File name: Pandora104s1_Downsview_20190210_L2Fit_fwvt1c21d20180627p1-8.txt File generation date: 20241127T000054.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c21p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 104 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora104_OF_v5d20171009.txt Instrument calibration file used: Pandora104s1_CF_v21d20180627.txt Level 1 file used: Pandora104s1_Downsview_20190210_L1_smca1c21d20180627p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20190210 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 12 to revisit NO2 and SO2 First and last pixel inside fitting window: 1633 1783 Nominal wavelengths inside fitting window [nm]: 492.0163 492.1368 492.2573 492.3778 492.4983 492.6187 492.7391 492.8596 492.9800 493.1003 493.2207 493.3411 493.4614 493.5817 493.7020 493.8223 493.9425 494.0628 494.1830 494.3032 494.4234 494.5436 494.6637 494.7839 494.9040 495.0241 495.1442 495.2643 495.3843 495.5044 495.6244 495.7444 495.8644 495.9844 496.1043 496.2242 496.3442 496.4641 496.5840 496.7038 496.8237 496.9435 497.0633 497.1831 497.3029 497.4227 497.5424 497.6621 497.7818 497.9015 498.0212 498.1409 498.2605 498.3801 498.4997 498.6193 498.7389 498.8585 498.9780 499.0975 499.2170 499.3365 499.4560 499.5754 499.6949 499.8143 499.9337 500.0531 500.1724 500.2918 500.4111 500.5304 500.6497 500.7690 500.8882 501.0075 501.1267 501.2459 501.3651 501.4843 501.6034 501.7226 501.8417 501.9608 502.0799 502.1989 502.3180 502.4370 502.5560 502.6750 502.7940 502.9130 503.0319 503.1509 503.2698 503.3887 503.5075 503.6264 503.7452 503.8641 503.9829 504.1017 504.2204 504.3392 504.4579 504.5766 504.6953 504.8140 504.9327 505.0513 505.1700 505.2886 505.4072 505.5258 505.6443 505.7629 505.8814 505.9999 506.1184 506.2368 506.3553 506.4737 506.5922 506.7106 506.8289 506.9473 507.0657 507.1840 507.3023 507.4206 507.5389 507.6571 507.7754 507.8936 508.0118 508.1300 508.2482 508.3663 508.4845 508.6026 508.7207 508.8388 508.9569 509.0749 509.1929 509.3109 509.4289 509.5469 509.6649 509.7828 509.9007 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190210T123010.0Z 6980.520949 472 1 32.01 2 89.78 110.30 118.20 52.43 0.00 1 0.00 1 0 36 7.358e-02 6.877e-02 5.312e-02 5.211e-02 -3.420575e+03 2.813713e+03 3.062207e+01 -6.000000e+00 3.830472e+03 271.77 -2.00 20.00 -2.00 505.22 0.00e+00 3.464602e-03 1.377389e-03 1.811359e-04 -6.000000e+00 1.990585e-03 271.77 -2.00 20.00 -2.00 500.06 0.00e+00 2.657368e+00 1.043879e+00 9.612053e-02 -6.000000e+00 1.442135e+00 224.44 -2.00 3.57 -2.00 501.71 0.00e+00 20.434 0.166 489.00 513.00 1 9.5841e+00 7.9822e-02 3.7696e-02 -6.0000e+00 1.1007e-01 1.4188e-01 2.0881e-02 2.5325e-03 -6.0000e+00 2.8757e-02 6.1918e-06 3.2698e-03 4.4663e-03 4.6850e-05 -6.0000e+00 6.4874e-03 2.7988e-02 1.3485e-04 12 9 8 11 8 0 -120.92 21.88 2.28 0.02799 0.05067 8 2 1 4 0 4000.000 21.88 15.00 18.77 -6268 -815 1607 -5973 6655 8467 2092 5712 1942 406 3348 2636 10197 9302 6347 5261 -4885 -5223 -6530 -2403 -9442 727 -14350 9569 -4601 17863 -6037 9682 -1041 4153 1034 4972 6777 -6831 4992 -7062 5043 -2978 1020 -421 11325 -13200 -188 -8645 1847 -4530 5578 1454 -994 -8632 6772 11620 9941 1830 3420 409 -3477 8748 1084 4498 -6342 5483 -2310 5726 -14975 -1999 -3851 4235 -545 5753 2955 -2580 -3236 2692 2228 787 -7884 -12860 7344 -4349 9962 -6116 2746 -2191 -5195 1504 9634 -11637 5888 -308 6924 3838 11848 2567 -1166 8944 -3214 10376 -2948 -5806 -5617 -671 -422 -1807 -7459 5558 -6956 3175 -1761 8905 6663 5052 7920 3906 -1104 1665 2802 -9072 2509 -8435 2313 -8253 2160 -7046 4253 2680 5521 -9212 2308 12736 11733 -4294 -4197 9153 -12983 -1574 -3490 8014 -5181 4885 2446 1575 -8189 6740 -4557 -262 -4493 4494 41452 9609 -4391 -6439 -811 1620 -6702 6738 8589 2298 6082 2139 445 3506 2748 9707 8828 6151 5171 -5369 -5905 -7682 -2726 -11437 800 -18237 9696 -5389 16788 -7106 9702 -1126 4097 1035 4816 6561 -7871 5274 -8381 5253 -3321 1080 -448 10804 -16081 -204 -10307 2012 -5256 5824 1556 -1071 -9773 6397 10216 8764 1752 3327 423 -3812 8569 1141 4559 -7124 5534 -2516 5764 -18220 -2110 -4058 4065 -542 5298 2757 -2540 -3228 2568 2161 768 -8172 -13710 6390 -4221 8416 -6092 2516 -2109 -5195 1417 8392 -12426 5299 -295 6213 3588 10475 2512 -1181 8136 -3260 9031 -2844 -5602 -5313 -608 -388 -1740 -7723 5015 -6951 2828 -1626 7479 5822 4566 7108 3706 -1110 1635 2730 -9884 2419 -8874 2163 -8460 1990 -7153 3904 2496 5005 -9611 2144 10741 9985 -4198 -4019 7584 -13164 -1434 -3311 6951 -5165 4462 2299 1490 -8531 6116 -4623 -255 -4476 3991 25055 7787 -4104 SO 20190210T123410.0Z 6980.523727 476 1 32.01 2 89.10 110.99 117.63 53.31 0.00 1 0.00 1 0 15 3.182e-02 3.135e-02 3.053e-02 3.023e-02 4.588523e+03 1.870039e+03 1.402092e+02 -6.000000e+00 1.655159e+03 271.77 -2.00 20.00 -2.00 505.24 0.00e+00 3.127578e-03 7.991345e-04 1.643101e-04 -6.000000e+00 8.610871e-04 271.77 -2.00 20.00 -2.00 500.11 0.00e+00 1.198496e+00 6.062820e-01 7.671342e-02 -6.000000e+00 6.242509e-01 224.44 -2.00 3.57 -2.00 501.74 0.00e+00 19.112 0.136 489.00 513.00 1 9.3032e+00 4.6200e-02 3.3476e-02 -6.0000e+00 4.7628e-02 1.4022e-01 1.2010e-02 2.2146e-03 -6.0000e+00 1.2469e-02 1.0908e-05 -1.9850e-03 2.5471e-03 4.7622e-05 -6.0000e+00 2.8143e-03 8.5012e-03 1.0510e-04 12 8 8 10 0 0 -1.85 21.88 1.85 0.00850 -0.00527 8 2 1 4 0 4000.000 21.88 15.01 18.78 -760 902 -4866 -2252 -2629 1984 1363 751 1545 -1394 3770 1534 5520 -2019 -1239 46 2433 -1938 -737 -3225 -1542 -217 4749 -3653 2159 -847 2455 464 -2752 -4339 -1322 1064 6543 960 -2696 1284 2171 -115 -3697 4919 2859 2957 -2063 2980 -2781 -1688 -3368 -1584 -1207 5608 264 3690 2449 677 -751 -1258 2581 -3924 2248 -5100 -3256 -738 2963 -422 3734 651 6814 -1058 1843 -2527 751 3326 28 206 -3305 2130 1086 -1902 -231 1044 -7474 826 -1756 230 -975 4853 -1125 1835 -5048 8099 2260 -1857 -1491 1129 -485 -6695 1292 777 -2001 131 324 -1256 2846 769 -1127 6051 794 -8068 -487 -2642 1756 -268 3073 2605 545 474 1581 2984 -321 51 57 1137 558 323 -384 -765 4231 4986 -2698 2419 1103 -9115 2731 1109 -1524 260 9567 -7505 3317 491 -847 -3090 450 -6774 3742 -2813 -1341 1805 9065 656 -3169 -729 863 -5065 -2374 -2856 2095 1480 829 1694 -1555 3915 1609 5488 -2125 -1282 47 2446 -2070 -803 -3652 -1713 -239 4971 -4148 2338 -946 2642 506 -3046 -4696 -1344 1056 6212 994 -3008 1397 2321 -124 -4094 4954 2930 3044 -2253 3132 -3131 -1893 -3828 -1750 -1308 5584 269 3527 2326 650 -745 -1300 2638 -4336 2341 -5685 -3549 -788 3073 -452 3829 678 6572 -1082 1810 -2562 725 3112 28 201 -3401 2086 1055 -1860 -219 972 -7514 771 -1691 218 -941 4474 -1102 1743 -5099 7177 2123 -1824 -1485 1112 -483 -6936 1212 715 -1841 115 278 -1093 2424 691 -1078 5479 752 -8217 -455 -2509 1619 -256 2884 2485 533 466 1544 2898 -323 50 55 1077 524 302 -366 -734 3864 4530 -2627 2234 1036 -9357 2448 994 -1389 232 7942 -7525 3034 467 -825 -3087 435 -7049 3527 -2821 -1315 1681 7662 589 -2947 SO 20190210T123805.0Z 6980.526447 480 1 32.01 2 88.44 111.67 117.07 54.16 0.00 1 0.00 1 0 15 1.943e-02 1.941e-02 1.659e-02 1.649e-02 2.384905e+03 9.635648e+02 1.383072e+02 -6.000000e+00 1.011151e+03 271.77 -2.00 20.00 -2.00 505.27 0.00e+00 4.107185e-03 4.367204e-04 1.948137e-04 -6.000000e+00 5.259448e-04 271.77 -2.00 20.00 -2.00 500.26 0.00e+00 1.631455e+00 3.283600e-01 3.961797e-02 -6.000000e+00 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