File name: Pandora103s1_Downsview_20210625_L2Fit_fout2c9d20181123p1-8.txt File generation date: 20241101T140313.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v10d20171016.txt Instrument calibration file used: Pandora103s1_CF_v9d20210521.txt Level 1 file used: Pandora103s1_Downsview_20210625_L1_smca1c9d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20210625 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 201 343 Nominal wavelengths inside fitting window [nm]: 305.0757 305.2165 305.3573 305.4981 305.6389 305.7797 305.9205 306.0612 306.2020 306.3427 306.4834 306.6241 306.7649 306.9055 307.0462 307.1869 307.3276 307.4682 307.6089 307.7495 307.8901 308.0307 308.1713 308.3119 308.4525 308.5930 308.7336 308.8741 309.0147 309.1552 309.2957 309.4362 309.5767 309.7172 309.8576 309.9981 310.1385 310.2790 310.4194 310.5598 310.7002 310.8406 310.9810 311.1214 311.2617 311.4021 311.5424 311.6827 311.8231 311.9634 312.1037 312.2439 312.3842 312.5245 312.6647 312.8050 312.9452 313.0854 313.2256 313.3658 313.5060 313.6462 313.7863 313.9265 314.0666 314.2068 314.3469 314.4870 314.6271 314.7672 314.9073 315.0473 315.1874 315.3274 315.4675 315.6075 315.7475 315.8875 316.0275 316.1675 316.3074 316.4474 316.5873 316.7273 316.8672 317.0071 317.1470 317.2869 317.4268 317.5666 317.7065 317.8463 317.9862 318.1260 318.2658 318.4056 318.5454 318.6852 318.8250 318.9647 319.1045 319.2442 319.3839 319.5236 319.6633 319.8030 319.9427 320.0824 320.2220 320.3617 320.5013 320.6409 320.7806 320.9202 321.0598 321.1993 321.3389 321.4785 321.6180 321.7575 321.8971 322.0366 322.1761 322.3156 322.4551 322.5945 322.7340 322.8734 323.0129 323.1523 323.2917 323.4311 323.5705 323.7099 323.8492 323.9886 324.1279 324.2673 324.4066 324.5459 324.6852 324.8245 324.9638 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210625T143142.1Z 7846.605349 309 1 50.49 2 40.08 106.60 132.89 273.64 0.00 1 0.00 1 0 17 8.426e-03 6.319e-03 8.654e-04 4.398e-04 1.790355e-01 2.356970e-04 2.159859e-03 -6.000000e+00 5.158415e-03 232.94 -2.00 3.57 -2.00 316.24 0.00e+00 5.336447e-04 2.590299e-05 1.226173e-04 -6.000000e+00 2.260769e-04 284.98 -2.00 20.00 -2.00 315.48 0.00e+00 1.306 0.000 302.00 328.00 3 2.9849e+00 6.1851e-04 1.5994e-02 -6.0000e+00 1.2954e-02 1.0709e-04 6.8787e-04 9.4521e-03 -6.0000e+00 1.3987e-02 -8.8957e-03 3.9285e-04 4.5565e-03 -6.0000e+00 8.3118e-03 -8.2128e-04 1.7492e-04 1.2445e-03 -6.0000e+00 3.4404e-03 6.2638e-03 -1.2050e-04 1.4115e-05 1.6966e-05 -6.0000e+00 2.5926e-04 -1.2313e-02 0.0000e+00 10 0 0 10 0 0 99.95 15.00 0.20 -0.01231 -0.01322 374 70 1 5 0 134.980 21.88 15.00 18.71 -471 -803 -668 -1303 331 -19 -628 -884 -1296 -1710 -1173 -82 -978 -420 15 -163 491 1404 1188 1631 