File name: Pandora104s1_Downsview_20180908_L2Fit_fwvt1c21d20180627p1-8.txt File generation date: 20241126T222959.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c21p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 104 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora104_OF_v5d20171009.txt Instrument calibration file used: Pandora104s1_CF_v21d20180627.txt Level 1 file used: Pandora104s1_Downsview_20180908_L1_smca1c21d20180627p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180908 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 12 to revisit NO2 and SO2 First and last pixel inside fitting window: 1633 1783 Nominal wavelengths inside fitting window [nm]: 492.0163 492.1368 492.2573 492.3778 492.4983 492.6187 492.7391 492.8596 492.9800 493.1003 493.2207 493.3411 493.4614 493.5817 493.7020 493.8223 493.9425 494.0628 494.1830 494.3032 494.4234 494.5436 494.6637 494.7839 494.9040 495.0241 495.1442 495.2643 495.3843 495.5044 495.6244 495.7444 495.8644 495.9844 496.1043 496.2242 496.3442 496.4641 496.5840 496.7038 496.8237 496.9435 497.0633 497.1831 497.3029 497.4227 497.5424 497.6621 497.7818 497.9015 498.0212 498.1409 498.2605 498.3801 498.4997 498.6193 498.7389 498.8585 498.9780 499.0975 499.2170 499.3365 499.4560 499.5754 499.6949 499.8143 499.9337 500.0531 500.1724 500.2918 500.4111 500.5304 500.6497 500.7690 500.8882 501.0075 501.1267 501.2459 501.3651 501.4843 501.6034 501.7226 501.8417 501.9608 502.0799 502.1989 502.3180 502.4370 502.5560 502.6750 502.7940 502.9130 503.0319 503.1509 503.2698 503.3887 503.5075 503.6264 503.7452 503.8641 503.9829 504.1017 504.2204 504.3392 504.4579 504.5766 504.6953 504.8140 504.9327 505.0513 505.1700 505.2886 505.4072 505.5258 505.6443 505.7629 505.8814 505.9999 506.1184 506.2368 506.3553 506.4737 506.5922 506.7106 506.8289 506.9473 507.0657 507.1840 507.3023 507.4206 507.5389 507.6571 507.7754 507.8936 508.0118 508.1300 508.2482 508.3663 508.4845 508.6026 508.7207 508.8388 508.9569 509.0749 509.1929 509.3109 509.4289 509.5469 509.6649 509.7828 509.9007 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180908T105517.0Z 6825.455058 376 1 32.01 2 89.77 82.44 73.33 87.23 0.00 1 0.00 1 0 22 1.796e-02 1.792e-02 1.414e-02 1.401e-02 1.691869e+04 1.020569e+03 1.031462e+03 -6.000000e+00 9.869439e+02 285.47 -2.00 20.00 -2.00 505.53 0.00e+00 7.003368e-04 3.880466e-04 7.248527e-05 -6.000000e+00 5.028136e-04 285.47 -2.00 20.00 -2.00 501.13 0.00e+00 1.536690e+00 2.669496e-01 1.236278e-01 -6.000000e+00 3.527139e-01 229.71 -2.00 3.57 -2.00 502.64 0.00e+00 20.049 0.157 489.00 513.00 1 8.3026e+00 2.0388e-02 3.7206e-02 -6.0000e+00 2.7019e-02 -1.6412e-02 5.1060e-03 3.4886e-03 -6.0000e+00 7.0710e-03 2.5454e-05 3.0725e-05 1.0980e-03 9.4856e-05 -6.0000e+00 1.5845e-03 -4.0334e-03 5.0456e-05 12 8 8 10 0 0 79.54 21.69 3.99 -0.00403 -0.00382 8 2 1 4 0 4000.000 21.69 15.00 18.86 -635 -4350 -2607 -1484 -3078 -1249 871 1643 -2955 2931 -2104 -215 -2014 -147 -3104 -83 360 735 -2449 209 -350 -613 2473 424 -838 1413 -361 695 1304 -608 -1199 -755 -862 -22 2653 1488 2415 -697 1649 -1121 3269 1134 2011 1212 4046 3354 107 2400 -2097 3748 -3606 -3795 -4218 -1794 -106 1476 -2710 -90 -46 710 2429 2337 2417 184 2721 1205 785 -1693 61 -498 526 638 -238 -137 189 -1553 1138 -1545 194 -1646 1698 1799 -220 -1453 -2749 -1024 652 604 -2557 -29 -548 1316 1824 2402 1923 -176 642 -42 1207 -2130 111 446 1291 -2061 739 -2648 224 -2177 1142 1092 -2163 -710 1617 1829 -356 -290 1550 2536 3822 636 1068 597 -1438 338 891 554 179 -220 1479 -991 -1463 -613 -1483 -3453 -264 -1302 -3482 -3111 284 2944 -281 2617 801 1076 -1018 396 1514 -2100 -2014 -963 -929 -511 -3677 -2233 -1309 -2839 -1154 809 1535 -2900 2703 -2001 -199 -1878 -133 -2872 -74 326 678 -2408 205 -344 -608 2388 419 -845 1400 -363 688 1269 -584 -1121 -704 -812 -21 2609 1505 2406 -709 1627 -1124 3138 1117 1986 1220 4019 3381 111 2417 -2173 3617 -3633 -3723 -4082 -1686 -100 1424 -2798 -92 -48 723 2428 2352 2450 191 2754 1224 788 -1713 60 -490 505 609 -231 -135 189 -1583 1113 -1518 184 -1585 1575 1675 -211 -1418 -2752 -1026 647 599 -2599 -29 -543 1288 1803 2385 1889 -170 593 -38 1046 -1880 94 379 1120 -1941 721 -2764 230 -2277 1146 1091 -2257 -742 1667 1890 -375 -306 1617 2671 4047 694 1143 629 -1512 346 916 578 187 -233 1535 -1050 -1567 -647 -1546 -3634 -270 -1349 -3766 -3444 309 3168 -317 2913 914 1233 -1192 457 1723 -2442 -2296 -1072 -1034 SO 20180908T105915.0Z 6825.457813 380 1 32.01 2 89.06 83.12 72.64 87.89 0.00 1 0.00 1 0 15 2.531e-02 2.522e-02 2.356e-02 2.341e-02 1.101428e+04 1.658094e+03 6.586474e+02 -6.000000e+00 1.390902e+03 285.47 -2.00 20.00 -2.00 505.36 0.00e+00 8.384121e-04 6.448573e-04 6.607894e-05 -6.000000e+00 7.089091e-04 285.47 -2.00 20.00 -2.00 500.39 0.00e+00 2.210208e+00 4.617158e-01 8.591960e-02 -6.000000e+00 4.977215e-01 229.71 -2.00 3.57 -2.00 502.00 0.00e+00 18.710 0.128 489.00 513.00 1 8.9836e+00 3.5376e-02 3.2561e-02 -6.0000e+00 3.8118e-02 5.9294e-02 8.9795e-03 2.5773e-03 -6.0000e+00 9.9938e-03 1.4849e-05 3.3723e-03 1.9139e-03 5.9716e-05 -6.0000e+00 2.2398e-03 1.8019e-02 -1.9722e-04 12 8 8 10 0 0 -177.76 21.69 2.74 0.01802 0.04141 8 2 1 4 0 4000.000 21.69 15.00 18.87 3062 -2575 -1369 -1991 1388 -1392 3434 -4546 3832 -1838 -38 -1182 -157 -3611 1196 1925 -4116 983 -311 -3058 -1322 2527 -1081 3119 1291 -1463 -1519 4553 -2550 3460 -1201 1885 -899 1807 327 1573 336 -2516 -1506 -436 1528 3799 3255 -157 3029 -1852 56 -2674 6197 -1256 4578 -5583 -723 1005 1122 -3691 794 1968 -128 -2332 -2713 5957 2292 1015 773 2157 2630 2994 -2077 703 -4410 181 -4159 3012 -1066 -154 -868 1184 -3122 -49 -807 1826 -3280 -1056 1183 -74 1536 -4985 2234 -2829 1619 -2427 52 -3744 4932 3881 1070 -5583 1549 3117 -3654 246 1263 -1030 -689 5147 466 305 -3640 3629 1570 2232 -3896 -349 119 3782 -1226 850 -403 449 1727 1224 4608 1374 -400 -1841 1769 -2163 -1917 1505 3423 -1953 -1888 -671 2483 -4131 -120 -765 -1636 2374 -128 2620 2091 1457 -3413 880 -1311 857 -2026 961 -4288 2665 -2400 -1299 -1975 1370 -1435 3464 -5008 3908 -1961 -39 -1220 -158 -3711 1165 1860 -4267 991 -328 -3369 -1431 2642 -1172 3251 1381 -1610 -1663 4679 -2764 3414 -1202 1833 -906 1837 351 1691 362 -2760 -1619 -459 1573 3844 3342 -168 3187 -2054 61 -2947 6172 -1319 4414 -5762 -699 949 1081 -3857 816 2031 -135 -2501 -2907 5900 2366 1062 807 2193 2615 2916 -2101 685 -4444 174 -4187 2860 -1070 -154 -858 1122 -3035 -46 -758 1682 -3196 -1012 1122 -72 1477 -5097 2121 -2804 1538 -2408 52 -3857 4616 3560 977 -5272 1331 2593 -3181 207 1079 -939 -661 4788 455 295 -3614 3343 1493 2141 -4004 -349 119 3643 -1246 859 -417 458 1710 1195 4270 1304 -390 -1833 1699 -2166 -1909 1445 3244 -1933 -1828 -635 2272 -4033 -115 -758 -1656 2346 -131 2645 2134 1504 -3701 915 -1384 872 -2071 938 -4400 SO 20180908T110310.0Z 6825.460532 384 1 32.01 2 88.36 83.80 71.97 88.54 0.00 1 0.00 1 0 15 1.827e-02 1.831e-02 1.607e-02 1.595e-02 7.612914e+03 1.091112e+03 4.866828e+02 -6.000000e+00 1.003718e+03 285.47 -2.00 20.00 -2.00 505.29 0.00e+00 9.809217e-04 4.381825e-04 7.388593e-05 -6.000000e+00 5.113649e-04 285.47 -2.00 20.00 -2.00 500.20 0.00e+00 1.953701e+00 3.179832e-01 5.494478e-02 -6.000000e+00 3.586851e-01 229.71 -2.00 3.57 -2.00 501.83 0.00e+00 16.943 0.095 489.00 513.00 1 8.8536e+00 2.4366e-02 2.7637e-02 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