File name: Pandora104s1_Downsview_20190201_L2Fit_fwvt1c21d20180627p1-8.txt File generation date: 20241126T234936.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c21p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 104 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora104_OF_v5d20171009.txt Instrument calibration file used: Pandora104s1_CF_v21d20180627.txt Level 1 file used: Pandora104s1_Downsview_20190201_L1_smca1c21d20180627p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20190201 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 12 to revisit NO2 and SO2 First and last pixel inside fitting window: 1633 1783 Nominal wavelengths inside fitting window [nm]: 492.0163 492.1368 492.2573 492.3778 492.4983 492.6187 492.7391 492.8596 492.9800 493.1003 493.2207 493.3411 493.4614 493.5817 493.7020 493.8223 493.9425 494.0628 494.1830 494.3032 494.4234 494.5436 494.6637 494.7839 494.9040 495.0241 495.1442 495.2643 495.3843 495.5044 495.6244 495.7444 495.8644 495.9844 496.1043 496.2242 496.3442 496.4641 496.5840 496.7038 496.8237 496.9435 497.0633 497.1831 497.3029 497.4227 497.5424 497.6621 497.7818 497.9015 498.0212 498.1409 498.2605 498.3801 498.4997 498.6193 498.7389 498.8585 498.9780 499.0975 499.2170 499.3365 499.4560 499.5754 499.6949 499.8143 499.9337 500.0531 500.1724 500.2918 500.4111 500.5304 500.6497 500.7690 500.8882 501.0075 501.1267 501.2459 501.3651 501.4843 501.6034 501.7226 501.8417 501.9608 502.0799 502.1989 502.3180 502.4370 502.5560 502.6750 502.7940 502.9130 503.0319 503.1509 503.2698 503.3887 503.5075 503.6264 503.7452 503.8641 503.9829 504.1017 504.2204 504.3392 504.4579 504.5766 504.6953 504.8140 504.9327 505.0513 505.1700 505.2886 505.4072 505.5258 505.6443 505.7629 505.8814 505.9999 506.1184 506.2368 506.3553 506.4737 506.5922 506.7106 506.8289 506.9473 507.0657 507.1840 507.3023 507.4206 507.5389 507.6571 507.7754 507.8936 508.0118 508.1300 508.2482 508.3663 508.4845 508.6026 508.7207 508.8388 508.9569 509.0749 509.1929 509.3109 509.4289 509.5469 509.6649 509.7828 509.9007 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190201T124119.0Z 6971.528692 438 1 32.01 2 89.78 114.25 73.21 146.74 0.00 1 0.00 1 0 15 5.287e-02 5.180e-02 4.461e-02 4.414e-02 1.856444e+03 2.521031e+03 7.854722e+01 -6.000000e+00 2.750522e+03 271.77 -2.00 20.00 -2.00 505.30 0.00e+00 3.096687e-03 1.166618e-03 1.572993e-04 -6.000000e+00 1.431067e-03 271.77 -2.00 20.00 -2.00 500.29 0.00e+00 3.152336e+00 8.703022e-01 7.295257e-02 -6.000000e+00 1.037276e+00 224.08 -2.00 3.57 -2.00 501.91 0.00e+00 20.440 0.166 489.00 513.00 1 9.3720e+00 6.6430e-02 3.7346e-02 -6.0000e+00 7.9135e-02 8.6894e-02 1.7160e-02 2.2865e-03 -6.0000e+00 2.0729e-02 7.3548e-06 4.9034e-03 3.7962e-03 4.4124e-05 -6.0000e+00 4.6721e-03 2.7484e-02 -5.3450e-05 12 8 8 10 0 0 93.18 21.79 5.53 0.02748 0.06150 8 2 1 4 0 4000.000 21.79 15.00 18.74 -8593 6904 -2958 5413 -223 7995 46 3823 2205 -3540 6315 -1185 1316 -9508 3801 -4503 4374 -5931 3590 -7167 1214 -14 6116 -4286 3207 -606 7727 612 4926 1529 1729 -2019 938 8561 -2930 -2967 -9235 -1248 -4993 8137 -8008 9093 -4747 -342 -40 1831 1119 4283 2111 -292 4959 7080 7478 -1419 -6859 -4280 510 -4338 2350 -5875 696 -4145 10668 -3301 8232 -1323 5113 -3308 350 2958 -2910 6471 -7315 4030 -5359 4318 -3786 6362 -13197 5878 -5060 4580 -3020 2897 -9038 11630 -3010 5492 -2387 9298 4887 -1902 120 -4475 -1529 -1129 99 -5355 -101 -4393 2391 1376 2504 6150 1703 1617 1557 -4284 -7156 805 -1228 7209 -237 65 1724 11149 -2757 2726 3387 1977 -6398 581 -6330 4663 -6419 9692 -4553 11736 3613 -2080 -1024 -143 -3621 -3235 3246 9518 198 -8663 3050 -5005 3004 -7145 7649 -4696 2114 -939 2505 -5002 16056 449 -131 -8600 6068 -2963 5187 -231 7786 49 3982 2332 -3890 6203 -1239 1321 -10478 3656 -4705 4253 -6528 3714 -8287 1291 -15 6223 -4842 3402 -666 7797 656 4956 1525 1688 -2054 940 8316 -3285 -3341 -10914 -1353 -5546 7895 -9096 8822 -5325 -372 -44 1980 1212 4434 2197 -305 4757 6480 6720 -1391 -7295 -4589 535 -4807 2438 -6573 728 -4580 10241 -3627 8022 -1392 4960 -3425 346 2813 -2885 5851 -7610 3802 -5616 4099 -3804 5672 -14067 5189 -4950 4118 -2933 2663 -9419 10004 -2982 5002 -2336 8129 4471 -1875 119 -4661 -1537 -1110 95 -5260 -92 -4071 2036 1190 2188 5391 1610 1531 1458 -4184 -7099 743 -1176 6469 -233 65 1694 10031 -2856 2693 3317 1934 -6678 559 -6444 4289 -6646 8606 -4642 10241 3392 -2069 -1012 -139 -3546 -3119 2915 8073 188 -9170 2920 -5246 2942 -7738 7203 -5011 2118 -968 2470 -5182 13206 423 -125 SO 20190201T124525.0Z 6971.531539 442 1 32.01 2 89.11 114.96 72.83 147.62 0.00 1 0.00 1 0 15 2.784e-02 2.790e-02 2.486e-02 2.471e-02 9.118085e+02 1.361762e+03 2.141586e+01 -6.000000e+00 1.448893e+03 271.77 -2.00 20.00 -2.00 505.30 0.00e+00 4.007588e-03 6.562342e-04 1.876834e-04 -6.000000e+00 7.537771e-04 271.77 -2.00 20.00 -2.00 500.33 0.00e+00 2.715583e+00 4.875200e-01 3.651341e-02 -6.000000e+00 5.477297e-01 224.08 -2.00 3.57 -2.00 501.95 0.00e+00 19.130 0.136 489.00 513.00 1 8.9762e+00 3.7247e-02 3.3196e-02 -6.0000e+00 4.1774e-02 8.2176e-02 9.6318e-03 1.8595e-03 -6.0000e+00 1.0976e-02 1.3422e-05 6.9266e-03 2.1459e-03 5.1363e-05 -6.0000e+00 2.4588e-03 2.6048e-02 -2.1075e-04 12 8 8 10 0 0 99.53 21.79 0.77 0.02605 0.07409 8 2 1 4 0 4000.000 21.79 14.99 18.75 3425 -4656 2337 -1460 -506 -423 5267 -1954 359 -1225 2297 228 -2426 543 -500 1093 -4814 5576 -4145 4221 -2240 -2330 -660 4703 -2511 -1106 56 1413 424 2022 -197 3127 -2325 -146 1652 -2521 -484 -4113 1873 -3453 3468 -1713 -70 -384 773 -488 3502 1188 3467 3665 702 1093 -3110 1953 347 7412 -1497 307 -4166 -460 -6543 281 -2225 4183 -2704 4197 -1521 7241 49 3157 -1069 -200 3609 178 158 -1585 2132 -6407 1075 -4015 -536 -2711 -1348 1134 802 -2827 1532 -869 1792 713 1178 -283 2029 2233 -3644 942 -2223 4145 -5223 2436 -1194 2829 -1056 -112 -2148 4358 -2518 93 878 4893 -1669 -736 -1228 2424 1741 1942 824 772 3354 -1144 814 -7517 1583 1502 2508 -1523 588 3479 979 895 -1678 -1431 1106 -1374 -4502 -3887 -1307 3450 877 106 -5705 436 -5533 127 5748 740 -1057 1722 3554 2024 -382 3030 -4537 2204 -1481 -520 -443 5334 -2135 384 -1308 2326 233 -2504 537 -497 1070 -5050 5412 -4555 4318 -2431 -2536 -707 4805 -2777 -1207 60 1488 442 1990 -193 2989 -2371 -152 1747 -2793 -519 -4529 1926 -3706 3487 -1826 -74 -414 835 -536 3685 1261 3545 3665 700 1058 -3088 1844 343 7063 -1593 325 -4594 -488 -7334 297 -2418 4276 -2933 4194 -1577 6788 48 3006 -1043 -194 3381 175 157 -1598 2031 -6486 1002 -3914 -503 -2621 -1293 1063 761 -2800 1455 -843 1687 678 1119 -275 1969 2191 -3772 918 -2200 3775 -5075 2146 -1066 2435 -961 -104 -2113 4032 -2458 87 808 4342 -1606 -714 -1219 2361 1723 1925 831 782 3307 -1161 798 -7883 1505 1433 2399 -1519 575 3315 950 871 -1681 -1412 1044 -1312 -4386 -3764 -1261 3254 859 106 -6081 439 -5910 129 5558 751 -1080 1673 3301 1875 -364 SO 20190201T124931.0Z 6971.534387 446 1 32.01 2 88.44 115.68 72.45 148.50 0.00 1 0.00 1 0 15 1.930e-02 1.921e-02 1.777e-02 1.768e-02 2.291573e+03 1.024078e+03 2.108871e+02 -6.000000e+00 1.004306e+03 271.77 -2.00 20.00 -2.00 505.30 0.00e+00 3.120066e-03 4.690654e-04 1.478342e-04 -6.000000e+00 5.224880e-04 271.77 -2.00 20.00 -2.00 500.34 0.00e+00 1.970821e+00 3.493225e-01 2.418383e-02 -6.000000e+00 3.787993e-01 224.08 -2.00 3.57 -2.00 501.95 0.00e+00 17.391 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