File name: Pandora104s1_Downsview_20171212_L2Fit_fwvt1c2d20130709p1-8.txt File generation date: 20241124T021443.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 104 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora104_OF_v2d20171009.txt Instrument calibration file used: Pandora104s1_CF_v2d20130709.txt Level 1 file used: Pandora104s1_Downsview_20171212_L1_smca1c2d20130709p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20171212 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB-data based on session 5 First and last pixel inside fitting window: 1634 1784 Nominal wavelengths inside fitting window [nm]: 492.1188 492.2393 492.3597 492.4802 492.6006 492.7210 492.8414 492.9618 493.0821 493.2025 493.3228 493.4431 493.5634 493.6837 493.8039 493.9242 494.0444 494.1646 494.2848 494.4049 494.5251 494.6452 494.7654 494.8854 495.0055 495.1256 495.2456 495.3657 495.4857 495.6057 495.7257 495.8456 495.9656 496.0855 496.2054 496.3253 496.4452 496.5650 496.6849 496.8047 496.9245 497.0443 497.1641 497.2838 497.4036 497.5233 497.6430 497.7627 497.8823 498.0020 498.1216 498.2412 498.3608 498.4804 498.6000 498.7195 498.8390 498.9586 499.0780 499.1975 499.3170 499.4364 499.5558 499.6753 499.7946 499.9140 500.0334 500.1527 500.2720 500.3913 500.5106 500.6299 500.7491 500.8684 500.9876 501.1068 501.2260 501.3451 501.4643 501.5834 501.7025 501.8216 501.9407 502.0597 502.1788 502.2978 502.4168 502.5358 502.6548 502.7737 502.8926 503.0116 503.1305 503.2493 503.3682 503.4871 503.6059 503.7247 503.8435 503.9623 504.0810 504.1998 504.3185 504.4372 504.5559 504.6746 504.7932 504.9119 505.0305 505.1491 505.2677 505.3862 505.5048 505.6233 505.7418 505.8603 505.9788 506.0973 506.2157 506.3341 506.4525 506.5709 506.6893 506.8076 506.9260 507.0443 507.1626 507.2809 507.3992 507.5174 507.6356 507.7538 507.8720 507.9902 508.1084 508.2265 508.3447 508.4628 508.5808 508.6989 508.8170 508.9350 509.0530 509.1710 509.2890 509.4070 509.5249 509.6429 509.7608 509.8787 509.9965 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20171212T124907.0Z 6555.534109 1 1 32.00 2 89.87 123.08 47.09 175.73 0.00 1 0.00 1 0 55 4.297e-01 2.718e-01 3.570e-01 2.788e-01 5.893546e+03 1.664284e+04 2.445221e+02 -6.000000e+00 2.262399e+04 274.09 -2.00 20.00 -2.00 504.98 0.00e+00 -1.147865e-02 7.262233e-03 3.445017e-04 -6.000000e+00 1.171325e-02 274.09 -2.00 20.00 -2.00 499.78 0.00e+00 -3.065456e+00 5.478854e+00 1.295442e-01 -6.000000e+00 8.429056e+00 222.22 -2.00 3.57 -2.00 501.38 0.00e+00 20.529 0.169 489.00 513.00 1 1.0361e+01 4.1741e-01 3.9354e-02 -6.0000e+00 6.4356e-01 2.7095e-01 1.1439e-01 2.7502e-03 -6.0000e+00 1.6877e-01 4.6727e-06 -5.8340e-02 2.2767e-02 1.7104e-04 -6.0000e+00 3.8678e-02 1.5149e-01 -1.5183e-03 12 8 8 10 0 0 48.64 21.69 14.21 0.15149 -0.25318 8 2 1 4 0 4000.000 21.69 15.00 18.80 20537 -13408 40792 -19522 10951 -10755 35510 8194 35167 31102 -6371 6300 19727 11190 27035 -25962 97753 17667 40641 41842 59610 108039 -29066 39592 -2784 -5589 -17617 -11437 -28475 27303 24481 21332 36416 76726 -10491 42295 1990 -13881 -21887 55473 6169 22120 32218 -17307 -2513 -10249 8583 -25678 7292 -1574 -7595 61310 42555 -14623 41113 -4821 -29704 40608 