File name: Pandora104s1_Downsview_20180821_L2Fit_fwvt1c21d20180627p1-8.txt File generation date: 20241126T222905.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c21p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 104 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora104_OF_v5d20171009.txt Instrument calibration file used: Pandora104s1_CF_v21d20180627.txt Level 1 file used: Pandora104s1_Downsview_20180821_L1_smca1c21d20180627p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180821 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 12 to revisit NO2 and SO2 First and last pixel inside fitting window: 1633 1783 Nominal wavelengths inside fitting window [nm]: 492.0163 492.1368 492.2573 492.3778 492.4983 492.6187 492.7391 492.8596 492.9800 493.1003 493.2207 493.3411 493.4614 493.5817 493.7020 493.8223 493.9425 494.0628 494.1830 494.3032 494.4234 494.5436 494.6637 494.7839 494.9040 495.0241 495.1442 495.2643 495.3843 495.5044 495.6244 495.7444 495.8644 495.9844 496.1043 496.2242 496.3442 496.4641 496.5840 496.7038 496.8237 496.9435 497.0633 497.1831 497.3029 497.4227 497.5424 497.6621 497.7818 497.9015 498.0212 498.1409 498.2605 498.3801 498.4997 498.6193 498.7389 498.8585 498.9780 499.0975 499.2170 499.3365 499.4560 499.5754 499.6949 499.8143 499.9337 500.0531 500.1724 500.2918 500.4111 500.5304 500.6497 500.7690 500.8882 501.0075 501.1267 501.2459 501.3651 501.4843 501.6034 501.7226 501.8417 501.9608 502.0799 502.1989 502.3180 502.4370 502.5560 502.6750 502.7940 502.9130 503.0319 503.1509 503.2698 503.3887 503.5075 503.6264 503.7452 503.8641 503.9829 504.1017 504.2204 504.3392 504.4579 504.5766 504.6953 504.8140 504.9327 505.0513 505.1700 505.2886 505.4072 505.5258 505.6443 505.7629 505.8814 505.9999 506.1184 506.2368 506.3553 506.4737 506.5922 506.7106 506.8289 506.9473 507.0657 507.1840 507.3023 507.4206 507.5389 507.6571 507.7754 507.8936 508.0118 508.1300 508.2482 508.3663 508.4845 508.6026 508.7207 508.8388 508.9569 509.0749 509.1929 509.3109 509.4289 509.5469 509.6649 509.7828 509.9007 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180821T103512.0Z 6807.441111 354 1 32.01 2 89.77 73.43 137.13 287.64 0.00 1 0.00 1 0 36 2.594e-01 1.930e-01 1.753e-01 1.546e-01 2.344387e+04 1.280547e+04 1.251571e+03 -6.000000e+00 1.433207e+04 286.99 -2.00 20.00 -2.00 505.28 0.00e+00 6.743104e-03 4.259012e-03 3.128819e-04 -6.000000e+00 7.287318e-03 286.99 -2.00 20.00 -2.00 499.95 0.00e+00 3.642547e-03 3.170726e+00 1.678347e-01 -6.000000e+00 5.087975e+00 231.38 -2.00 3.57 -2.00 501.58 0.00e+00 20.000 0.156 489.00 513.00 1 1.0782e+01 2.4100e-01 3.8821e-02 -6.0000e+00 3.9006e-01 1.5826e-01 6.1834e-02 4.0323e-03 -6.0000e+00 1.0180e-01 2.0524e-06 2.5862e-03 1.1746e-02 1.2317e-04 -6.0000e+00 2.2971e-02 -3.0462e-02 3.5190e-04 12 9 8 11 8 0 94.40 22.09 11.93 -0.03046 -0.01252 8 2 1 4 0 4000.000 22.09 15.00 19.19 17574 20499 -18307 10441 7569 503 -6237 8282 -9344 -3559 -27701 16768 -5488 56117 1423 44812 -30554 18316 20396 17501 -5145 -8311 24276 -11957 9263 -20041 2467 -6512 9637 -12315 40397 -16650 43559 9552 -2349 932 26962 54655 12035 -7 63301 -8567 6768 8107 -7905 10937 -23474 13826 -16994 11574 -16686 25219 -15414 37524 -2603 22151 -16400 15556 -3913 40620 -3190 24900 8782 -5735 15027 -1939 21192 -9037 23438 -3756 9708 -15775 19664 -5871 5819 2508 61109 -6829 -23575 10653 -710 34145 40558 324 -30052 78533 2138 38110 -17886 27614 -11946 36667 -5111 4196 -12141 10560 -27 32216 -13698 56644 -2948 7319 -3713 436 28141 -13512 13507 -3362 -7315 -11166 2394 937 24843 -21595 56608 -18204 24092 -602 29665 3809 7301 30001 13230 19609 -799 13257 -25431 19309 -26778 34735 -19812 