816 1406 1645 772 499 -86 -1126 -619 -64 199 27 -115 -696 -3058 -2621 -1562 -1644 -857 -552 -979 -752 -196 119 -107 372 13 -328 -322 -213 454 821 645 1071 941 753 1169 719 392 658 978 1364 1597 1214 834 -324 -37 91 307 1155 330 -221 -144 -270 -98 -607 -944 -1242 -1335 -1180 -1758 -1914 -1919 -1824 -841 -191 30 513 406 522 304 447 -146 -253 207 92 61 213 149 -310 -479 -580 -643 61 202 -858 -688 -130 153 851 1166 946 582 429 265 171 382 333 384 284 -220 -168 99 70 -218 3 -441 -224 19 -431 -564 -616 -676 -138 233 143 12 447 288 77 35 -73 -304 0 -101 -184 -153 -281 64 -3 -120 -187 -301 -411 -279 -20 -255 -122 5 -56 173 503 438 614 314 538 632 310 211 -38 -484 -251 -24 73 10 -45 -292 -1318 -1084 -629 -711 -427 -323 -594 -495 -135 83 -76 261 9 -224 -212 -136 287 533 443 771 704 578 910 569 310 513 761 1090 1353 1101 790 -306 -33 73 240 945 300 -219 -148 -280 -98 -573 -813 -972 -1090 -988 -1474 -1783 -1947 -1970 -950 -209 35 630 514 658 371 510 -166 -264 207 95 68 240 183 -401 -617 -705 -794 72 248 -1039 -884 -174 212 1226 1758 1367 845 649 374 223 467 404 485 382 -317 -250 146 100 -302 5 -555 -294 24 -540 -751 -853 -955 -198 346 223 20 695 456 124 55 -122 -491 0 SS 20210625T144604.8Z 7846.615333 315 1 43.97 2 37.62 110.10 135.33 276.23 0.00 1 0.00 1 0 17 8.517e-03 6.385e-03 1.337e-03 7.146e-04 1.733945e-01 3.828521e-04 2.093334e-03 -6.000000e+00 5.214035e-03 232.94 -2.00 3.57 -2.00 316.04 0.00e+00 4.952163e-04 4.036416e-05 1.114329e-04 -6.000000e+00 2.285160e-04 284.98 -2.00 20.00 -2.00 315.29 0.00e+00 1.261 0.000 302.00 328.00 3 3.8894e+00 1.0024e-03 1.5464e-02 -6.0000e+00 1.3093e-02 4.7068e-03 1.1134e-03 9.1534e-03 -6.0000e+00 1.4137e-02 -8.3657e-03 6.3541e-04 4.4116e-03 -6.0000e+00 8.4014e-03 -1.1500e-03 2.8125e-04 1.1998e-03 -6.0000e+00 3.4775e-03 2.6709e-03 -1.3637e-04 2.2939e-05 1.6545e-05 -6.0000e+00 2.6206e-04 -1.2291e-02 0.0000e+00 12 1 1 12 1 1 99.94 15.00 0.19 -0.01229 -0.01332 124 27 1 5 0 350.380 21.88 15.00 18.72 -663 -625 -695 -867 1040 -578 -826 -728 -1286 -1816 -1211 -575 -673 -270 -14 -160 752 1491 1176 1516 866 1173 1816 963 560 -152 -1222 -520 -15 439 -121 9 -936 -3070 -2774 -1295 -1711 -693 -646 -1026 -819 20 78 -234 355 165 -591 -279 -215 363 578 611 863 841 785 1108 829 358 716 969 1289 1685 1266 725 -243 -256 209 357 1273 360 -350 -100 -169 -22 -694 -932 -1274 -1339 -1297 -1570 -1931 -1883 -1896 -870 -243 101 455 466 513 264 371 -133 -372 261 -8 -17 293 193 -304 -557 -579 -719 37 208 -744 -637 -158 108 848 1104 1006 671 496 347 101 462 207 306 180 -118 -128 75 116 -237 47 -310 -309 62 -499 -536 -606 -606 -140 218 135 20 414 298 95 83 -62 -367 -36 -153 -154 -171 -200 214 -114 -169 -165 -319 -467 -308 -147 -186 -83 -5 -58 280 563 