File name: Pandora104s1_Downsview_20171213_L2Fit_fwvt1c2d20130709p1-8.txt File generation date: 20241124T021336.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 104 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora104_OF_v2d20171009.txt Instrument calibration file used: Pandora104s1_CF_v2d20130709.txt Level 1 file used: Pandora104s1_Downsview_20171213_L1_smca1c2d20130709p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20171213 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB-data based on session 5 First and last pixel inside fitting window: 1634 1784 Nominal wavelengths inside fitting window [nm]: 492.1188 492.2393 492.3597 492.4802 492.6006 492.7210 492.8414 492.9618 493.0821 493.2025 493.3228 493.4431 493.5634 493.6837 493.8039 493.9242 494.0444 494.1646 494.2848 494.4049 494.5251 494.6452 494.7654 494.8854 495.0055 495.1256 495.2456 495.3657 495.4857 495.6057 495.7257 495.8456 495.9656 496.0855 496.2054 496.3253 496.4452 496.5650 496.6849 496.8047 496.9245 497.0443 497.1641 497.2838 497.4036 497.5233 497.6430 497.7627 497.8823 498.0020 498.1216 498.2412 498.3608 498.4804 498.6000 498.7195 498.8390 498.9586 499.0780 499.1975 499.3170 499.4364 499.5558 499.6753 499.7946 499.9140 500.0334 500.1527 500.2720 500.3913 500.5106 500.6299 500.7491 500.8684 500.9876 501.1068 501.2260 501.3451 501.4643 501.5834 501.7025 501.8216 501.9407 502.0597 502.1788 502.2978 502.4168 502.5358 502.6548 502.7737 502.8926 503.0116 503.1305 503.2493 503.3682 503.4871 503.6059 503.7247 503.8435 503.9623 504.0810 504.1998 504.3185 504.4372 504.5559 504.6746 504.7932 504.9119 505.0305 505.1491 505.2677 505.3862 505.5048 505.6233 505.7418 505.8603 505.9788 506.0973 506.2157 506.3341 506.4525 506.5709 506.6893 506.8076 506.9260 507.0443 507.1626 507.2809 507.3992 507.5174 507.6356 507.7538 507.8720 507.9902 508.1084 508.2265 508.3447 508.4628 508.5808 508.6989 508.8170 508.9350 509.0530 509.1710 509.2890 509.4070 509.5249 509.6429 509.7608 509.8787 509.9965 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20171213T124955.0Z 6556.534664 1 1 32.00 2 89.88 123.18 52.69 162.66 0.00 1 0.00 1 0 15 2.047e-02 2.017e-02 1.969e-02 1.960e-02 1.598467e+02 1.040134e+03 5.023136e+01 -6.000000e+00 1.077984e+03 273.97 -2.00 20.00 -2.00 505.25 0.00e+00 2.064135e-03 5.229104e-04 8.854816e-05 -6.000000e+00 5.582630e-04 273.97 -2.00 20.00 -2.00 500.41 0.00e+00 2.815057e+00 3.833889e-01 2.041205e-02 -6.000000e+00 4.017330e-01 222.21 -2.00 3.57 -2.00 501.99 0.00e+00 20.533 0.169 489.00 513.00 1 7.0212e+00 2.9321e-02 3.7250e-02 -6.0000e+00 3.0666e-02 9.5774e-02 7.6434e-03 2.0487e-03 -6.0000e+00 8.0519e-03 7.9390e-05 1.6193e-03 1.7173e-03 2.7899e-05 -6.0000e+00 1.8431e-03 7.2074e-03 2.3646e-04 12 8 8 10 0 0 18.11 21.69 2.35 0.00721 0.01844 8 2 1 4 0 4000.000 21.69 15.00 18.82 678 -1546 -672 -1292 783 -309 -1158 477 -1201 165 -888 2780 -2350 4332 -1882 -304 -1401 2130 -2190 -108 1991 33 -800 525 1536 1671 -736 -2870 2772 4497 5193 -1714 -208 -753 788 -2374 446 -3876 950 -1672 -574 3100 -2100 2712 -1036 1197 -1359 709 -1080 122 -3868 2079 2400 3305 -1516 91 1929 1068 -2078 -2207 1980 1483 2125 1207 -1087 -1140 4068 1819 -1791 -5134 2644 -2037 -1556 -1593 -64 289 -349 1191 2685 -800 -2316 1821 1360 -3410 -3814 484 -2413 2777 3406 257 872 1390 78 1448 985 829 1524 277 -2505 -3562 -2451 1387 916 752 -3365 -2431 -40 743 4457 -4093 -1094 3239 532 1321 727 -1079 821 1338 -213 2001 990 1056 892 1344 -1266 -2033 4256 123 -1901 -2062 -2785 798 -738 2765 -124 -2086 -1490 1851 528 -371 -134 -539 539 -830 1063 312 4617 -2308 -833 -2419 900000 651 -1566 -661 -1309 793 -323 -1235 501 -1267 169 -908 2697 -2371 4057 -1877 -303 -1443 2188 -2380 -115 2078 35 -862 564 1633 1765 -792 -3096 2719 4222 4858 -1741 -217 -818 851 -2617 473 -4247 983 -1774 -606 3190 -2304 2871 -1143 1287 -1480 744 -1132 122 -3924 1955 2242 3140 -1565 95 2001 1116 -2235 -2369 2051 1551 2209 1260 -1143 -1178 3925 1777 -1792 -5225 2482 -2018 -1552 -1616 -64 282 -336 1113 2463 -759 -2247 1707 1285 -3413 -3874 472 -2424 2641 3225 252 858 1388 80 1463 984 819 1463 263 -2388 -3364 -2298 1275 877 748 -3311 -2342 -37 712 4109 -4176 -1042 3010 516 1284 714 -1086 814 1318 -211 1900 938 988 838 1273 -1235 -1998 3937 118 -1862 -2033 -2737 742 -687 2460 -113 -1992 -1452 1772 519 -372 -134 -545 543 -852 1072 314 4355 -2268 -792 -2344 900000 SO 20171213T125153.0Z 6556.536030 3 1 32.00 2 89.58 123.52 52.60 163.25 0.00 1 0.00 1 0 15 1.117e-02 1.111e-02 9.503e-03 9.472e-03 3.402139e+03 5.525814e+02 2.253710e+02 -6.000000e+00 5.880436e+02 273.97 -2.00 20.00 -2.00 505.39 0.00e+00 4.667308e-03 2.547018e-04 2.321344e-04 -6.000000e+00 3.046063e-04 273.97 -2.00 20.00 -2.00 500.92 0.00e+00 2.304558e+00 1.822703e-01 4.966579e-02 -6.000000e+00 2.192735e-01 222.21 -2.00 3.57 -2.00 502.44 0.00e+00 20.082 0.158 489.00 513.00 1 6.3156e+00 1.3891e-02 3.6394e-02 -6.0000e+00 1.6736e-02 2.6185e-02 3.5563e-03 2.1164e-03 -6.0000e+00 4.3997e-03 1.7059e-04 9.5390e-04 8.3757e-04 7.4596e-05 -6.0000e+00 1.0038e-03 1.1212e-02 1.4897e-04 12 9 8 11 8 0 99.39 21.79 3.14 0.01121 0.01783 8 2 1 4 0 4000.000 21.79 15.00 18.84 -2332 -1532 -534 -1829 67 -575 -971 48 -466 635 -1748 -2717 -1439 731 -1150 -585 -998 83 344 820 968 1945 1283 1735 2192 827 1708 909 592 -970 -398 -234 1097 895 -662 -196 -501 648 -1055 -267 69 -761 2619 1155 -756 -898 1505 -304 -565 1202 -1542 -807 -1004 136 -48 -30 749 920 -578 -278 195 2759 1087 1093 523 1223 -69 721 -86 -358 -1362 58 -1344 -1402 -760 -1162 284 2066 357 -185 -5 353 114 407 106 906 -219 -338 81 -1502 -1265 1120 -63 671 496 402 678 1210 -341 -1585 -2471 588 919 1842 -1441 -818 -754 -413 -522 917 -1318 -529 893 -12 451 -179 -195 749 1451 2079 978 2578 378 1451 263 -73 564 -2171 122 -1426 218 -1182 -608 -1291 -2228 -65 746 -1405 1514 -613 909 43 1027 1724 -31 45 -1659 -749 -1434 -1585 900000 -2065 -1390 -500 -1783 65 -579 -992 49 -470 621 -1733 -2680 -1383 683 -1094 -561 -981 84 350 831 983 1960 1238 1687 2131 813 1656 875 551 -891 -364 -217 1041 887 -675 -198 -502 636 -1045 -263 68 -771 2605 1184 -796 -948 1535 -311 -570 1159 -1487 -760 -945 130 -47 -31 772 948 -604 -289 204 2828 1135 1138 541 1234 -70 713 -85 -348 -1334 57 -1342 -1424 -770 -1161 274 1932 339 -176 -4 339 110 395 104 888 -217 -334 79 -1506 -1278 1128 -65 690 503 401 659 1141 -320 -1474 -2320 545 881 1823 -1419 -796 -762 -411 -519 915 -1306 -531 897 -12 463 -186 -206 783 1493 2092 982 2515 377 1453 268 -74 577 -2278 125 -1496 224 -1203 -607 -1289 -2246 -66 765 -1496 1587 -665 976 47 1114 1867 -34 49 -1813 -790 -1494 -1659 900000 SO 20171213T125347.0Z 6556.537350 5 1 32.00 2 89.29 123.85 52.51 163.82 0.00 1 0.00 1 0 15 5.650e-03 5.649e-03 3.912e-03 3.886e-03 3.618303e+03 2.254465e+02 2.636862e+02 -6.000000e+00 2.977374e+02 273.97 -2.00 20.00 -2.00 505.43 0.00e+00 5.850784e-03 1.048045e-04 3.096418e-04 -6.000000e+00 1.541897e-04 273.97 -2.00 20.00 -2.00 501.16 0.00e+00 2.241440e+00 7.390945e-02 5.738292e-02 -6.000000e+00 1.111466e-01 222.21 -2.00 3.57 -2.00 502.65 0.00e+00 19.522 0.145 489.00 513.00 1 5.3818e+00 5.6304e-03 3.5130e-02 -6.0000e+00 8.4809e-03 -2.1847e-02 1.4436e-03 2.0638e-03 -6.0000e+00 2.2337e-03 4.6461e-04 3.2875e-03 3.4461e-04 9.8291e-05 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