File name: Pandora104s1_Downsview_20171210_L2Fit_fwvt1c2d20130709p1-8.txt File generation date: 20241124T021358.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 104 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora104_OF_v2d20171009.txt Instrument calibration file used: Pandora104s1_CF_v2d20130709.txt Level 1 file used: Pandora104s1_Downsview_20171210_L1_smca1c2d20130709p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20171210 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB-data based on session 5 First and last pixel inside fitting window: 1634 1784 Nominal wavelengths inside fitting window [nm]: 492.1188 492.2393 492.3597 492.4802 492.6006 492.7210 492.8414 492.9618 493.0821 493.2025 493.3228 493.4431 493.5634 493.6837 493.8039 493.9242 494.0444 494.1646 494.2848 494.4049 494.5251 494.6452 494.7654 494.8854 495.0055 495.1256 495.2456 495.3657 495.4857 495.6057 495.7257 495.8456 495.9656 496.0855 496.2054 496.3253 496.4452 496.5650 496.6849 496.8047 496.9245 497.0443 497.1641 497.2838 497.4036 497.5233 497.6430 497.7627 497.8823 498.0020 498.1216 498.2412 498.3608 498.4804 498.6000 498.7195 498.8390 498.9586 499.0780 499.1975 499.3170 499.4364 499.5558 499.6753 499.7946 499.9140 500.0334 500.1527 500.2720 500.3913 500.5106 500.6299 500.7491 500.8684 500.9876 501.1068 501.2260 501.3451 501.4643 501.5834 501.7025 501.8216 501.9407 502.0597 502.1788 502.2978 502.4168 502.5358 502.6548 502.7737 502.8926 503.0116 503.1305 503.2493 503.3682 503.4871 503.6059 503.7247 503.8435 503.9623 504.0810 504.1998 504.3185 504.4372 504.5559 504.6746 504.7932 504.9119 505.0305 505.1491 505.2677 505.3862 505.5048 505.6233 505.7418 505.8603 505.9788 506.0973 506.2157 506.3341 506.4525 506.5709 506.6893 506.8076 506.9260 507.0443 507.1626 507.2809 507.3992 507.5174 507.6356 507.7538 507.8720 507.9902 508.1084 508.2265 508.3447 508.4628 508.5808 508.6989 508.8170 508.9350 509.0530 509.1710 509.2890 509.4070 509.5249 509.6429 509.7608 509.8787 509.9965 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20171210T124724.0Z 6553.532917 1 1 32.00 2 89.88 122.84 41.73 209.12 0.00 1 0.00 1 0 29 1.503e-01 1.342e-01 1.349e-01 1.281e-01 7.918445e+03 8.624095e+03 5.740601e+02 -6.000000e+00 7.926313e+03 274.31 -2.00 20.00 -2.00 505.18 0.00e+00 -6.776162e-04 3.378793e-03 2.592735e-05 -6.000000e+00 4.104669e-03 274.31 -2.00 20.00 -2.00 499.75 0.00e+00 1.300131e-01 2.564419e+00 4.314025e-02 -6.000000e+00 2.956399e+00 222.25 -2.00 3.57 -2.00 501.43 0.00e+00 20.525 0.168 489.00 513.00 1 9.1809e+00 1.9560e-01 3.7205e-02 -6.0000e+00 2.2565e-01 1.9788e-01 4.9929e-02 2.0586e-03 -6.0000e+00 5.9339e-02 1.1164e-05 3.2767e-02 1.0827e-02 5.9902e-05 -6.0000e+00 1.3517e-02 4.0767e-02 -1.0500e-03 12 8 8 10 0 0 59.89 21.58 -1.59 0.04077 0.26806 8 2 1 4 0 4000.000 21.58 15.00 18.62 10734 -13289 19980 2880 929 17220 -3103 3109 -14791 -4852 -4805 20954 5302 -2578 -1074 15191 -1763 11290 -10540 18425 -1698 19964 -5222 -3675 -12866 16195 -8693 8859 19696 -15316 10255 16009 -12133 4968 -20615 1926 -510 -5925 27206 1524 -3389 -11535 37380 5418 14211 -11565 7721 16204 16029 -8757 2070 -16502 -4291 22320 -4373 12587 15381 -5743 -7562 21409 -8789 14580 -23301 -2462 -1365 -9483 -26432 -9627 31107 998 3771 13130 13882 -4626 23972 -2218 9577 39001 -2398 -12651 7683 -8969 53543 -22540 21361 -2744 8883 -22237 19927 -7331 7465 -4063 6165 1486 24972 24106 -12672 6572 -6597 -3161 -14076 8267 -2194 -2987 -7267 14605 -3131 1569 -13500 -571 26557 -6806 8664 1576 1624 -18107 35633 -1159 6385 6819 31841 -6977 13902 -12239 28115 2431 37652 8042 8977 -11555 -10024 4746 -1181 13458 -17313 14309 -9303 7484 12328 -5119 6887 28272 -19358 -8884 -7183 19932 -5161 14059 -988 -5102 13289 10022 -16369 18184 3164 1064 17024 -3774 3537 -19728 -5786 -5655 18742 5491 -2872 -1188 14541 -2061 11870 -13811 18070 -2039 19266 -6514 -4527 -16246 16137 -10981 9106 17462 -19106 9977 15073 -14873 5574 -28010 2191 -589 -6694 23267 1686 -3728 -13884 29621 5601 14272 -14005 8057 15256 14714 -9376 2063 -18401 -4278 18738 -4650 12246 14602 -6319 -8432 18981 -9995 13135 -30627 -2600 -1401 -10363 -33767 -10308 23186 936 3453 11053 11788 -4782 19561 -2162 8133 26010 -2266 -13265 6638 -9206 31507 -27131 16720 -2736 7871 -26766 15745 -7633 6781 -4200 5736 1416 18256 17266 -12727 5338 -5992 -2754 -13928 6776 -2106 -3000 -7674 12295 -3098 1460 -14654 -552 19807 -7137 7805 1525 1571 -21527 24997 -1172 5894 6143 21867 -6956 11292 -13014 19930 2226 24189 6889 7624 -12031 -10066 4030 -1055 10336 -18282 11306 -9480 6521 10378 -5179 6204 20668 -21600 -9447 -7479 15602 -5068 11108 -898 -4860 10696 SO 20171210T124922.0Z 6553.534282 3 1 31.99 2 89.58 123.18 41.91 209.79 0.00 1 0.00 1 0 43 1.633e-01 1.465e-01 1.234e-01 1.173e-01 -6.949732e+03 6.506075e+03 6.055362e+02 -6.000000e+00 8.616429e+03 274.31 -2.00 20.00 -2.00 505.28 0.00e+00 4.099196e-03 3.124481e-03 1.977639e-04 -6.000000e+00 4.456571e-03 274.31 -2.00 20.00 -2.00 500.18 0.00e+00 7.226419e+00 2.346774e+00 6.113541e-02 -6.000000e+00 3.188458e+00 222.25 -2.00 3.57 -2.00 501.81 0.00e+00 20.072 0.158 489.00 513.00 1 8.5754e+00 1.7906e-01 3.6341e-02 -6.0000e+00 2.4364e-01 4.1668e-02 4.5952e-02 2.4385e-03 -6.0000e+00 6.3561e-02 1.2347e-05 5.7029e-03 9.9665e-03 9.6274e-05 -6.0000e+00 1.4656e-02 6.9899e-03 5.7998e-04 12 9 8 11 8 0 79.11 21.58 -1.71 0.00699 0.04655 8 2 1 4 0 4000.000 21.58 14.99 18.65 47 1917 20714 3399 -8492 -5787 17177 5615 -2496 1669 -17167 7463 -11078 -28624 7281 16118 -10368 28863 -3240 31650 -5957 11403 1457 6673 -3904 18095 12393 -1297 16165 -10582 8767 -15729 23010 -16739 26747 -17469 2403 -5181 22248 14923 16755 -4539 23949 11254 11138 -11806 -934 7970 -14168 10042 -24663 23551 1635 -5862 -18587 12467 -7535 23954 10902 37873 -6484 -290 1302 3931 11464 15759 9581 -12530 -5288 -14354 1717 -14708 26285 2076 1901 -13100 15451 -2160 13569 -6580 11197 -15545 2434 38103 303 -4189 4675 12107 6915 32787 -6933 8996 -9529 3493 -10347 18401 57 28868 -7491 2865 -13230 21158 -17014 9963 -13227 -13949 11767 -21476 49266 -17184 39877 -15716 12839 -6906 14567 -945 29378 6929 24422 3892 37014 11529 3787 8176 -11241 -740 -18226 6465 -8676 13955 -18524 22639 -15643 43 -15584 21132 4971 7120 -24783 5576 -1971 49512 14075 25952 1473 -1224 16443 -7992 6611 -14871 900000 45 1901 18734 3493 -10068 -6778 16045 5850 -2762 1751 -21463 7186 -12736 -39079 7011 14477 -12516 24058 -3725 25699 -7063 11389 1623 7096 -4600 17033 12200 -1417 14286 -12166 8378 -19778 20502 -22611 23255 -23347 2608 -5994 19503 14154 15772 -5348 21510 11564 11444 -15100 -1053 8075 -17408 9380 -31899 18615 1633 -6529 -24173 12094 -8934 20654 10654 28302 -7594 -319 1403 4067 10791 13928 8881 -14315 -5509 -16193 1653 -16804 20209 2043 1844 -14402 12545 -2080 11115 -6619 9493 -17201 2256 24915 290 -4184 4267 10266 6211 22852 -7323 8274 -10681 3438 -11673 15469 56 20743 -7536 2573 -13242 16267 -18525 8806 -13596 -14150 9638 -22947 27966 -18245 26075 -17324 11531 -7192 13084 -933 22587 6186 19128 3501 25266 9590 3457 7188 -12011 -716 -20954 5815 -9153 11703 -21171 17893 -16820 39 -16862 16292 4605 6549 -31677 5280 -2013 32375 12469 20534 1485 -1242 13566 -8215 5857 -16594 900000 SO 20171210T125116.0Z 6553.535602 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