File name: Pandora104s1_Downsview_20181114_L2Fit_fwvt1c21d20180627p1-8.txt File generation date: 20241126T230033.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c21p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 104 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora104_OF_v5d20171009.txt Instrument calibration file used: Pandora104s1_CF_v21d20180627.txt Level 1 file used: Pandora104s1_Downsview_20181114_L1_smca1c21d20180627p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20181114 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 12 to revisit NO2 and SO2 First and last pixel inside fitting window: 1633 1783 Nominal wavelengths inside fitting window [nm]: 492.0163 492.1368 492.2573 492.3778 492.4983 492.6187 492.7391 492.8596 492.9800 493.1003 493.2207 493.3411 493.4614 493.5817 493.7020 493.8223 493.9425 494.0628 494.1830 494.3032 494.4234 494.5436 494.6637 494.7839 494.9040 495.0241 495.1442 495.2643 495.3843 495.5044 495.6244 495.7444 495.8644 495.9844 496.1043 496.2242 496.3442 496.4641 496.5840 496.7038 496.8237 496.9435 497.0633 497.1831 497.3029 497.4227 497.5424 497.6621 497.7818 497.9015 498.0212 498.1409 498.2605 498.3801 498.4997 498.6193 498.7389 498.8585 498.9780 499.0975 499.2170 499.3365 499.4560 499.5754 499.6949 499.8143 499.9337 500.0531 500.1724 500.2918 500.4111 500.5304 500.6497 500.7690 500.8882 501.0075 501.1267 501.2459 501.3651 501.4843 501.6034 501.7226 501.8417 501.9608 502.0799 502.1989 502.3180 502.4370 502.5560 502.6750 502.7940 502.9130 503.0319 503.1509 503.2698 503.3887 503.5075 503.6264 503.7452 503.8641 503.9829 504.1017 504.2204 504.3392 504.4579 504.5766 504.6953 504.8140 504.9327 505.0513 505.1700 505.2886 505.4072 505.5258 505.6443 505.7629 505.8814 505.9999 506.1184 506.2368 506.3553 506.4737 506.5922 506.7106 506.8289 506.9473 507.0657 507.1840 507.3023 507.4206 507.5389 507.6571 507.7754 507.8936 508.0118 508.1300 508.2482 508.3663 508.4845 508.6026 508.7207 508.8388 508.9569 509.0749 509.1929 509.3109 509.4289 509.5469 509.6649 509.7828 509.9007 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20181114T121732.0Z 6892.512176 504 1 32.01 2 89.78 115.99 147.41 48.76 0.00 1 0.00 1 0 15 2.019e-01 1.799e-01 1.581e-01 1.470e-01 7.693413e+03 9.865808e+03 9.283349e+02 -6.000000e+00 1.072375e+04 277.28 -2.00 20.00 -2.00 505.22 0.00e+00 2.706620e-03 4.023573e-03 5.970126e-05 -6.000000e+00 5.544259e-03 277.28 -2.00 20.00 -2.00 500.11 0.00e+00 2.899610e+00 2.959064e+00 4.038739e-02 -6.000000e+00 3.956780e+00 222.65 -2.00 3.57 -2.00 501.72 0.00e+00 20.325 0.164 489.00 513.00 1 1.0605e+01 2.2816e-01 3.6695e-02 -6.0000e+00 3.0221e-01 9.2307e-02 5.7936e-02 2.3733e-03 -6.0000e+00 7.9547e-02 2.0911e-06 1.5179e-02 1.2197e-02 1.0414e-04 -6.0000e+00 1.7849e-02 1.7001e-01 -1.3073e-03 12 8 8 10 0 0 -311.99 21.98 20.47 0.17001 0.27530 8 2 1 4 0 4000.000 21.98 15.00 18.95 9608 7275 -13379 36063 -4841 13062 -7095 14120 15139 26416 -5805 14003 -4033 681 17580 15328 49692 -10728 23039 -937 22332 940 2311 -13505 13416 -12120 8672 -22810 4897 -13897 -5544 17721 -5971 7309 -10393 40509 4812 9718 -14492 2894 -19014 37354 -33432 12127 -23667 2629 4234 945 21000 2719 48347 12250 -2560 31408 7712 8378 27021 -11523 21682 -16576 21719 -13621 45097 -22875 -9680 -900 34009 -3875 11823 28986 -14186 1095 12850 11991 1962 9162 -13390 -8535 -19935 28494 -11858 35007 -37653 22610 3413 9591 -12398 37665 -5552 16362 -17528 20412 8519 -2903 5734 -17641 18210 2210 17044 -17394 25801 -17307 18357 -25649 15886 10241 7358 23484 14337 -8715 -12396 12995 7132 12308 2708 39837 6519 59950 -2021 48458 -32395 -83 -20139 11130 -15078 -8451 1263 -5291 2013 25678 