File name: Pandora104s1_Downsview_20190312_L2Fit_fwvt1c21d20180627p1-8.txt File generation date: 20241127T001718.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c21p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 104 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora104_OF_v5d20171009.txt Instrument calibration file used: Pandora104s1_CF_v21d20180627.txt Level 1 file used: Pandora104s1_Downsview_20190312_L1_smca1c21d20180627p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20190312 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 12 to revisit NO2 and SO2 First and last pixel inside fitting window: 1633 1783 Nominal wavelengths inside fitting window [nm]: 492.0163 492.1368 492.2573 492.3778 492.4983 492.6187 492.7391 492.8596 492.9800 493.1003 493.2207 493.3411 493.4614 493.5817 493.7020 493.8223 493.9425 494.0628 494.1830 494.3032 494.4234 494.5436 494.6637 494.7839 494.9040 495.0241 495.1442 495.2643 495.3843 495.5044 495.6244 495.7444 495.8644 495.9844 496.1043 496.2242 496.3442 496.4641 496.5840 496.7038 496.8237 496.9435 497.0633 497.1831 497.3029 497.4227 497.5424 497.6621 497.7818 497.9015 498.0212 498.1409 498.2605 498.3801 498.4997 498.6193 498.7389 498.8585 498.9780 499.0975 499.2170 499.3365 499.4560 499.5754 499.6949 499.8143 499.9337 500.0531 500.1724 500.2918 500.4111 500.5304 500.6497 500.7690 500.8882 501.0075 501.1267 501.2459 501.3651 501.4843 501.6034 501.7226 501.8417 501.9608 502.0799 502.1989 502.3180 502.4370 502.5560 502.6750 502.7940 502.9130 503.0319 503.1509 503.2698 503.3887 503.5075 503.6264 503.7452 503.8641 503.9829 504.1017 504.2204 504.3392 504.4579 504.5766 504.6953 504.8140 504.9327 505.0513 505.1700 505.2886 505.4072 505.5258 505.6443 505.7629 505.8814 505.9999 506.1184 506.2368 506.3553 506.4737 506.5922 506.7106 506.8289 506.9473 507.0657 507.1840 507.3023 507.4206 507.5389 507.6571 507.7754 507.8936 508.0118 508.1300 508.2482 508.3663 508.4845 508.6026 508.7207 508.8388 508.9569 509.0749 509.1929 509.3109 509.4289 509.5469 509.6649 509.7828 509.9007 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190312T114148.0Z 7010.487361 424 1 32.01 2 89.77 94.84 115.83 31.36 0.00 1 0.00 1 0 22 8.315e-02 7.982e-02 6.588e-02 6.457e-02 -3.966084e+03 3.549715e+03 2.255613e+02 -6.000000e+00 4.360436e+03 273.66 -2.00 20.00 -2.00 505.20 0.00e+00 3.489535e-03 1.725935e-03 2.025967e-04 -6.000000e+00 2.260895e-03 273.66 -2.00 20.00 -2.00 500.05 0.00e+00 2.769703e+00 1.295068e+00 4.481318e-02 -6.000000e+00 1.632983e+00 225.63 -2.00 3.57 -2.00 501.69 0.00e+00 20.374 0.165 489.00 513.00 1 9.7852e+00 9.9299e-02 3.7081e-02 -6.0000e+00 1.2464e-01 1.3813e-01 2.5815e-02 2.1591e-03 -6.0000e+00 3.2644e-02 5.0284e-06 8.4061e-03 5.5421e-03 6.2353e-05 -6.0000e+00 7.3458e-03 -2.1268e-02 2.3519e-04 12 8 8 10 0 0 89.70 21.79 6.98 -0.02127 0.03704 8 2 1 4 0 4000.000 21.79 15.00 18.76 2917 -15434 14890 -2216 11827 -1904 -1029 13331 -430 14611 2549 4195 -3877 5713 -2882 9478 -3409 5693 -3394 5222 -6439 16292 -5182 4714 -517 968 -6381 4525 -7216 -9545 2814 -2634 5210 -5480 -59 -11776 3028 3317 7564 -4237 7458 -11143 3488 -1714 10200 -2770 -5619 -12828 3899 11946 -4067 3637 17352 -3845 -8737 1514 -8777 11246 -7710 6941 11013 18460 -10619 5989 2960 8621 -3182 1419 -5454 3665 -2385 -2728 9795 -877 6625 -4275 6914 -10658 -7923 2861 -5287 -15506 478 -4023 56 -3952 19768 -1590 -5600 12998 -8915 -2897 6864 5779 -9071 8057 -8139 10451 1389 20576 -14323 6411 -876 -476 -3439 7039 1268 4648 6312 -8903 19439 390 10722 -9891 3968 -6300 19257 -6984 10370 -7359 -4580 -12179 5200 -7358 -291 -401 -4450 10564 7761 6408 2873 659 -7852 15798 -10884 9248 -1038 13026 -6710 