File name: Pandora104s1_Downsview_20190212_L2Fit_fwvt1c21d20180627p1-8.txt File generation date: 20241127T000155.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c21p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 104 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora104_OF_v5d20171009.txt Instrument calibration file used: Pandora104s1_CF_v21d20180627.txt Level 1 file used: Pandora104s1_Downsview_20190212_L1_smca1c21d20180627p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20190212 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 12 to revisit NO2 and SO2 First and last pixel inside fitting window: 1633 1783 Nominal wavelengths inside fitting window [nm]: 492.0163 492.1368 492.2573 492.3778 492.4983 492.6187 492.7391 492.8596 492.9800 493.1003 493.2207 493.3411 493.4614 493.5817 493.7020 493.8223 493.9425 494.0628 494.1830 494.3032 494.4234 494.5436 494.6637 494.7839 494.9040 495.0241 495.1442 495.2643 495.3843 495.5044 495.6244 495.7444 495.8644 495.9844 496.1043 496.2242 496.3442 496.4641 496.5840 496.7038 496.8237 496.9435 497.0633 497.1831 497.3029 497.4227 497.5424 497.6621 497.7818 497.9015 498.0212 498.1409 498.2605 498.3801 498.4997 498.6193 498.7389 498.8585 498.9780 499.0975 499.2170 499.3365 499.4560 499.5754 499.6949 499.8143 499.9337 500.0531 500.1724 500.2918 500.4111 500.5304 500.6497 500.7690 500.8882 501.0075 501.1267 501.2459 501.3651 501.4843 501.6034 501.7226 501.8417 501.9608 502.0799 502.1989 502.3180 502.4370 502.5560 502.6750 502.7940 502.9130 503.0319 503.1509 503.2698 503.3887 503.5075 503.6264 503.7452 503.8641 503.9829 504.1017 504.2204 504.3392 504.4579 504.5766 504.6953 504.8140 504.9327 505.0513 505.1700 505.2886 505.4072 505.5258 505.6443 505.7629 505.8814 505.9999 506.1184 506.2368 506.3553 506.4737 506.5922 506.7106 506.8289 506.9473 507.0657 507.1840 507.3023 507.4206 507.5389 507.6571 507.7754 507.8936 508.0118 508.1300 508.2482 508.3663 508.4845 508.6026 508.7207 508.8388 508.9569 509.0749 509.1929 509.3109 509.4289 509.5469 509.6649 509.7828 509.9007 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190212T122725.0Z 6982.519039 468 1 32.01 2 89.77 109.36 120.85 25.27 0.00 1 0.00 1 0 49 6.769e-01 3.922e-01 5.990e-01 4.195e-01 3.597320e+04 4.139004e+04 3.154890e+03 -6.000000e+00 3.802833e+04 271.77 -2.00 20.00 -2.00 505.20 0.00e+00 -4.775490e-03 1.146843e-02 3.482180e-04 -6.000000e+00 1.930078e-02 271.77 -2.00 20.00 -2.00 499.63 0.00e+00 -5.511381e+00 9.359693e+00 6.780711e-02 -6.000000e+00 1.433270e+01 224.52 -2.00 3.57 -2.00 501.26 0.00e+00 20.431 0.166 489.00 513.00 1 1.2324e+01 6.9620e-01 3.7875e-02 -6.0000e+00 1.0946e+00 2.6973e-01 1.8081e-01 2.9065e-03 -6.0000e+00 2.8364e-01 5.7777e-07 6.4958e-03 2.7830e-02 3.4600e-04 -6.0000e+00 6.2664e-02 -3.4053e-02 1.9363e-03 12 8 8 10 0 0 94.02 21.69 25.99 -0.03405 0.01101 8 2 1 4 0 4000.000 21.69 15.00 18.72 30858 31823 -25574 25509 -40687 92617 7791 91260 344 13126 -13551 20435 63369 41018 60736 100396 22520 -18960 33530 27905 -3441 32889 -10979 27439 164403 -8951 99598 -19202 900000 40989 39631 13136 -2993 -37703 43066 -13862 27245 3845 -16433 25031 -36575 125990 7366 25885 -19868 -5826 -7664 99902 -23010 900000 15504 81940 -7939 44434 -22689 21577 91525 108281 -11831 143780 -38349 -15131 -3774 389 5985 34395 22890 62005 900000 35203 134035 15790 148693 44620 900000 30879 59153 79165 9083 2390 8861 148684 44683 29916 -55794 39217 -45226 114477 -715 58669 -19408 199374 -12292 5847 -8364 116634 32748 175635 15309 900000 73887 16185 -44353 -10056 27394 21046 900000 14728 900000 3477 900000 13469 544 -24337 900000 44915 29620 40214 168799 86851 1773 56231 -9966 42269 115472 97068 -9874 19784 -49720 163745 -15840 67762 -64098 168613 14250 71694 4212 38214 158160 19984 175593 -8770 79342 -18065 118381 4647 106198 4999 900000 900000 900000 26902 28409 -39560 24978 -75280 50386 9256 49664 426 14291 -18586 20204 41889 33348 41774 49222 23238 -29012 31513 27640 -4539 30972 -15567 27080 67455 -12157 48814 -26981 900000 32549 32296 14198 -3869 -67592 36086 -19452 25759 4459 -22904 23801 -61894 51694 8405 24868 -28959 -7345 -9665 45878 -31681 900000 14337 41285 -9402 33513 -32514 20689 46093 46587 -15317 58993 -64250 -20434 -4561 446 6402 27971 20560 38500 900000 27761 54995 15286 61010 33484 900000 25168 36733 40639 8827 2489 8778 61006 33036 25741 -106437 30852 -76699 46970 -793 37890 -25852 81804 -14188 5351 -8207 47856 20891 72064 11311 900000 34674 13995 -72484 -12456 24294 19583 900000 14261 900000 3776 900000 12883 578 -32278 900000 33028 25483 31099 69259 40902 1760 33520 -10998 28823 47379 40040 -10728 16276 -77573 67185 -17184 34265 -109902 69183 12340 36941 4053 27444 64894 17457 72047 -9989 39812 -21966 48572 4473 43574 4689 900000 900000 900000 SO 20190212T123131.0Z 6982.521887 472 1 32.01 2 89.08 110.07 120.53 26.32 0.00 1 0.00 1 0 43 2.994e-01 2.117e-01 2.662e-01 2.238e-01 4.678727e+04 2.068406e+04 1.368105e+03 -6.000000e+00 1.560358e+04 271.77 -2.00 20.00 -2.00 505.20 0.00e+00 -5.878407e-03 5.999811e-03 2.336678e-04 -6.000000e+00 8.115174e-03 271.77 -2.00 20.00 -2.00 499.69 0.00e+00 -6.542619e+00 4.720750e+00 3.645876e-01 -6.000000e+00 5.902634e+00 224.52 -2.00 3.57 -2.00 501.40 0.00e+00 19.058 0.135 489.00 513.00 1 1.1992e+01 3.5615e-01 4.3683e-02 -6.0000e+00 4.4998e-01 2.7938e-01 9.3677e-02 7.1254e-03 -6.0000e+00 1.1850e-01 1.3155e-06 -5.0692e-02 1.3373e-02 3.9281e-05 -6.0000e+00 2.6412e-02 -1.8084e-01 1.9039e-03 12 8 8 10 0 0 73.26 21.79 21.47 -0.18084 -0.53246 8 2 1 4 0 4000.000 21.79 15.00 18.74 2170 -7208 34351 16632 32880 2430 26558 -9477 -14944 -23656 16693 -33042 -14882 6421 29527 -24177 20474 15315 4356 17906 1922 11576 -14685 805 -2100 3984 -15324 31294 -22901 42411 12772 51274 -13126 3667 8157 28162 -17897 2764 16558 56778 34490 6049 46788 -18780 -13619 14809 70358 15361 582 -754 31518 28849 -29330 10532 76190 -6986 8623 23029 58445 22845 -23460 298 27492 28975 -31336 19635 2634 20398 -12060 1122 4303 39027 -13605 -12073 -12883 -7290 46718 88108 16226 -17878 49902 -18261 38802 5416 14074 21327 36116 862 1199 -10087 7201 -9467 -7094 -21076 2276 19527 30479 2424 38419 -778 -16645 -2898 43274 50287 -20910 56387 6422 8860 -18753 31461 29306 -2025 -16372 -287 6851 -3387 24204 5720 -10829 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9084 -8748 10724 10996 -713 2143 -12943 -21953 25692 10451 -3152 -19455 12785 -19539 38285 -13168 900000 SO 20190212T123533.0Z 6982.524688 476 1 32.01 2 88.39 110.77 120.21 27.35 0.00 1 0.00 1 0 55 1.412e-01 1.266e-01 1.271e-01 1.212e-01 2.821347e+04 9.781803e+03 2.070752e+03 -6.000000e+00 7.348119e+03 271.77 -2.00 20.00 -2.00 505.22 0.00e+00 2.136113e-03 3.226781e-03 1.761481e-04 -6.000000e+00 3.826535e-03 271.77 -2.00 20.00 -2.00 499.94 0.00e+00 -4.304716e+00 2.532403e+00 1.098760e-01 -6.000000e+00 2.788418e+00 224.52 -2.00 3.57 -2.00 501.58 0.00e+00 17.270 0.100 489.00 513.00 1 1.1371e+01 1.9248e-01 2.9913e-02 -6.0000e+00 2.1243e-01 2.2427e-01 4.9989e-02 3.8026e-03 -6.0000e+00 5.6205e-02 2.5515e-06 -6.5658e-03 8.5246e-03 1.6702e-04 -6.0000e+00 1.2500e-02 3.2041e-02 -3.5260e-04 12 8 8 10 0 0 44.12 21.79 2.86 0.03204 -0.01350 8 2 1 4 0 4000.000 21.79 15.00 18.75 900000 24956 -12646 5500 498 5779 -9676 3624 -2017 8062 1776 6916 -3588 -12419 -6026 -2037 29531 -7827 7075 -8422 13265 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