5249 36226 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-502 11935 -31626 -39659 -26662 47070 -2145 12411 49498 23220 -10002 3062 38399 -26703 17512 -10252 8637 -37357 -34051 -24787 35203 -1102 -2583 13681 -843 43731 -15872 9564 -7261 28994 -65080 11230 -15193 29887 -5784 43060 34970 34798 -45371 23674 -23198 18374 -17529 14465 37740 1969 37108 11267 42562 35516 27441 34195 16216 25066 39596 15363 -45582 20596 27309 -46068 27126 27966 -6588 13655 11998 25733 9203 -33619 37240 27069 24615 87 -11515 24425 -8323 -4173 -11526 10285 -3953 SO 20171212T125104.0Z 6555.535463 3 1 32.00 2 89.58 123.42 47.07 176.39 0.00 1 0.00 1 0 69 3.456e-01 2.523e-01 3.341e-01 2.779e-01 -1.295480e+04 1.544675e+04 2.619621e+03 -6.000000e+00 1.823684e+04 274.09 -2.00 20.00 -2.00 505.07 0.00e+00 6.435457e-03 7.258310e-03 9.511760e-04 -6.000000e+00 9.433720e-03 274.09 -2.00 20.00 -2.00 499.78 0.00e+00 1.499693e+00 5.775100e+00 2.538542e-01 -6.000000e+00 6.763564e+00 222.22 -2.00 3.57 -2.00 501.40 0.00e+00 20.081 0.158 489.00 513.00 1 9.8591e+00 4.4109e-01 4.7050e-02 -6.0000e+00 5.1675e-01 2.3403e-01 1.1419e-01 5.8654e-03 -6.0000e+00 1.3492e-01 4.7821e-06 2.3901e-02 2.3963e-02 5.2248e-04 -6.0000e+00 3.1099e-02 -3.0639e-01 2.4404e-03 12 8 8 10 0 0 -130.29 21.69 21.32 -0.30639 -0.14060 8 2 1 4 0 4000.000 21.69 15.00 18.82 53697 -27966 -10350 16850 65138 -17838 -12364 47475 43128 5779 7031 -8063 -14622 -8886 95244 -8244 14108 16002 -8813 24586 -21564 3094 42162 23687 -14994 35854 -23858 11105 -742 6393 35913 -6309 -28861 -10784 28388 17792 45946 4014 32165 -700 2109 -16005 19487 1704 15401 -20809 44366 44297 21226 48941 9897 24564 41492 52185 -22610 -11846 -29411 -21519 -9764 12629 10964 -23377 11329 24349 -12654 45752 -3253 53697 3499 -23856 -29640 -1234 4763 63067 24474 79733 38700 17694 6248 7122 27534 39530 -13973 -20985 21597 593 30711 85822 -13637 -8805 -27869 56704 8689 26156 -9549 47125 -1380 132535 -1530 -39810 55982 -8775 -21052 23389 -12471 34985 39321 -9468 78077 13452 14798 17372 52778 3246 5850 -19949 45811 33615 7765 32533 21494 -16980 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34951 35403 22629 23934 -33738 -4940 -20555 31159 20473 -16398 -37115 -1625 -15865 12325 -16523 32673 900000 SO 20171212T125259.0Z 6555.536794 5 1 32.00 2 89.29 123.75 47.06 177.03 0.00 1 0.00 1 0 57 2.483e-01 2.037e-01 2.474e-01 2.221e-01 -6.299736e+03 1.283959e+04 7.845772e+02 -6.000000e+00 1.308369e+04 274.09 -2.00 20.00 -2.00 505.22 0.00e+00 4.641668e-03 6.077969e-03 2.160836e-04 -6.000000e+00 6.775904e-03 274.09 -2.00 20.00 -2.00 499.66 0.00e+00 6.733961e+00 4.525102e+00 4.642279e-02 -6.000000e+00 4.875159e+00 222.22 -2.00 3.57 -2.00 501.41 0.00e+00 19.516 0.145 489.00 513.00 1 9.3578e+00 3.4802e-01 3.4587e-02 -6.0000e+00 3.7214e-01 8.3836e-02 8.6074e-02 2.1786e-03 -6.0000e+00 9.7781e-02 6.0774e-06 6.2622e-02 2.0415e-02 7.6448e-05 -6.0000e+00 2.2325e-02 -6.3669e-02 6.2950e-04 12 9 8 11 8 0 91.01 21.79 3.64 -0.06367 0.37070 8 2 1 4 0 4000.000 21.79 15.00 18.83 9761 11972 -1868 -11743 -11034 -22489 43265 -423 3150 -21786 -10013 -3220 -21396 -9880 17360 -20897 13209 33657 -9092 15647 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