File name: Pandora104s1_Downsview_20180902_L2Fit_fwvt1c21d20180627p1-8.txt File generation date: 20241126T222939.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c21p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 104 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora104_OF_v5d20171009.txt Instrument calibration file used: Pandora104s1_CF_v21d20180627.txt Level 1 file used: Pandora104s1_Downsview_20180902_L1_smca1c21d20180627p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180902 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 12 to revisit NO2 and SO2 First and last pixel inside fitting window: 1633 1783 Nominal wavelengths inside fitting window [nm]: 492.0163 492.1368 492.2573 492.3778 492.4983 492.6187 492.7391 492.8596 492.9800 493.1003 493.2207 493.3411 493.4614 493.5817 493.7020 493.8223 493.9425 494.0628 494.1830 494.3032 494.4234 494.5436 494.6637 494.7839 494.9040 495.0241 495.1442 495.2643 495.3843 495.5044 495.6244 495.7444 495.8644 495.9844 496.1043 496.2242 496.3442 496.4641 496.5840 496.7038 496.8237 496.9435 497.0633 497.1831 497.3029 497.4227 497.5424 497.6621 497.7818 497.9015 498.0212 498.1409 498.2605 498.3801 498.4997 498.6193 498.7389 498.8585 498.9780 499.0975 499.2170 499.3365 499.4560 499.5754 499.6949 499.8143 499.9337 500.0531 500.1724 500.2918 500.4111 500.5304 500.6497 500.7690 500.8882 501.0075 501.1267 501.2459 501.3651 501.4843 501.6034 501.7226 501.8417 501.9608 502.0799 502.1989 502.3180 502.4370 502.5560 502.6750 502.7940 502.9130 503.0319 503.1509 503.2698 503.3887 503.5075 503.6264 503.7452 503.8641 503.9829 504.1017 504.2204 504.3392 504.4579 504.5766 504.6953 504.8140 504.9327 505.0513 505.1700 505.2886 505.4072 505.5258 505.6443 505.7629 505.8814 505.9999 506.1184 506.2368 506.3553 506.4737 506.5922 506.7106 506.8289 506.9473 507.0657 507.1840 507.3023 507.4206 507.5389 507.6571 507.7754 507.8936 508.0118 508.1300 508.2482 508.3663 508.4845 508.6026 508.7207 508.8388 508.9569 509.0749 509.1929 509.3109 509.4289 509.5469 509.6649 509.7828 509.9007 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180902T104836.0Z 6819.450417 309 1 32.00 2 89.77 79.34 28.52 187.76 0.00 1 0.00 1 0 32 1.179e-01 1.124e-01 9.069e-02 8.744e-02 2.614864e+04 7.168078e+03 1.545694e+03 -6.000000e+00 6.490026e+03 285.97 -2.00 20.00 -2.00 505.33 0.00e+00 -1.158808e-04 2.369576e-03 1.230051e-04 -6.000000e+00 3.303859e-03 285.97 -2.00 20.00 -2.00 500.01 0.00e+00 3.020413e-01 1.749597e+00 1.475162e-01 -6.000000e+00 2.316576e+00 230.27 -2.00 3.57 -2.00 501.65 0.00e+00 20.030 0.157 489.00 513.00 1 1.0285e+01 1.3277e-01 3.7835e-02 -6.0000e+00 1.7747e-01 1.3279e-01 3.4147e-02 4.0667e-03 -6.0000e+00 4.6464e-02 3.7638e-06 -4.3079e-03 6.4519e-03 1.2100e-04 -6.0000e+00 1.0406e-02 -2.7279e-02 1.6482e-04 12 9 8 11 8 0 62.83 21.88 4.71 -0.02728 -0.05716 8 2 1 4 0 4000.000 21.88 15.00 19.23 -10367 702 -811 7948 3247 4484 -12302 1059 -7487 23879 -21861 4916 -5843 12043 -12025 9700 -8921 9693 -5262 1809 3792 899 -4991 -763 18146 -11758 5421 -2996 10466 10304 8714 -12767 1034 7251 5885 4925 13183 5113 4983 -951 13622 9319 10122 -7033 -15535 1866 -3825 1584 -10927 7366 7638 26595 -12734 16531 -12141 1046 -3325 9608 -611 35439 -12457 -18280 424 5555 5194 -2997 9686 -635 -3059 1170 14091 -14328 14264 10162 15921 -98 36627 -17836 8482 -4853 -2054 3666 -3914 -1260 10340 6657 8517 10560 -2047 11143 -17597 17418 5159 21633 8817 8534 8288 -4975 -16891 13612 -3662 8019 3902 17630 -3213 -9827 -3648 2177 -1893 -12303 18 -19937 -6985 -9450 5370 -15194 17652 8863 18379 2358 10593 17388 8534 9475 18664 -1988 -3256 18464 -15168 7106 -14027 1346 -17891 18448 -11010 