457 602 351 474 734 407 249 -69 -552 -221 -6 167 -47 4 -410 -1378 -1196 -541 -769 -358 -357 -647 -560 14 57 -171 258 119 -417 -190 -142 237 388 433 641 647 618 887 672 290 573 774 1058 1462 1176 704 -235 -231 173 284 1060 334 -354 -105 -178 -23 -668 -817 -1015 -1011 -1004 -1333 -1824 -1936 -2076 -913 -269 120 567 596 655 327 428 -153 -392 264 -9 -19 334 238 -396 -722 -708 -820 44 235 -905 -822 -212 150 1229 1545 1458 976 695 490 131 566 252 387 243 -169 -190 111 168 -329 62 -390 -406 81 -626 -712 -838 -853 -200 323 209 30 642 471 152 131 -96 -592 -57 SS 20210625T145526.4Z 7846.621834 318 1 50.45 2 36.05 112.54 136.91 277.99 0.00 1 0.00 1 0 17 8.291e-03 6.263e-03 5.156e-04 2.732e-04 1.696312e-01 1.473287e-04 2.034347e-03 -6.000000e+00 5.075389e-03 232.94 -2.00 3.57 -2.00 316.12 0.00e+00 5.295665e-04 1.565624e-05 1.169722e-04 -6.000000e+00 2.224411e-04 284.98 -2.00 20.00 -2.00 315.37 0.00e+00 1.236 0.000 302.00 328.00 3 2.0961e+00 3.8615e-04 1.5119e-02 -6.0000e+00 1.2745e-02 -3.2790e-03 4.2955e-04 8.9034e-03 -6.0000e+00 1.3761e-02 -8.4542e-03 2.4454e-04 4.2933e-03 -6.0000e+00 8.1780e-03 -9.8435e-04 1.0777e-04 1.1801e-03 -6.0000e+00 3.3850e-03 1.6627e-02 -1.4252e-04 8.8173e-06 1.5913e-05 -6.0000e+00 2.5509e-04 -1.2247e-02 0.0000e+00 10 0 0 10 0 0 99.89 15.00 0.17 -0.01225 -0.01332 1118 208 1 5 0 45.080 21.88 15.00 18.72 -868 -794 -576 -1237 554 -138 -491 -624 -1072 -1777 -1163 -173 -528 -317 28 -311 599 1475 1156 1412 933 1324 1538 852 432 -119 -1134 -626 -3 341 -99 -185 -741 -3040 -2573 -1376 -1794 -637 -683 -988 -783 -80 21 -92 423 62 -318 -243 -172 505 759 566 1039 909 760 1122 846 392 698 947 1495 1637 1279 728 -299 -156 118 141 1188 212 -256 -162 -239 -153 -571 -874 -1208 -1385 -1114 -1614 -1960 -1776 -1871 -816 -239 30 445 451 420 263 363 -174 -279 220 42 22 194 167 -327 -540 -552 -688 96 149 -786 -700 -90 186 864 1164 961 553 484 243 180 393 322 305 202 -182 -139 66 24 -199 35 -365 -312 37 -463 -566 -642 -654 -132 202 101 28 452 282 30 53 -68 -327 6 -200 -195 -141 -285 114 -27 -100 -140 -264 -454 -293 -44 -144 -96 9 -112 221 550 444 554 373 527 615 355 189 -54 -504 -263 -1 128 -38 -75 -318 -1340 -1087 -565 -793 -323 -408 -611 -525 -56 15 -66 301 43 -219 -162 -111 322 497 392 753 683 586 877 670 310 545 739 1197 1390 1162 691 -283 -137 95 110 966 192 -252 -166 -246 -153 -536 -748 -939 -1123 -923 -1337 -1805 -1777 -1996 -910 -282 35 540 564 523 318 409 -196 -286 217 43 24 235 201 -414 -681 -657 -834 112 180 -934 -883 -119 253 1220 1720 1471 850 715 335 228 512 416 410 266 -255 -201 95 34 -269 45 -489 -401 47 -617 -799 -865 -897 -184 291 153 44 739 470 50 88 -110 -514 9 SS 20210625T150245.3Z 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