6144 21449 23176 37082 13594 -6654 24845 8720 18499 -3917 18712 -23928 6432 -5154 7879 -23430 33240 -7735 20142 7971 53964 8426 6681 -15542 26997 -5451 12666 -8481 13831 14639 22484 -6633 13094 -4406 704 15397 13801 32792 -12942 20662 -1058 20184 1044 2534 -17338 13407 -15400 8989 -31660 5066 -16530 -6028 15530 -6698 7544 -13016 31163 5135 9812 -18220 3061 -24888 28785 -51233 12156 -33742 2918 4590 1042 18801 2827 31568 11006 -2617 23404 7437 8275 22817 -14121 19316 -21183 19235 -17036 32248 -31272 -11535 -970 25785 -4155 10811 22148 -16162 1080 11403 10878 1982 8549 -15143 -9030 -23304 20879 -12730 24256 -52330 17752 3256 8681 -13823 25973 -5735 13699 -20321 16654 7915 -3013 5379 -20130 14377 1974 12953 -17937 17405 -17800 13838 -30830 13311 9106 6672 18030 11883 -9060 -13578 11329 6647 10996 2661 27551 6250 34965 -2125 31088 -44138 -81 -23661 9748 -17138 -9035 1232 -5503 1941 19823 5720 16966 17708 24646 11241 -6729 19085 7960 15564 -4139 16104 -31086 6278 -5644 7624 -30520 24903 -8373 16328 7179 31645 SO 20181114T122142.0Z 6892.515070 508 1 32.01 2 89.11 116.72 146.86 50.17 0.00 1 0.00 1 0 22 1.034e-01 9.542e-02 8.297e-02 8.085e-02 -4.353466e+03 4.451661e+03 2.974701e+02 -6.000000e+00 5.501990e+03 277.28 -2.00 20.00 -2.00 505.18 0.00e+00 4.065179e-03 2.155546e-03 3.568549e-04 -6.000000e+00 2.837173e-03 277.28 -2.00 20.00 -2.00 500.13 0.00e+00 6.406371e-01 1.622043e+00 8.064245e-02 -6.000000e+00 2.011734e+00 222.65 -2.00 3.57 -2.00 501.76 0.00e+00 19.036 0.134 489.00 513.00 1 1.0358e+01 1.2338e-01 3.4183e-02 -6.0000e+00 1.5393e-01 1.7710e-01 3.2997e-02 2.2126e-03 -6.0000e+00 4.0027e-02 3.9428e-06 -1.3889e-02 6.8966e-03 1.0228e-04 -6.0000e+00 9.1082e-03 -5.8884e-02 8.0074e-04 12 9 8 11 8 0 -492.53 21.98 7.51 -0.05888 -0.15523 8 2 1 4 0 4000.000 21.98 15.00 18.97 -1397 3685 1821 4517 4861 1090 13632 15286 9992 14176 1321 -4646 -3943 -6337 -8272 -15103 9369 3994 -917 -6332 14762 -11554 6011 -4721 24660 -1473 5698 -4799 -424 1167 4992 -6469 -8740 -318 -14739 5687 5421 5131 -11095 908 2564 9514 1973 5374 3195 15190 25 25943 -9399 -4056 -4691 2330 511 -19298 1078 -10199 -10129 -5982 -7579 -13133 12113 1416 -282 1444 30984 181 15188 -2789 -8279 -6462 2761 28187 2636 -3347 -8415 -4559 -8324 2494 -4883 9060 -8465 20400 -1262 32668 9348 23411 2721 -1566 18614 -9371 16726 -4842 -1768 -6559 -6077 -12226 8233 -3425 2560 -4281 16793 3466 5631 3830 -1417 -5660 2205 424 1716 145 -5695 12776 -7651 -5463 -4827 -10920 -10594 17318 -13998 1158 -11041 17880 1534 21896 16101 9055 -12411 13802 52 843 8744 -8230 7168 -636 -7848 -11659 -4557 -2329 12516 -5037 10484 13007 15749 160 5829 2654 1535 -15172 13193 4059 9500 -1384 3482 1790 4483 4974 1175 13295 14896 10277 13925 1438 -5268 -4383 -7078 -9303 -17987 8855 4028 -995 -7413 14125 -14196 6243 -5431 21499 -1662 5979 -5534 -464 1222 4829 -6897 -9573 -328 -18202 5914 5636 5282 -13221 952 2627 9153 2060 5488 3377 14453 27 22106 -11078 -4463 -5069 2280 498 -22443 1039 -11327 -11591 -6712 -8684 -15835 11405 1477 -301 1520 24516 190 13606 -2916 -8996 -6836 2630 20776 2488 -3374 -9031 -4764 -8923 2358 -4866 7852 -8647 15841 -1218 22818 8181 18074 2575 -1543 15100 -9933 13859 -4957 -1784 -7081 -6615 -14094 7737 -3576 2465 -4283 13346 3084 4944 3480 -1397 -5870 2089 401 1578 134 -5614 10736 -7979 -5700 -5088 -12304 -11946 14941 -16238 1145 -12036 14577 1448 16902 13267 8035 -13486 11667 50 800 7718 -8516 6284 -588 -7649 -11634 -4269 -2183 10362 -4987 9010 10929 12837 151 5262 2474 1439 -16380 10521 3431 7541 SO 20181114T122539.0Z 6892.517813 512 1 32.01 2 88.47 117.41 146.32 51.47 0.00 1 0.00 1 0 15 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