File name: Pandora104s1_Downsview_20171206_L2Fit_fwvt1c2d20130709p1-8.txt File generation date: 20241124T021130.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 104 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora104_OF_v2d20171009.txt Instrument calibration file used: Pandora104s1_CF_v2d20130709.txt Level 1 file used: Pandora104s1_Downsview_20171206_L1_smca1c2d20130709p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20171206 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB-data based on session 5 First and last pixel inside fitting window: 1634 1784 Nominal wavelengths inside fitting window [nm]: 492.1188 492.2393 492.3597 492.4802 492.6006 492.7210 492.8414 492.9618 493.0821 493.2025 493.3228 493.4431 493.5634 493.6837 493.8039 493.9242 494.0444 494.1646 494.2848 494.4049 494.5251 494.6452 494.7654 494.8854 495.0055 495.1256 495.2456 495.3657 495.4857 495.6057 495.7257 495.8456 495.9656 496.0855 496.2054 496.3253 496.4452 496.5650 496.6849 496.8047 496.9245 497.0443 497.1641 497.2838 497.4036 497.5233 497.6430 497.7627 497.8823 498.0020 498.1216 498.2412 498.3608 498.4804 498.6000 498.7195 498.8390 498.9586 499.0780 499.1975 499.3170 499.4364 499.5558 499.6753 499.7946 499.9140 500.0334 500.1527 500.2720 500.3913 500.5106 500.6299 500.7491 500.8684 500.9876 501.1068 501.2260 501.3451 501.4643 501.5834 501.7025 501.8216 501.9407 502.0597 502.1788 502.2978 502.4168 502.5358 502.6548 502.7737 502.8926 503.0116 503.1305 503.2493 503.3682 503.4871 503.6059 503.7247 503.8435 503.9623 504.0810 504.1998 504.3185 504.4372 504.5559 504.6746 504.7932 504.9119 505.0305 505.1491 505.2677 505.3862 505.5048 505.6233 505.7418 505.8603 505.9788 506.0973 506.2157 506.3341 506.4525 506.5709 506.6893 506.8076 506.9260 507.0443 507.1626 507.2809 507.3992 507.5174 507.6356 507.7538 507.8720 507.9902 508.1084 508.2265 508.3447 508.4628 508.5808 508.6989 508.8170 508.9350 509.0530 509.1710 509.2890 509.4070 509.5249 509.6429 509.7608 509.8787 509.9965 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20171206T124338.0Z 6549.530301 1 1 32.00 2 89.88 122.22 63.67 271.10 0.00 1 0.00 1 0 15 2.218e-02 2.214e-02 1.931e-02 1.925e-02 7.329966e+02 1.031198e+03 1.034962e+02 -6.000000e+00 1.171779e+03 274.77 -2.00 20.00 -2.00 505.34 0.00e+00 4.895295e-03 5.181686e-04 2.239028e-04 -6.000000e+00 6.062993e-04 274.77 -2.00 20.00 -2.00 500.84 0.00e+00 2.430607e+00 3.717671e-01 3.624310e-02 -6.000000e+00 4.355815e-01 222.30 -2.00 3.57 -2.00 502.36 0.00e+00 20.514 0.168 489.00 513.00 1 6.9891e+00 2.8447e-02 3.7638e-02 -6.0000e+00 3.3251e-02 5.1810e-02 7.3244e-03 2.0577e-03 -6.0000e+00 8.7454e-03 8.1145e-05 1.7250e-03 1.7078e-03 6.7751e-05 -6.0000e+00 1.9950e-03 3.1749e-02 -6.4017e-06 12 8 8 10 0 0 -84.49 21.79 4.15 0.03175 0.04371 8 2 1 4 0 4000.000 21.79 15.00 18.90 -4397 -2349 -1066 283 -2366 223 -1531 1624 -1024 -2172 2748 -1586 567 -1383 -88 -400 712 -1064 2368 -916 465 -3689 19 -711 2660 1243 1884 -382 515 -971 1316 563 2155 2515 -1233 -2361 -1733 228 -3958 1601 1011 1633 -362 972 3117 1144 2445 2063 2513 679 434 -2061 -732 -4208 2931 559 5004 -3367 4382 -332 2639 -1787 1238 316 -224 333 307 1350 -1710 1109 -2020 2533 -2873 2017 -2788 1381 -4586 486 -1754 1813 -254 -3256 -3402 606 -1048 -737 -197 4292 -1505 816 4361 1055 2956 -573 3805 -1584 3954 851 879 -4587 2051 -3846 244 -2383 -4112 2325 -1096 -1149 3945 3196 2921 3499 -2009 5498 -1799 705 1693 1159 -1185 -1787 -3059 -582 -1733 1371 267 1749 -401 -937 -2301 783 -1560 1157 2930 -1584 -212 -3349 -1152 -2750 -859 -2303 1658 1806 2123 -941 3064 -2326 1630 62 -3252 -168 900000 -4151 -2246 -987 266 -2323 