File name: Pandora104s1_Downsview_20190104_L2Fit_fwvt1c21d20180627p1-8.txt File generation date: 20241126T234746.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c21p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 104 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora104_OF_v5d20171009.txt Instrument calibration file used: Pandora104s1_CF_v21d20180627.txt Level 1 file used: Pandora104s1_Downsview_20190104_L1_smca1c21d20180627p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20190104 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 12 to revisit NO2 and SO2 First and last pixel inside fitting window: 1633 1783 Nominal wavelengths inside fitting window [nm]: 492.0163 492.1368 492.2573 492.3778 492.4983 492.6187 492.7391 492.8596 492.9800 493.1003 493.2207 493.3411 493.4614 493.5817 493.7020 493.8223 493.9425 494.0628 494.1830 494.3032 494.4234 494.5436 494.6637 494.7839 494.9040 495.0241 495.1442 495.2643 495.3843 495.5044 495.6244 495.7444 495.8644 495.9844 496.1043 496.2242 496.3442 496.4641 496.5840 496.7038 496.8237 496.9435 497.0633 497.1831 497.3029 497.4227 497.5424 497.6621 497.7818 497.9015 498.0212 498.1409 498.2605 498.3801 498.4997 498.6193 498.7389 498.8585 498.9780 499.0975 499.2170 499.3365 499.4560 499.5754 499.6949 499.8143 499.9337 500.0531 500.1724 500.2918 500.4111 500.5304 500.6497 500.7690 500.8882 501.0075 501.1267 501.2459 501.3651 501.4843 501.6034 501.7226 501.8417 501.9608 502.0799 502.1989 502.3180 502.4370 502.5560 502.6750 502.7940 502.9130 503.0319 503.1509 503.2698 503.3887 503.5075 503.6264 503.7452 503.8641 503.9829 504.1017 504.2204 504.3392 504.4579 504.5766 504.6953 504.8140 504.9327 505.0513 505.1700 505.2886 505.4072 505.5258 505.6443 505.7629 505.8814 505.9999 506.1184 506.2368 506.3553 506.4737 506.5922 506.7106 506.8289 506.9473 507.0657 507.1840 507.3023 507.4206 507.5389 507.6571 507.7754 507.8936 508.0118 508.1300 508.2482 508.3663 508.4845 508.6026 508.7207 508.8388 508.9569 509.0749 509.1929 509.3109 509.4289 509.5469 509.6649 509.7828 509.9007 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190104T125843.0Z 6943.540776 494 1 32.01 2 89.79 122.57 78.85 134.99 0.00 1 0.00 1 0 15 2.442e-02 2.414e-02 1.912e-02 1.894e-02 5.448209e+03 1.206279e+03 3.180480e+02 -6.000000e+00 1.274244e+03 272.48 -2.00 20.00 -2.00 505.27 0.00e+00 2.636405e-03 5.033280e-04 1.203630e-04 -6.000000e+00 6.623002e-04 272.48 -2.00 20.00 -2.00 500.09 0.00e+00 1.974124e+00 3.803207e-01 5.708896e-02 -6.000000e+00 4.789369e-01 222.96 -2.00 3.57 -2.00 501.73 0.00e+00 20.446 0.167 489.00 513.00 1 8.5860e+00 2.9025e-02 3.7191e-02 -6.0000e+00 3.6547e-02 1.3168e-01 7.4777e-03 2.3211e-03 -6.0000e+00 9.5818e-03 1.7622e-05 -3.6629e-04 1.5946e-03 4.8814e-05 -6.0000e+00 2.1533e-03 4.1393e-03 2.1264e-05 12 8 8 10 0 0 -13.17 21.58 2.73 0.00414 0.00160 8 2 1 4 0 4000.000 21.58 14.99 18.60 -2831 202 -5629 106 -4375 -833 -3247 -1603 1187 -555 1770 -2467 1775 -1373 1646 -2892 5642 -3176 949 -3726 4703 -2715 1718 -695 1851 631 -656 2596 -3088 1079 1795 1477 -1682 3144 1467 1181 748 2715 464 1712 -701 -348 -711 2343 -1374 3004 -359 1423 451 985 3385 -4385 851 -3038 1479 -1514 -162 -1468 -72 -896 1782 591 1723 -1861 3209 -1900 4117 1971 791 4525 -2600 -204 -1427 3246 448 3410 -3649 2414 -2400 1145 -1009 4215 -4253 -205 -555 -72 4102 -1803 404 -1840 2970 -879 3993 -2696 2331 -1768 2043 -1638 3575 -4447 2020 122 4219 -1950 -1264 1056 -343 -1649 -1915 2703 -1637 3266 -39 4146 -599 959 -2753 4502 -2338 -2024 -1513 1662 -855 -275 -248 -174 2305 -2188 2438 -3096 -2214 -1142 2316 -1931 2867 -945 3360 -375 5088 -1614 3699 -2520 268 2041 -745 -2791 -2153 -980 -6026 -414 -2259 -2760 194 -5864 109 -4808 -900 -3668 -1802 1302 -613 1872 -2690 1831 -1436 1658 -3033 5508 -3435 1018 -4249 4937 -3061 1858 -769 2017 698 -730 2784 -3445 1116 1782 1469 -1737 3199 1579 1293 816 2873 496 1789 -748 -371 -769 2487 -1531 3231 -397 1533 482 1029 3357 -4547 823 -3026 1437 -1567 -170 -1584 -76 -959 1851 623 1807 -2020 3306 -2027 4073 1955 784 4280 -2588 -197 -1401 3076 444 3291 -3705 2259 -2315 1062 -949 3789 -4175 -194 -531 -69 3806 -1766 386 -1787 2757 -850 3748 -2734 2243 -1731 1883 -1524 3082 -4051 1689 103 3507 -1781 -1200 998 -327 -1574 -1808 2429 -1552 3002 -38 3872 -589 931 -2782 4284 -2386 -2042 -1492 1565 -811 -257 -235 -165 2139 -2125 2255 -3009 -2143 -1086 2086 -1785 2511 -855 2969 -352 4596 -1572 3467 -2520 261 1967 -740 -2822 -2150 -949 -5966 -381 -2108 SO 20190104T130245.0Z 6943.543576 498 1 32.01 2 89.18 123.27 78.36 135.78 0.00 1 0.00 1 0 15 1.218e-02 1.179e-02 1.189e-02 1.181e-02 3.041850e+03 7.079367e+02 1.494685e+02 -6.000000e+00 6.354210e+02 272.48 -2.00 20.00 -2.00 505.25 0.00e+00 3.139742e-03 3.135337e-04 1.694906e-04 -6.000000e+00 3.302764e-04 272.48 -2.00 20.00 -2.00 500.13 0.00e+00 1.764870e+00 2.356758e-01 4.671470e-02 -6.000000e+00 2.387911e-01 222.96 -2.00 3.57 -2.00 501.76 0.00e+00 19.295 0.140 489.00 513.00 1 8.2616e+00 1.7990e-02 3.3693e-02 -6.0000e+00 1.8222e-02 1.2968e-01 4.6645e-03 1.9870e-03 -6.0000e+00 4.7767e-03 2.8995e-05 9.6998e-04 1.0119e-03 4.9698e-05 -6.0000e+00 1.0741e-03 1.1054e-02 -1.3325e-05 12 8 8 10 0 0 41.34 21.69 0.99 0.01105 0.01778 8 2 1 4 0 4000.000 21.69 15.00 18.61 -2920 1057 -1735 722 -788 94 -536 537 -297 -124 1169 -135 -1743 -1667 445 -327 -366 1346 -257 -864 1461 662 932 120 1478 -451 1603 1128 1118 1005 -238 -307 -2381 -1266 -700 -466 -736 1097 -178 344 127 1772 -425 -297 188 1151 338 -819 -533 573 200 -71 -576 -510 1235 -963 1091 -1907 -659 -43 1202 612 1178 153 1835 -596 213 1473 -250 -493 -2716 606 -617 -1696 903 253 -2454 233 -115 34 821 73 418 3415 1052 712 -248 625 1916 377 -531 -360 -1545 -1054 -1233 -2269 -555 -522 1268 -110 1124 -3506 5301 -179 -110 -624 -644 520 -1531 1089 -958 130 -1394 1571 -745 1910 263 1083 -637 -949 1596 81 434 213 152 1064 1290 538 995 397 -408 -871 511 -1518 -510 -1811 324 -405 -201 -47 2019 -251 2050 -1528 -125 300 -549 -2206 1733 -1069 -1515 -2849 1007 -1746 737 -837 101 -590 590 -329 -135 1238 -143 -1849 -1741 451 -334 -377 1391 -278 -953 1571 717 1008 131 1606 -500 1733 1218 1187 1030 -239 -309 -2463 -1340 -765 -514 -806 1169 -190 362 134 1844 -457 -322 205 1253 370 -895 -571 597 203 -71 -563 -495 1203 -991 1130 -2061 -704 -45 1252 643 1239 162 1910 -626 218 1465 -250 -488 -2701 581 -602 -1685 889 251 -2457 223 -108 32 761 68 394 3130 994 681 -240 599 1805 359 -512 -348 -1538 -1059 -1237 -2257 -533 -490 1140 -98 967 -3145 4451 -163 -105 -602 -617 486 -1439 996 -905 124 -1365 1514 -740 1855 261 1072 -641 -948 1529 78 408 200 145 1008 1217 512 939 375 -391 -829 471 -1404 -463 -1659 296 -382 -191 -46 1924 -246 1961 -1518 -123 294 -537 -2148 1583 -983 -1397 SO 20190104T130639.0Z 6943.546285 502 1 32.01 2 88.60 123.95 77.89 136.54 0.00 1 0.00 1 0 22 1.248e-02 1.304e-02 6.542e-03 6.522e-03 6.153231e+03 4.076769e+02 4.181189e+02 -6.000000e+00 6.513229e+02 272.48 -2.00 20.00 -2.00 505.34 0.00e+00 3.493126e-03 1.737431e-04 1.746017e-04 -6.000000e+00 3.385343e-04 272.48 -2.00 20.00 -2.00 500.54 0.00e+00 1.491235e+00 1.278957e-01 5.725467e-02 -6.000000e+00 2.447999e-01 222.96 -2.00 3.57 -2.00 502.12 0.00e+00 17.814 0.110 489.00 513.00 1 7.8309e+00 9.7481e-03 2.9904e-02 -6.0000e+00 1.8680e-02 6.5840e-02 2.5021e-03 2.0088e-03 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