2542 -543 14012 6799 3754 -11015 3468 -3336 3701 -8912 7352 8826 2739 -17665 13190 -2396 11383 -2133 -1164 13171 -484 13938 2687 4304 -4224 5610 -3051 8942 -3692 5792 -3873 5502 -7572 15408 -6025 5006 -581 1070 -7535 4764 -8284 -10744 2769 -2746 5123 -6236 -65 -14630 3216 3482 7522 -4687 7387 -13315 3660 -1912 10255 -3162 -6539 -15768 4009 11097 -4268 3455 14256 -3892 -9567 1549 -10133 10763 -8840 6877 10469 16455 -12536 6019 3031 8217 -3333 1400 -5693 3446 -2344 -2692 8622 -867 6166 -4378 6215 -11128 -7994 2593 -5180 -16934 449 -3945 53 -3930 15638 -1543 -5639 10983 -9336 -2898 6384 5498 -9952 7426 -8704 9140 1291 15476 -14808 5456 -814 -455 -3435 6274 1172 4089 5403 -8894 15055 370 9397 -10759 3811 -6708 16067 -7478 9290 -7678 -4589 -13006 4669 -7525 -280 -386 -4459 9147 6866 5770 2674 616 -7823 12331 -10856 7622 -967 10813 -6819 2385 -527 11807 6154 3521 -11946 3264 -3300 3324 -8779 6114 7294 SO 20190312T114547.0Z 7010.490127 428 1 32.01 2 89.05 95.53 115.46 32.30 0.00 1 0.00 1 0 22 3.900e-02 3.810e-02 4.074e-02 4.026e-02 4.217077e+03 2.510761e+03 1.646870e+02 -6.000000e+00 2.044645e+03 273.66 -2.00 20.00 -2.00 505.23 0.00e+00 2.250678e-03 1.070528e-03 1.502836e-04 -6.000000e+00 1.060083e-03 273.66 -2.00 20.00 -2.00 500.01 0.00e+00 2.013771e+00 8.103841e-01 6.554427e-02 -6.000000e+00 7.653336e-01 225.63 -2.00 3.57 -2.00 501.65 0.00e+00 18.953 0.133 489.00 513.00 1 9.5558e+00 6.2011e-02 3.2910e-02 -6.0000e+00 5.8425e-02 1.3193e-01 1.5933e-02 2.1086e-03 -6.0000e+00 1.5287e-02 8.2169e-06 4.9946e-03 3.3748e-03 4.2000e-05 -6.0000e+00 3.4494e-03 2.0589e-03 1.6861e-04 12 8 8 10 0 0 -224.18 21.79 4.88 0.00206 0.03670 8 2 1 4 0 4000.000 21.79 15.00 18.78 -1165 -2024 -2079 -5646 6717 -1882 4827 1522 3589 -3720 1550 -3565 -1179 -2136 6518 -4508 1273 2595 2942 -3287 -1603 3188 -2445 2232 -1765 -4349 -3360 2919 -6560 7631 942 -74 -371 -3136 -5011 -1652 4666 3610 88 569 3724 672 1323 -623 4711 1921 8089 6257 7846 -1391 -1401 -488 3269 1045 -3513 -112 -709 -2433 -2657 316 -3479 64 154 2039 2382 3839 -2608 71 798 4381 2494 -5585 270 276 -3585 -970 -3952 -8839 407 -286 -4121 1709 6067 5420 -104 -6128 2219 -289 -236 -2565 4988 -523 -7511 470 -1533 278 3934 -4486 4353 -3113 -2327 -7605 8973 738 1973 -2571 3852 3511 -4550 3182 5244 -1257 1838 5145 3910 -3444 2187 1374 -1567 4769 -3146 686 -2344 3359 10281 -3757 -1167 6250 7608 224 2142 -1238 -2982 -6396 -3643 -1157 -4623 -4751 921 6483 -3724 3951 943 9750 3593 2124 -5381 -1247 -7140 -571 -3014 -1136 -2030 -2160 -6289 6775 -2102 5154 1685 3892 -4250 1655 -3957 -1257 -2270 6325 -4880 1321 2726 3169 -3782 -1809 3443 -2785 2440 -2020 -5088 -3870 3137 -7541 7331 949 -76 -386 -3494 -5857 -1872 4910 3801 94 604 3836 718 1419 -689 4994 2096 8257 6407 7778 -1473 -1436 -483 3074 1006 -3643 -116 -755 -2656 -2899 333 -3798 68 164 2129 2456 3837 -2722 71 785 4102 2344 -5675 261 270 -3694 -968 -3966 -9103 379 -267 -3983 1575 5381 4851 -99 -6251 2087 -278 -226 -2506 4540 -506 -7929 462 -1517 265 3529 -4247 3697 -2774 -2023 -7019 7235 672 1837 -2508 3495 3149 -4358 2841 4666 -1208 1736 4751 3670 -3477 2105 1342 -1571 4429 -3100 641 -2224 3029 8756 -3667 -1110 5537 6607 209 1967 -1154 -2771 -6078 -3346 -1043 -4412 -4632 859 5807 -3714 3667 904 8620 3375 2019 -5426 -1179 -6960 -516 -2805 SO 20190312T114941.0Z 7010.492836 432 1 32.01 2 88.35 96.20 115.08 33.20 0.00 1 0.00 1 0 15 2.381e-02 2.355e-02 2.430e-02 2.405e-02 2.770399e+03 1.450482e+03 1.633435e+02 -6.000000e+00 1.248032e+03 273.66 -2.00 20.00 -2.00 505.23 0.00e+00 3.236794e-03 6.405894e-04 1.624746e-04 -6.000000e+00 6.472219e-04 273.66 -2.00 20.00 -2.00 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