File name: Pandora104s1_Downsview_20181018_L2Fit_fwvt1c21d20180627p1-8.txt File generation date: 20241126T225655.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c21p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 104 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora104_OF_v5d20171009.txt Instrument calibration file used: Pandora104s1_CF_v21d20180627.txt Level 1 file used: Pandora104s1_Downsview_20181018_L1_smca1c21d20180627p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20181018 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 12 to revisit NO2 and SO2 First and last pixel inside fitting window: 1633 1783 Nominal wavelengths inside fitting window [nm]: 492.0163 492.1368 492.2573 492.3778 492.4983 492.6187 492.7391 492.8596 492.9800 493.1003 493.2207 493.3411 493.4614 493.5817 493.7020 493.8223 493.9425 494.0628 494.1830 494.3032 494.4234 494.5436 494.6637 494.7839 494.9040 495.0241 495.1442 495.2643 495.3843 495.5044 495.6244 495.7444 495.8644 495.9844 496.1043 496.2242 496.3442 496.4641 496.5840 496.7038 496.8237 496.9435 497.0633 497.1831 497.3029 497.4227 497.5424 497.6621 497.7818 497.9015 498.0212 498.1409 498.2605 498.3801 498.4997 498.6193 498.7389 498.8585 498.9780 499.0975 499.2170 499.3365 499.4560 499.5754 499.6949 499.8143 499.9337 500.0531 500.1724 500.2918 500.4111 500.5304 500.6497 500.7690 500.8882 501.0075 501.1267 501.2459 501.3651 501.4843 501.6034 501.7226 501.8417 501.9608 502.0799 502.1989 502.3180 502.4370 502.5560 502.6750 502.7940 502.9130 503.0319 503.1509 503.2698 503.3887 503.5075 503.6264 503.7452 503.8641 503.9829 504.1017 504.2204 504.3392 504.4579 504.5766 504.6953 504.8140 504.9327 505.0513 505.1700 505.2886 505.4072 505.5258 505.6443 505.7629 505.8814 505.9999 506.1184 506.2368 506.3553 506.4737 506.5922 506.7106 506.8289 506.9473 507.0657 507.1840 507.3023 507.4206 507.5389 507.6571 507.7754 507.8936 508.0118 508.1300 508.2482 508.3663 508.4845 508.6026 508.7207 508.8388 508.9569 509.0749 509.1929 509.3109 509.4289 509.5469 509.6649 509.7828 509.9007 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20181018T114206.0Z 6865.487570 449 1 32.01 2 89.77 103.72 151.90 332.01 0.00 1 0.00 1 0 15 1.369e-01 1.245e-01 1.347e-01 1.294e-01 -8.222855e+03 7.275962e+03 9.110801e+02 -6.000000e+00 7.381117e+03 280.73 -2.00 20.00 -2.00 505.31 0.00e+00 -2.174741e-03 3.512882e-03 1.658497e-04 -6.000000e+00 3.787457e-03 280.73 -2.00 20.00 -2.00 500.18 0.00e+00 4.513108e+00 2.556696e+00 3.076840e-02 -6.000000e+00 2.673783e+00 225.15 -2.00 3.57 -2.00 501.87 0.00e+00 20.194 0.160 489.00 513.00 1 1.0475e+01 1.9572e-01 3.6371e-02 -6.0000e+00 2.0467e-01 8.5294e-02 5.0187e-02 2.0232e-03 -6.0000e+00 5.3418e-02 2.4371e-06 8.9539e-03 1.0820e-02 1.3617e-04 -6.0000e+00 1.2113e-02 8.7901e-02 -3.1162e-04 12 8 8 10 0 0 76.20 22.09 10.26 0.08790 0.15001 8 2 1 4 0 4000.000 22.09 15.00 19.11 -24040 9105 4967 24293 708 -10559 -1771 181 -13826 -10959 8099 9154 7049 -1934 3731 -2124 -15294 -3618 7584 -11125 -1199 23845 5320 -4535 16467 1621 13988 5203 -25860 -9805 -17594 7586 -8728 14292 9618 18390 -5976 15091 13074 30395 -10713 18684 3369 18509 1958 8870 -12952 15808 -8367 1803 12266 17320 -3053 24979 1495 -7406 -6998 13516 17530 -9608 1820 -20743 14039 -4574 6725 10442 21179 -5303 16686 -4199 3698 10370 -4231 4520 -18524 -155 -6978 6557 -3682 -8766 6868 4450 -440 19920 7416 65856 4419 10128 5272 26238 -3311 -1122 -2188 -6721 16661 -17845 969 -14137 27918 23917 8391 2035 37741 6115 -9266 -5642 -3782 11828 10014 -1964 -1465 -781 -16462 7434 -10775 512 -8582 -15981 2230 11721 -6885 12523 8872 -1448 7123 6111 -2264 12276 2244 10180 -12963 1701 3172 4876 15311 -8353 -1667 -12484 8247 -23524 10510 11836 -16742 -4502 11925 -8452 24027 13378 -13812 25471 -8872 -28783 8146 4799 20110 747 -12684 -1989 201 -17452 -13209 8069 8930 6908 -2048 3733 -2269 -18892 -4128 7968 -14001 -1374 21565 5732 -5398 16081 1810 13803 5522 -35771 -11212 -21568 7366 -10155 13934 9990 17478 -7071 14463 12582 24618 -12826 16980 3567 17108 2130 9005 -15997 14590 -9542 1814 10806 14207 -3000 19030 1471 -8144 -7801 12390 15411 -10863 1843 -26203 12713 -4933 6426 9465 17018 -5411 13677 -4126 3340 8825 -4173 4170 -21476 -149 -6987 5678 -3498 -8723 5923 3973 -412 15493 6575 33850 4068 8856 4851 19944 -3341 -1124 -2253 -7293 14463 -21456 969 -15954 20609 17893 7213 1881 25445 5739 -10143 -5855 -3776 9995 8516 -1886 -1422 -766 -19143 6988 -12135 519 -9480 -18784 2172 10242 -7120 10693 7840 -1427 6492 5609 -2252 10595 2125 8996 -14231 1600 2891 4306 12140 -8373 -1611 -13686 7527 -29353 9521 10587 -19788 -4780 10884 -9351 19188 11486 -14962 18854 -9191 SO 20181018T114610.0Z 6865.490394 453 1 32.01 2 89.06 104.43 152.21 333.87 0.00 1 0.00 1 0 57 1.326e-01 1.285e-01 8.960e-02 8.617e-02 7.306968e+03 6.008668e+03 3.910209e+02 -6.000000e+00 7.151111e+03 280.73 -2.00 20.00 -2.00 505.36 0.00e+00 -1.453660e-03 2.359333e-03 7.529341e-05 -6.000000e+00 3.666699e-03 280.73 -2.00 20.00 -2.00 500.26 0.00e+00 4.149587e+00 1.711029e+00 8.290745e-02 -6.000000e+00 2.584093e+00 225.15 -2.00 3.57 -2.00 501.89 0.00e+00 18.824 0.130 489.00 513.00 1 1.0226e+01 1.3088e-01 3.2768e-02 -6.0000e+00 1.9788e-01 4.5514e-02 3.3022e-02 2.4116e-03 -6.0000e+00 5.1499e-02 3.7280e-06 -4.8673e-03 7.1986e-03 3.3488e-05 -6.0000e+00 1.1662e-02 7.1235e-03 3.4238e-04 12 9 8 11 8 0 33.90 22.19 7.40 0.00712 -0.02664 8 2 1 4 0 4000.000 22.19 15.00 19.12 23564 -3824 21311 -20304 2792 -18040 -1506 -8830 10067 -7288 8092 2940 12096 -2170 19058 -6805 11266 8363 -1780 16343 3173 21992 -5119 6877 -12661 1163 -17988 15502 -6666 7170 -4026 11290 -5278 5187 -2186 -7846 3168 20937 24252 -4722 10928 6882 16136 -17715 12843 -9554 15676 -14607 22273 -27524 10903 -23517 4132 -2257 9440 1880 11803 22584 3466 25162 -5905 10037 -9293 10091 -5944 10417 -3948 5234 -8759 10555 -10279 2548 8762 12567 5875 14678 -785 30235 2748 -4801 3670 -14619 26886 -6651 11953 -24062 15476 406 4245 -6184 -1660 -13947 7204 -16555 5026 9939 5390 2215 1267 15626 2871 22318 -3498 14210 -23757 7406 -7383 13127 2976 10643 -11448 12847 -11963 9354 -17824 7979 8907 11060 18020 -470 26480 -901 30843 -15312 22 -15234 8158 1124 29899 -7804 -8448 -11600 -7567 -3296 -167 6552 27808 4324 -581 16015 3375 10775 -1118 27292 -9173 13739 -18896 11980 -12420 10745 -12721 17478 -3742 16892 -24933 2818 -22652 -1653 -10517 10042 -8512 8014 3039 11289 -2293 16328 -7477 10550 8244 -2002 15692 3456 20065 -6064 7265 -16269 1307 -24154 14998 -7851 7122 -4332 10509 -5819 5364 -2521 -9659 3473 19157 21242 -5394 10695 7017 15164 -23235 12685 -11745 15035 -18490 19453 -38002 10077 -29355 3878 -2237 8554 1895 11084 19355 3563 20906 -6572 9625 -10770 9704 -6629 9783 -4177 4983 -9432 9334 -10921 2384 7775 10871 5511 12656 -770 21530 2508 -4684 3284 -15705 19553 -6696 10190 -29358 12964 393 3943 -6332 -1629 -15475 6622 -19235 4684 8594 4738 1950 1099 11587 2362 15361 -3163 11346 -28676 6747 -7733 11168 2750 9106 -12245 11024 -13151 8430 -20917 7313 8142 10023 15370 -474 20299 -883 21940 -16892 21 -17065 7292 1078 21677 -8108 -8883 -12446 -7660 -3173 -156 5738 20349 4067 -582 13885 3351 10045 -1176 22011 -10536 12670 -23693 10968 -14045 9574 -14238 SO 20181018T115005.0Z 6865.493113 457 1 32.01 2 88.37 105.11 152.49 335.69 0.00 1 0.00 1 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