218 -1542 1588 -1015 -2135 2546 -1511 522 -1288 -81 -374 672 -1055 2304 -920 462 -3826 19 -727 2641 1248 1871 -382 492 -914 1213 530 2073 2508 -1292 -2484 -1794 229 -4119 1579 1013 1649 -379 1018 3220 1204 2514 2099 2500 669 417 -1998 -699 -4262 2868 576 5013 -3671 4419 -351 2723 -1941 1306 335 -236 343 311 1341 -1733 1074 -2010 2425 -2935 1996 -2901 1355 -4671 465 -1710 1702 -245 -3262 -3420 591 -1049 -737 -196 4066 -1511 804 4190 1071 2997 -603 3787 -1641 3804 824 832 -4483 1875 -3789 239 -2343 -4145 2176 -1046 -1082 3738 3106 2748 3343 -2067 5318 -1885 725 1737 1195 -1236 -1846 -3163 -580 -1752 1364 270 1744 -410 -962 -2394 795 -1608 1138 2790 -1564 -206 -3425 -1182 -2916 -905 -2490 1730 1886 2227 -1024 3207 -2552 1683 63 -3360 -169 900000 SO 20171206T124536.0Z 6549.531667 3 1 32.00 2 89.58 122.56 64.01 271.42 0.00 1 0.00 1 0 15 1.111e-02 1.103e-02 7.289e-03 7.213e-03 4.840994e+03 4.294524e+02 3.228413e+02 -6.000000e+00 5.868330e+02 274.77 -2.00 20.00 -2.00 505.52 0.00e+00 6.650669e-03 1.961101e-04 3.439510e-04 -6.000000e+00 3.036343e-04 274.77 -2.00 20.00 -2.00 501.37 0.00e+00 1.775640e+00 1.369619e-01 7.122168e-02 -6.000000e+00 2.181570e-01 222.30 -2.00 3.57 -2.00 502.85 0.00e+00 20.058 0.157 489.00 513.00 1 6.0336e+00 1.0423e-02 3.7090e-02 -6.0000e+00 1.6653e-02 -2.3334e-02 2.6603e-03 2.2838e-03 -6.0000e+00 4.3805e-03 2.2948e-04 2.6348e-03 6.3772e-04 1.0944e-04 -6.0000e+00 9.9941e-04 3.0912e-02 -7.2704e-06 12 8 8 10 0 0 56.15 21.79 6.57 0.03091 0.04919 8 2 1 4 0 4000.000 21.79 15.00 18.92 -2212 -3648 -1183 437 318 429 1523 -525 670 -136 -726 -733 -2538 -885 -463 -1197 224 1044 -1168 271 -200 730 104 1518 2105 1653 -142 -314 -1309 -369 -1033 -1251 168 1302 -192 383 468 9 1454 921 968 1476 930 276 1189 53 974 684 -650 -347 -993 -410 5 -871 208 476 -738 1004 68 998 1383 2547 1445 722 -92 1481 -782 -800 501 -435 -865 -776 -848 -143 -825 -125 -1464 -2427 -1334 -1719 -658 -1020 750 -1410 -253 -522 -90 -902 609 78 239 -100 1309 2189 356 1350 411 -991 -1409 -742 -2493 -676 -1358 442 -505 395 -733 -633 -865 -98 285 1051 1627 1714 2605 1424 1539 752 1537 737 848 -309 771 -550 -465 -1651 550 -1334 342 1182 -150 -320 180 -1759 -1467 -324 -791 -346 -1173 738 1000 241 506 1804 187 291 -145 -756 -2355 -1559 900000 -1818 -3151 -1040 388 289 399 1416 -499 621 -125 -663 -660 -2300 -784 -409 -1079 204 971 -1128 258 -192 696 101 1465 2033 1602 -139 -305 -1235 -336 -951 -1171 161 1196 -182 357 433 8 1314 842 896 1383 891 271 1168 52 952 662 -627 -325 -914 -370 5 -813 200 469 -749 1004 69 1000 1394 2559 1472 739 -94 1464 -779 -791 484 -418 -832 -753 -833 -142 -826 -122 -1422 -2355 -1277 -1649 -630 -986 714 -1387 -249 -515 -88 -889 591 76 237 -102 1336 2214 361 1328 399 -953 -1335 -684 -2341 -635 -1335 444 -519 401 -744 -635 -873 -100 297 1112 1741 1856 2817 1573 1719 850 1710 814 924 -336 832 -611 -521 -1875 615 -1517 384 1323 -169 -354 196 -1937 -1614 -360 -846 -374 -1296 811 1102 269 567 2005 211 326 -160 -819 -2550 -1683 900000 SO 20171206T124724.0Z 6549.532917 5 1 32.00 2 89.30 122.88 64.33 271.72 0.00 1 0.00 1 0 15 7.819e-03 7.635e-03 3.865e-03 3.821e-03 4.698737e+03 2.262810e+02 3.323742e+02 -6.000000e+00 4.130205e+02 274.77 -2.00 20.00 -2.00 505.51 0.00e+00 7.401527e-03 1.039380e-04 3.817489e-04 -6.000000e+00 2.136992e-04 274.77 -2.00 20.00 -2.00 501.42 0.00e+00 1.561030e+00 7.228046e-02 7.288618e-02 -6.000000e+00 1.534956e-01 222.30 -2.00 3.57 -2.00 502.87 0.00e+00 19.524 0.145 489.00 513.00 1 5.3893e+00 5.5083e-03 3.5775e-02 -6.0000e+00 1.1718e-02 -3.8155e-02 1.4040e-03 2.1961e-03 -6.0000e+00 3.0808e-03 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