15308 -15381 20619 -48 -285 -1358 13063 20026 -10155 356 -1710 10943 -7808 1771 -22314 20383 -10969 671 -804 7511 3319 4606 -15183 1169 -9020 21213 -29602 5082 -6621 11310 -14089 9172 -10157 9385 -6058 1997 4120 1003 -5909 -866 17271 -14982 5826 -3470 10544 10111 8343 -14869 1062 7172 6158 5328 13143 5442 5262 -1048 12965 9251 10039 -8294 -20110 2062 -4459 1738 -13313 7399 7459 20978 -14296 13844 -13502 1060 -3622 9432 -665 27216 -15066 -23379 456 5706 5346 -3305 9296 -660 -3211 1169 12268 -16203 12307 9199 13851 -101 26136 -20929 7566 -4864 -1986 3344 -3864 -1221 9057 6147 7803 9460 -2055 9721 -20062 14216 4778 17264 7821 7247 6699 -4348 -15998 9511 -2968 5789 3006 12510 -2988 -10286 -3685 2086 -1868 -13268 18 -23561 -7327 -10114 4950 -16955 14372 7993 15529 2343 9608 14407 7467 8020 14458 -1896 -3145 14523 -16488 6192 -14969 1237 -19290 13819 -10955 11869 -16276 15885 -46 -274 -1346 11447 16582 -11286 357 -1742 9807 -8284 1686 -26309 15881 SO 20180902T105239.0Z 6819.453229 313 1 32.01 2 89.05 80.04 28.62 189.74 0.00 1 0.00 1 0 22 6.363e-02 6.288e-02 4.689e-02 4.624e-02 8.797732e+03 3.215322e+03 5.639803e+02 -6.000000e+00 3.500816e+03 285.97 -2.00 20.00 -2.00 505.30 0.00e+00 2.069756e-03 1.276352e-03 5.289531e-05 -6.000000e+00 1.785192e-03 285.97 -2.00 20.00 -2.00 500.22 0.00e+00 2.280943e+00 9.280806e-01 6.269806e-02 -6.000000e+00 1.255511e+00 230.27 -2.00 3.57 -2.00 501.85 0.00e+00 18.672 0.127 489.00 513.00 1 9.6695e+00 7.1238e-02 3.2098e-02 -6.0000e+00 9.6050e-02 8.6944e-02 1.8312e-02 2.2567e-03 -6.0000e+00 2.5373e-02 7.3471e-06 4.4405e-03 3.8440e-03 5.1827e-05 -6.0000e+00 5.6410e-03 4.5324e-02 -4.9739e-04 12 8 8 10 0 0 52.61 21.88 7.45 0.04532 0.07613 8 2 1 4 0 4000.000 21.88 15.00 19.24 900000 9184 -15528 13152 -4612 7256 -1151 5000 1241 9358 8393 -2239 156 -1284 -2575 -4736 8514 -2030 -1804 -3308 1985 -3946 3427 -5309 671 -977 10888 7535 3103 2142 -505 1683 -5353 5829 -174 4797 -12114 3043 -6503 -731 -10991 -245 -9443 9031 -2442 3641 397 50 7488 91 3149 -721 14951 2593 13043 -6924 998 -10773 2811 -8016 4994 -4873 2450 3824 13416 -2077 3942 -3350 -1048 2180 7275 2396 1198 4089 1380 -3126 -12560 2967 -10742 766 -3003 727 -11782 -5148 -8482 7290 6278 718 -2867 -2501 9890 1217 8329 5688 8766 -9474 3298 -4422 10691 -8814 3116 -7078 11242 -8286 8334 474 3689 -1764 2013 4348 488 -1714 -2836 16022 -3857 4964 -4953 5007 -4825 7696 -3192 -7408 -7866 2920 -5187 -996 4941 6673 3544 13882 6774 -10033 6569 1914 -376 -5122 276 -3179 -173 -6919 2625 -11101 2998 2966 5852 6797 2239 -2250 -261 1318 5612 900000 7885 -17415 11618 -4978 7099 -1250 5179 1337 9236 8194 -2399 161 -1323 -2666 -4992 7979 -2148 -1966 -3725 2121 -4469 3620 -6105 735 -1089 10771 7654 3245 2181 -510 1661 -5705 5755 -190 5062 -14932 3204 -7435 -780 -12922 -261 -11095 8965 -2744 3885 436 55 7475 96 3127 -720 12597 2441 11306 -7539 1034 -12717 2913 -9195 5027 -5415 2552 3934 12530 -2224 3914 -3502 -1059 2113 6603 2263 1150 3853 1358 -3227 -13970 2773 -11273 715 -2886 677 -12466 -5125 -8797 6574 5741 691 -2843 -2456 8621 1158 7516 5330 7915 -9938 2972 -4174 8489 -8283 2552 -6388 8675 -8024 7227 454 3429 -1712 1859 3903 459 -1676 -2837 13473 -3950 4675 -5158 4790 -5122 7200 -3261 -7743 -8108 2687 -5214 -969 4532 6039 3296 11636 6110 -10581 5777 1736 -347 -4936 257 -3139 -168 -7277 2554 -12433 2941 2925 5629 6474 2216 -2287 -254 1238 5044 SO 20180902T105633.0Z 6819.455937 317 1 32.00 2 88.35 80.71 28.74 191.64 0.00 1 0.00 1 0 15 4.147e-02 4.050e-02 3.900e-02 3.843e-02 1.017402e+04 2.773910e+03 7.142663e+02 -6.000000e+00 2.282189e+03 285.97 -2.00 20.00 -2.00 505.25 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