File name: Pandora104s1_Downsview_20181025_L2Fit_fwvt1c21d20180627p1-8.txt File generation date: 20241126T225714.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c21p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 104 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora104_OF_v5d20171009.txt Instrument calibration file used: Pandora104s1_CF_v21d20180627.txt Level 1 file used: Pandora104s1_Downsview_20181025_L1_smca1c21d20180627p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20181025 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 12 to revisit NO2 and SO2 First and last pixel inside fitting window: 1633 1783 Nominal wavelengths inside fitting window [nm]: 492.0163 492.1368 492.2573 492.3778 492.4983 492.6187 492.7391 492.8596 492.9800 493.1003 493.2207 493.3411 493.4614 493.5817 493.7020 493.8223 493.9425 494.0628 494.1830 494.3032 494.4234 494.5436 494.6637 494.7839 494.9040 495.0241 495.1442 495.2643 495.3843 495.5044 495.6244 495.7444 495.8644 495.9844 496.1043 496.2242 496.3442 496.4641 496.5840 496.7038 496.8237 496.9435 497.0633 497.1831 497.3029 497.4227 497.5424 497.6621 497.7818 497.9015 498.0212 498.1409 498.2605 498.3801 498.4997 498.6193 498.7389 498.8585 498.9780 499.0975 499.2170 499.3365 499.4560 499.5754 499.6949 499.8143 499.9337 500.0531 500.1724 500.2918 500.4111 500.5304 500.6497 500.7690 500.8882 501.0075 501.1267 501.2459 501.3651 501.4843 501.6034 501.7226 501.8417 501.9608 502.0799 502.1989 502.3180 502.4370 502.5560 502.6750 502.7940 502.9130 503.0319 503.1509 503.2698 503.3887 503.5075 503.6264 503.7452 503.8641 503.9829 504.1017 504.2204 504.3392 504.4579 504.5766 504.6953 504.8140 504.9327 505.0513 505.1700 505.2886 505.4072 505.5258 505.6443 505.7629 505.8814 505.9999 506.1184 506.2368 506.3553 506.4737 506.5922 506.7106 506.8289 506.9473 507.0657 507.1840 507.3023 507.4206 507.5389 507.6571 507.7754 507.8936 508.0118 508.1300 508.2482 508.3663 508.4845 508.6026 508.7207 508.8388 508.9569 509.0749 509.1929 509.3109 509.4289 509.5469 509.6649 509.7828 509.9007 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20181025T115104.0Z 6872.493796 375 1 32.01 2 89.77 107.22 84.38 278.55 0.00 1 0.00 1 0 22 1.494e-01 1.443e-01 1.189e-01 1.138e-01 2.665504e+04 9.175456e+03 1.150803e+03 -6.000000e+00 8.026183e+03 279.84 -2.00 20.00 -2.00 505.29 0.00e+00 1.899340e-03 3.062161e-03 3.494585e-04 -6.000000e+00 4.132488e-03 279.84 -2.00 20.00 -2.00 500.41 0.00e+00 -1.320730e+00 2.240866e+00 3.162860e-01 -6.000000e+00 2.943739e+00 224.50 -2.00 3.57 -2.00 501.95 0.00e+00 20.224 0.161 489.00 513.00 1 1.0643e+01 1.6957e-01 4.4535e-02 -6.0000e+00 2.2477e-01 1.3159e-01 4.3190e-02 6.2756e-03 -6.0000e+00 5.9544e-02 2.7805e-06 6.3511e-03 8.0731e-03 1.2706e-04 -6.0000e+00 1.3193e-02 6.3011e-03 -3.7849e-04 12 9 8 11 8 0 91.36 21.98 16.40 0.00630 0.05035 8 2 1 4 0 4000.000 21.98 15.00 18.94 900000 15744 11736 -4384 18416 -12918 -15124 -2427 1838 -21166 12854 -7180 21823 -12092 25798 -9550 17923 4074 10352 20101 -3100 29226 -3213 16183 26301 8779 -12284 4984 5999 -4346 -22533 -4953 2670 -9510 -10715 20492 -808 28127 -5786 11677 16279 24682 26631 3609 4160 -20063 30267 -11313 16123 -17329 14779 -10063 10667 -24954 3725 -18279 7531 8899 8863 3615 16748 19532 -7836 9450 -10028 11223 -20293 28825 -15135 11300 -2341 30457 -29834 1533 5969 16460 1515 33041 18529 8984 9186 9600 4507 10371 23046 -4308 8436 9843 12034 -20105 -4851 -22512 -19355 -21903 9017 -19061 4593 2773 7189 14322 5347 3256 -1405 -2474 -10604 10463 991 1419 -8961 -2288 -11524 18261 -15855 21424 11985 28028 2839 20344 12013 8849 241 15775 6428 -6088 14652 7568 10955 11942 13200 -12307 11151 -15871 38783 -15911 29780 14594 14159 -14765 3836 -9188 2063 910 -3639 13874 -14417 -1102 -8933 3675 -5059 4982 -3812 900000 12687 10094 -4568 15882 -15288 -18705 -2690 1963 -27958 12005 -8040 18251 -13778 20279 -10488 15273 4035 9959 17966 -3457 23935 -3593 15029 22357 8855 -15091 5158 6072 -4696 -27981 -5181 2618 -10793 -12839 18526 -891 23241 -6556 11063 14711 20686 22129 3777 4391 -26955 25074 -13837 14936 -21753 13275 -11128 9490 -30987 3576 -22467 7441 8838 8831 3783 15398 17557 -9231 9453 -12075 10902 -26233 22877 -18094 10402 -2420 22859 -40125 1542 5852 14704 1538 24245 15332 8073 8167 8503 4221 9242 18419 -4548 7938 9097 10796 -24200 -5016 -27683 -23382 -27337 8186 -21580 3939 2308 5575 10256 4094 2544 -1182 -2219 -11044 9352 989 1412 -9746 -2318 -12889 15573 -18842 17744 10801 21554 2786 17262 11314 8637 252 13803 5968 -6237 12357 6903 9676 10485 11453 -13527 9813 -17978 25365 -17325 21014 11935 11857 -16724 3665 -10058 2067 934 -3935 12728 -17291 -1156 -10027 3608 -5308 4671 -3878 SO 20181025T115511.0Z 6872.496655 379 1 32.01 2 89.06 107.94 85.08 279.24 0.00 1 0.00 1 0 36 8.673e-02 8.420e-02 6.728e-02 6.596e-02 3.653410e+02 3.676289e+03 3.688760e+02 -6.000000e+00 4.659910e+03 279.84 -2.00 20.00 -2.00 505.25 0.00e+00 5.018801e-03 1.795001e-03 2.214476e-04 -6.000000e+00 2.395289e-03 279.84 -2.00 20.00 -2.00 500.11 0.00e+00 3.553397e+00 1.305777e+00 1.011818e-01 -6.000000e+00 1.697789e+00 224.50 -2.00 3.57 -2.00 501.76 0.00e+00 18.858 0.131 489.00 513.00 1 9.9207e+00 1.0048e-01 3.3377e-02 -6.0000e+00 1.2986e-01 9.0497e-02 2.5828e-02 2.1759e-03 -6.0000e+00 3.4003e-02 4.9276e-06 7.5008e-03 5.7432e-03 8.7747e-05 -6.0000e+00 7.6482e-03 -4.2894e-02 2.8039e-04 12 9 8 11 8 0 89.40 21.98 8.18 -0.04289 0.00913 8 2 1 4 0 4000.000 21.98 15.00 18.96 -3851 604 15441 15203 2708 -4657 -9118 2213 2862 3266 3784 -5253 -3326 -654 6684 -6940 6058 -11348 2221 2148 -6938 -6715 -3222 -2047 13069 -8598 13372 -1803 -523 2111 -7798 8279 -6432 19441 -4855 26086 -2288 14545 -5522 2949 -10338 -5522 -12905 1945 -791 4271 -6454 13594 13916 5403 1701 4927 15709 3184 2307 681 4164 -8693 3310 -8855 18040 -7130 4773 -2181 10353 -4592 11739 3661 3145 4134 -664 3058 -10402 7602 -14877 13075 -1227 4734 -4649 6752 -21721 2660 -9837 -5402 -4747 2631 -2511 -7480 -6286 13500 2536 5584 5534 -1291 5694 -10608 2383 -9777 17371 -9626 33 -3783 7767 6883 11100 4070 3829 -760 -2328 10616 -269 -123 8070 2957 1237 11933 -11141 20605 -10958 11300 -6615 5055 -13072 7428 -3817 9289 1577 10937 8590 22045 -1722 -3446 3025 -15477 4070 -18775 8869 -2822 14191 -9796 2908 217 -3595 -3240 1647 -2193 8927 -1685 -1723 6278 1120 -3785 580 13298 13616 2797 -5262 -10976 2400 3082 3443 3895 -5835 -3565 -675 6373 -7559 5892 -13353 2360 2301 -8086 -7821 -3630 -2290 12767 -10347 12958 -2008 -563 2124 -8446 7709 -6997 17163 -5597 22411 -2552 13665 -6224 3039 -12136 -6244 -15861 2098 -887 4580 -7636 13078 13131 5415 1713 4684 13263 3033 2281 707 4280 -10205 3456 -10355 16230 -8235 4926 -2406 10033 -5057 10834 3591 3069 3934 -651 2886 -11241 6981 -17205 11479 -1210 4311 -4586 5940 -25051 2443 -10220 -5379 -4736 2459 -2464 -7675 -6343 11257 2357 5086 5150 -1299 5335 -11453 2238 -10091 13454 -9421 29 -3434 6419 5935 9453 3698 3439 -703 -2160 8743 -251 -117 7204 2817 1210 10573 -12405 16954 -12166 9968 -6826 4606 -14048 6590 -3818 8206 1502 9535 7623 17241 -1698 -3406 2754 -16619 3585 -20656 7635 -2780 12018 -10575 2800 215 -3695 -3339 1624 -2242 8096 -1651 -1643 5457 1030 SO 20181025T115910.0Z 6872.499421 383 1 32.01 2 88.38 108.63 85.76 279.90 0.00 1 0.00 1 0 22 3.944e-02 3.867e-02 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