File name: Pandora104s1_Downsview_20180719_L2Fit_fwvt1c21d20180627p1-8.txt File generation date: 20241126T220228.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c21p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 104 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora104_OF_v4d20171009.txt Instrument calibration file used: Pandora104s1_CF_v21d20180627.txt Level 1 file used: Pandora104s1_Downsview_20180719_L1_smca1c21d20180627p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180719 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 12 to revisit NO2 and SO2 First and last pixel inside fitting window: 1633 1783 Nominal wavelengths inside fitting window [nm]: 492.0163 492.1368 492.2573 492.3778 492.4983 492.6187 492.7391 492.8596 492.9800 493.1003 493.2207 493.3411 493.4614 493.5817 493.7020 493.8223 493.9425 494.0628 494.1830 494.3032 494.4234 494.5436 494.6637 494.7839 494.9040 495.0241 495.1442 495.2643 495.3843 495.5044 495.6244 495.7444 495.8644 495.9844 496.1043 496.2242 496.3442 496.4641 496.5840 496.7038 496.8237 496.9435 497.0633 497.1831 497.3029 497.4227 497.5424 497.6621 497.7818 497.9015 498.0212 498.1409 498.2605 498.3801 498.4997 498.6193 498.7389 498.8585 498.9780 499.0975 499.2170 499.3365 499.4560 499.5754 499.6949 499.8143 499.9337 500.0531 500.1724 500.2918 500.4111 500.5304 500.6497 500.7690 500.8882 501.0075 501.1267 501.2459 501.3651 501.4843 501.6034 501.7226 501.8417 501.9608 502.0799 502.1989 502.3180 502.4370 502.5560 502.6750 502.7940 502.9130 503.0319 503.1509 503.2698 503.3887 503.5075 503.6264 503.7452 503.8641 503.9829 504.1017 504.2204 504.3392 504.4579 504.5766 504.6953 504.8140 504.9327 505.0513 505.1700 505.2886 505.4072 505.5258 505.6443 505.7629 505.8814 505.9999 506.1184 506.2368 506.3553 506.4737 506.5922 506.7106 506.8289 506.9473 507.0657 507.1840 507.3023 507.4206 507.5389 507.6571 507.7754 507.8936 508.0118 508.1300 508.2482 508.3663 508.4845 508.6026 508.7207 508.8388 508.9569 509.0749 509.1929 509.3109 509.4289 509.5469 509.6649 509.7828 509.9007 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180719T100007.0Z 6774.416748 331 1 32.01 2 89.79 60.75 138.59 338.47 0.00 1 0.00 1 0 32 6.303e-02 6.118e-02 5.953e-02 5.894e-02 5.009530e+03 3.800020e+03 2.275166e+02 -6.000000e+00 3.484622e+03 286.91 -2.00 20.00 -2.00 505.33 0.00e+00 1.318822e-03 1.629222e-03 6.936698e-05 -6.000000e+00 1.770975e-03 286.91 -2.00 20.00 -2.00 500.52 0.00e+00 2.791735e-01 1.151969e+00 6.621038e-02 -6.000000e+00 1.243063e+00 232.92 -2.00 3.57 -2.00 502.11 0.00e+00 20.013 0.156 489.00 513.00 1 9.8824e+00 8.8315e-02 3.6052e-02 -6.0000e+00 9.5230e-02 1.1021e-01 2.2692e-02 2.2915e-03 -6.0000e+00 2.4960e-02 5.7978e-06 7.0385e-03 5.0371e-03 2.3806e-05 -6.0000e+00 5.5741e-03 -1.2124e-02 2.0267e-05 12 9 8 11 8 0 54.17 22.09 2.70 -0.01212 0.03670 8 2 1 4 0 4000.000 22.09 15.00 19.26 -10340 -802 2528 4387 -4175 -3144 -3492 -3109 963 -3616 3887 5131 6916 14947 -6733 14747 3092 -611 -5430 1275 2267 9493 -6020 -1652 -1069 -4712 3212 5042 1522 -4096 -2265 -8649 -14110 -4533 -2608 6967 -567 -2849 4407 7274 5324 -3580 -1925 9890 4290 9145 5910 4572 -3808 -4782 -2024 -2061 5168 -536 -3861 -4707 659 772 4042 -12530 -5875 16681 14606 15914 -648 10925 1210 -8071 4148 5320 -7024 -1452 -610 -3465 3523 -5525 -8269 199 -1192 -7124 16784 -1933 4623 1314 3279 -2470 12218 1232 1712 4502 1781 -3065 6741 -4574 -9893 -6809 5079 8795 -3666 -7523 4998 11452 6092 6765 -4615 2113 3621 332 4900 2689 -6151 -1712 -7692 -2788 -6035 5368 597 -3578 2656 755 -839 -2959 8755 5554 8270 1806 -3669 6103 -3923 2890 -5140 -2568 -4617 -15824 2198 10017 3162 11883 820 -5663 1734 2647 -3108 -8355 -348 -847 2896 9095 -658 4423 -4386 -10225 -736 2322 4107 -4344 -3300 -3758 -3360 1002 -3877 3808 4924 6417 12676 -6985 12456 2959 -620 -5963 1327 2332 9130 -6726 -1774 -1152 -5249 3296 5052 1547 -4222 -2240 -9136 -15909 -4850 -2837 6962 -603 -3066 4372 6952 5184 -3821 -2043 9469 4390 8968 5952 4605 -4093 -5086 -2034 -2015 4641 -508 -3885 -4945 675 798 4048 -14678 -6437 14816 13294 14324 -680 10114 1210 -8688 3936 4932 -7232 -1416 -595 -3519 3402 -5815 -8766 190 -1143 -7214 13468 -1875 4240 1250 3100 -2497 10754 1205 1661 4253 1733 -3150 6422 -4906 -11063 -7224 4703 7661 -3518 -7338 4245 9207 5285 6083 -4826 2091 3506 328 4566 2561 -6474 -1752 -8446 -2947 -6619 5281 619 -3895 2726 780 -863 -3058 7963 5208 7635 1778 -3803 5764 -4056 2796 -5390 -2591 -4654 -17559 2034 8616 2969 10495 816 -6075 1751 2659 -3311 -9405 -364 -888 2897 8386 -649 4088 -4427 SO 20180719T100406.0Z 6774.419514 335 1 32.01 2 89.16 61.44 138.85 339.86 0.00 1 0.00 1 0 15 5.375e-02 5.424e-02 4.274e-02 4.225e-02 4.767604e+02 2.435363e+03 2.149771e+01 -6.000000e+00 2.971912e+03 286.91 -2.00 20.00 -2.00 505.30 0.00e+00 3.017821e-03 1.161355e-03 7.640606e-05 -6.000000e+00 1.508294e-03 286.91 -2.00 20.00 -2.00 500.28 0.00e+00 3.454431e+00 8.378845e-01 2.029319e-02 -6.000000e+00 1.053914e+00 232.92 -2.00 3.57 -2.00 501.90 0.00e+00 18.887 0.131 489.00 513.00 1 9.4446e+00 6.4435e-02 3.2381e-02 -6.0000e+00 8.0826e-02 8.0296e-02 1.6597e-02 1.8049e-03 -6.0000e+00 2.1032e-02 8.1828e-06 -3.2260e-03 3.6902e-03 2.5011e-05 -6.0000e+00 4.7300e-03 -3.7966e-04 3.8711e-04 12 8 8 10 0 0 -266.35 22.09 5.47 -0.00038 -0.02276 8 2 1 4 0 4000.000 22.09 14.99 19.27 4942 -12228 4991 -5474 4336 -705 2158 -8022 -2238 1430 9254 7777 3335 -6065 10394 -2157 4330 -140 -2070 -252 -9012 7550 -5005 4398 -3890 1443 -124 7831 471 -830 -5088 10080 8665 9303 -597 -2228 916 -2968 -3109 -13411 3948 -6992 -2710 -5390 9242 690 4156 -2970 4843 1044 5184 3899 -2049 7212 -2149 16921 1721 5734 1119 5436 -12165 5604 -381 -1472 -12046 3909 1146 -4792 -2937 9002 1973 -1756 -3247 1596 7922 2688 -1646 -7238 1856 -1853 7189 -15583 -88 -2999 4514 2726 1531 651 3119 911 -916 6743 -585 5625 1730 1517 -2666 -814 -3292 5366 789 -395 -399 -35 -2217 4208 -3008 2924 4989 -4778 -6612 747 -1872 4296 5568 -3015 -890 -3040 4611 -1744 2560 -2244 2292 -2861 511 -5383 3508 8527 13110 -949 -1118 -5375 -3103 -2742 2886 5081 -261 61 -3648 -1839 -8625 8525 -4523 3370 -6852 8969 -674 -1163 4153 5073 -3431 4376 -12998 4641 -5849 4318 -751 2285 -9448 -2496 1518 8935 7545 3324 -6532 9478 -2221 4239 -146 -2274 -275 -10680 7641 -5720 4602 -4453 1570 -136 7912 501 -860 -5350 9181 8088 8970 -656 -2510 990 -3297 -3419 -16127 4012 -7950 -2988 -6168 9295 757 4392 -3319 4936 1081 5000 3702 -2027 6500 -2175 14734 1779 5768 1176 5456 -14413 5627 -407 -1587 -14294 3914 1156 -5033 -2998 8079 1864 -1713 -3234 1533 7269 2590 -1620 -7350 1706 -1758 6222 -16942 -83 -2906 4105 2543 1446 619 2888 861 -884 6088 -578 5302 1688 1460 -2632 -772 -3118 4560 686 -349 -358 -32 -2168 3875 -2934 2652 4377 -4613 -6602 707 -1848 4058 5243 -3096 -901 -3154 4432 -1757 2434 -2208 2135 -2809 491 -5495 3284 7622 11155 -926 -1097 -5435 -3011 -2614 2582 4449 -245 59 -3689 -1850 -9355 7852 -4736 3291 -7416 8333 -681 -1154 3805 4529 -3337 SO 20180719T100802.0Z 6774.422245 339 1 32.01 2 88.54 62.11 139.09 341.24 0.00 1 0.00 1 0 22 3.442e-02 3.435e-02 2.630e-02 2.612e-02 4.560577e+03 1.681020e+03 4.070492e+02 -6.000000e+00 1.901964e+03 286.91 -2.00 20.00 -2.00 505.31 0.00e+00 2.101763e-03 7.154727e-04 6.882452e-05 -6.000000e+00 9.666646e-04 286.91 -2.00 20.00 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