28987 -15220 108330 -6203 46496 -5854 37777 224 -11747 -26781 -8062 -22799 32188 91830 -8507 7173 15683 10488 -2603 37274 14845 17139 -22846 10283 7838 566 -7641 8881 -11832 -4193 -40222 15761 -6260 35274 1486 31009 -43637 16754 18810 16721 -6069 -10108 21674 -15110 9667 -27679 2737 -7817 9724 -14688 28531 -20236 30286 9511 -2711 1050 23441 36272 11822 -8 38189 -10290 7124 8537 -9838 11454 -34017 13881 -22540 11470 -21008 20786 -18424 27148 -2829 19696 -21571 15271 -4623 31392 -3726 22447 9266 -6954 14866 -2220 19124 -10684 20157 -4126 9236 -19064 17070 -6556 5899 2612 35850 -7431 -29648 9599 -706 24467 27446 322 -40284 38152 2125 26735 -21007 20809 -13072 25526 -5367 4041 -13266 8893 -24 20363 -13089 27482 -2452 5562 -3229 385 20244 -14796 11507 -3335 -7460 -11856 2276 917 19489 -26323 32938 -21424 19201 -620 23256 3789 6878 22202 11186 15493 -774 11318 -31363 15654 -33440 24152 -23148 20955 -16307 36292 -6063 27825 -5866 25496 217 -12900 -34444 -8745 -28563 23931 38896 -9185 6600 13079 8998 -2496 24663 SO 20180821T103917.1Z 6807.443948 358 1 32.14 2 89.06 74.13 137.81 288.56 0.00 1 0.00 1 0 22 9.397e-02 8.778e-02 9.413e-02 9.123e-02 2.029242e+04 7.339264e+03 1.686510e+03 -6.000000e+00 5.190419e+03 286.99 -2.00 20.00 -2.00 505.28 0.00e+00 2.811015e-03 2.531912e-03 1.300432e-04 -6.000000e+00 2.642737e-03 286.99 -2.00 20.00 -2.00 499.91 0.00e+00 1.663213e+00 1.873973e+00 2.928576e-02 -6.000000e+00 1.855692e+00 231.38 -2.00 3.57 -2.00 501.55 0.00e+00 18.678 0.127 489.00 513.00 1 1.0383e+01 1.4402e-01 3.1984e-02 -6.0000e+00 1.4200e-01 1.1919e-01 3.6415e-02 2.4897e-03 -6.0000e+00 3.7514e-02 3.6297e-06 1.4019e-02 6.9699e-03 1.2527e-04 -6.0000e+00 8.3309e-03 6.6406e-02 -6.3218e-04 12 8 8 10 0 0 -42.35 22.09 8.87 0.06641 0.16365 8 2 1 4 0 4000.000 22.09 15.00 19.20 900000 8126 5971 4173 1268 5626 -9852 11056 9263 -5386 -1170 1410 -1570 -14083 -6268 -1883 -5894 -2706 7519 -949 -5697 4679 4475 10537 17184 5806 2954 3209 -9476 13780 -9825 12102 -9143 962 -13639 2311 6936 -424 -12907 6186 -4059 5283 8260 -5097 -2840 -1588 -2171 8203 -1558 -1692 5038 3328 22556 3162 198 -1848 3284 -7746 2094 9258 10587 -9337 -2436 -10815 10593 9912 -971 11678 -5182 13992 3342 -9262 2920 -13682 -2111 -1489 -9360 -12585 10845 -13132 -213 -792 14921 -15787 9990 25656 205 8569 -3783 13916 2267 516 26322 -7987 5893 3481 90 10015 -7088 -1054 360 -16146 23777 -11113 9980 -2993 -7933 19972 -1725 6705 7195 1987 -12236 17515 -2286 -9522 -7668 12183 -7242 7334 -14679 -6481 -116 -7190 16105 2662 18939 2235 11863 1427 20889 -3709 790 3814 -7826 -6592 3170 1866 292 -3463 14208 -1083 -4569 -1153 -2899 -15692 -1373 -1299 7385 8552 19304 900000 7467 5809 4271 1361 5904 -12220 11263 9580 -6286 -1291 1501 -1691 -16928 -6938 -2008 -6624 -3028 7835 -1077 -6751 5028 4815 10748 16573 6223 3237 3477 -11299 12607 -11114 11151 -10514 1048 -17570 2554 7236 -471 -15952 6314 -4584 5495 8439 -5988 -3300 -1827 -2493 8404 -1724 -1831 4947 3241 18022 3056 203 -1996 3451 -9105 2235 9181 10346 -11135 -2723 -13102 10344 9579 -1022 10719 -5536 12245 3197 -10004 2824 -15713 -2197 -1526 -10102 -13696 9310 -14073 -200 -753 12252 -17503 8771 19553 199 7616 -3738 11511 2098 489 19764 -8280 5172 2991 76 7480 -6131 -845 281 -14974 15629 -10820 8363 -2898 -8060 15370 -1616 5825 6322 1855 -13131 14117 -2224 -9913 -7947 10661 -7706 6717 -16239 -6457 -106 -7041 12754 2407 14665 2036 9794 1302 15848 -3487 697 3260 -7478 -6291 2826 1712 274 -3429 12047 -1072 -4701 -1149 -2928 -17828 -1345 -1247 6397 7254 14876 SO 20180821T104323.1Z 6807.446795 362 1 32.15 2 88.35 74.84 138.48 289.50 0.00 1 0.00 1 0 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