000000e+00 1.328012e-02 284.78 -2.00 20.00 -2.00 321.17 0.00e+00 5.032 0.002 302.00 328.00 3 8.3039e-01 4.2699e-03 6.9382e-02 -6.0000e+00 7.6148e-01 5.4970e-02 6.2530e-03 5.3269e-02 -6.0000e+00 8.2226e-01 -1.4511e-01 6.4056e-03 3.0339e-02 -6.0000e+00 4.8858e-01 5.8496e-02 2.8987e-03 1.0182e-02 -6.0000e+00 2.0218e-01 7.8283e-04 -5.5666e-04 5.9345e-05 2.2124e-04 -6.0000e+00 1.5242e-02 -1.1598e-02 0.0000e+00 11 8 0 10 0 0 94.81 15.00 0.19 -0.01160 -0.01578 424 79 1 5 0 119.250 21.88 15.00 18.75 -207415 -127702 -180086 -88163 -194894 -185789 -176808 -69298 -101953 -124247 -149168 -131987 -110503 -90687 -83124 -82855 -44794 -66314 -37200 -56937 -28773 -47598 -20018 -58608 -33702 -39889 -28616 -41549 -29140 -21058 -9361 -8659 -751 -9199 -12611 -10103 -7997 -9138 -3572 4257 -1816 -271 3396 6706 -353 10925 4830 5766 1189 4014 2040 7954 6892 4613 6517 3382 3109 2200 -214 1407 5232 5295 6807 5418 4831 2191 3409 77 2112 2695 2351 677 1283 285 -1137 -2161 -2845 -3879 -2541 -2694 -1465 -1261 -2100 -1222 -1185 -235 226 726 971 724 191 -479 -2050 -1443 -1746 -815 -283 507 139 -409 -969 -1107 -885 -625 -1545 -1223 -303 358 1489 1622 1629 817 626 -7 -343 -182 8 -183 -135 -134 415 767 579 -291 -133 -843 -636 -222 -497 -350 -353 -231 -212 62 -183 -60 368 301 107 85 -15 -138 -29 -1246 -458 -1082 -233 -1305 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