File name: Pandora104s1_Downsview_20190623_L2Fit_fout2c21d20180627p1-8.txt
File generation date: 20241127T011347.2Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c21p1-8
Local principal investigator: Vitoli Fiolitov
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 104
Spectrometer number: 1
Processing software version used: BlickP v1.8.60
Instrument operation file used: Pandora104_OF_v5d20171009.txt
Instrument calibration file used: Pandora104s1_CF_v21d20180627.txt
Level 1 file used: Pandora104s1_Downsview_20190623_L1_smca1c21d20180627p1-8.txt
Full location name: Environment Canada HQ - Downsview
Short location name: Downsview
Country of location: Canada
Location latitude [deg]: 43.7810
Location longitude [deg]: -79.4680
Location altitude [m]: 187
Local noon date: 20190623
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: Based on session 12 to revisit NO2 and SO2
First and last pixel inside fitting window: 209 351
Nominal wavelengths inside fitting window [nm]: 305.1061 305.2467 305.3872 305.5277 305.6683 305.8088 305.9493 306.0898 306.2302 306.3707 306.5112 306.6516 306.7920 306.9325 307.0729 307.2133 307.3537 307.4940 307.6344 307.7748 307.9151 308.0554 308.1958 308.3361 308.4764 308.6167 308.7569 308.8972 309.0375 309.1777 309.3179 309.4582 309.5984 309.7386 309.8788 310.0189 310.1591 310.2993 310.4394 310.5795 310.7196 310.8598 310.9999 311.1399 311.2800 311.4201 311.5601 311.7002 311.8402 311.9802 312.1202 312.2602 312.4002 312.5402 312.6801 312.8201 312.9600 313.1000 313.2399 313.3798 313.5197 313.6595 313.7994 313.9393 314.0791 314.2190 314.3588 314.4986 314.6384 314.7782 314.9180 315.0577 315.1975 315.3372 315.4770 315.6167 315.7564 315.8961 316.0358 316.1755 316.3151 316.4548 316.5944 316.7341 316.8737 317.0133 317.1529 317.2925 317.4321 317.5716 317.7112 317.8507 317.9902 318.1298 318.2693 318.4088 318.5482 318.6877 318.8272 318.9666 319.1061 319.2455 319.3849 319.5243 319.6637 319.8031 319.9424 320.0818 320.2211 320.3605 320.4998 320.6391 320.7784 320.9177 321.0569 321.1962 321.3355 321.4747 321.6139 321.7531 321.8924 322.0315 322.1707 322.3099 322.4491 322.5882 322.7273 322.8665 323.0056 323.1447 323.2838 323.4228 323.5619 323.7010 323.8400 323.9790 324.1181 324.2571 324.3961 324.5350 324.6740 324.8130 324.9519
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Temperature at electronics board [°C], 999=no temperature signal
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SU 20190623T122047.6Z 7113.514440 244 1 33.24 2 63.35 82.23 63.58 216.91 0.00 1 0.00 1 0 17 1.371e-02 6.248e-03 1.236e-03 2.436e-04 3.068116e-01 1.272033e-04 3.660279e-03 -6.000000e+00 8.143305e-03 232.93 -2.00 3.57 -2.00 318.30 0.00e+00 1.125383e-03 2.402422e-05 3.752489e-04 -6.000000e+00 3.588736e-04 284.79 -2.00 20.00 -2.00 317.50 0.00e+00 2.217 0.000 302.00 328.00 3 4.0799e-01 3.4649e-04 2.7352e-02 -6.0000e+00 2.0474e-02 2.0066e-02 3.9288e-04 1.6412e-02 -6.0000e+00 2.2154e-02 -7.3996e-03 2.5033e-04 7.9938e-03 -6.0000e+00 1.3153e-02 -5.6755e-03 1.2598e-04 2.2854e-03 -6.0000e+00 5.4753e-03 2.7360e-02 -6.7146e-05 7.2633e-06 2.3460e-05 -6.0000e+00 3.8034e-04 1.7684e-02 0.0000e+00 10 0 0 10 0 0 11.35 22.09 0.30 0.01768 0.01718 1755 359 1 5 0 18.860 22.09 15.00 19.21 -371 -1308 -1599 -4372 -3549 -3437 -2050 -2075 -3243 -4940 -5802 -2946 -1898 -606 -468 -285 -162 1016 887 1645 1052 1139 1039 384 -332 -1097 -1772 -1854 -1059 -488 701 -636 -108 -3293 -4032 -2887 -1975 -935 -774 -1066 -1331 -888 -478 -59 319 320 -178 232 -138 823 1220 1254 1017 1317 627 963 596 164 364 957 1657 1839 1525 1375 18 -52 430 290 1808 801 201 -99 -307 69 -180 -376 -627 -977 -649 -1120 -1811 -1818 -2308 -1413 -518 -175 284 1 278 271 481 534 82 717 626 314 -128 48 -439 -1007 -517 -678 174 164 -742 -1441 -471 -607 607 447 652 -29 380 255 450 691 1044 469 290 -253 -310 -165 198 122 490 599 -20 815 48 -306 -495 -651 -250 167 268 52 202 145 5 -308 110 -336 -264 -22 -84 -104 -266 -216 -208 -134 -155 -243 -386 -499 -269 -181 -66 -58 -39 -23 150 136 262 170 182 172 68 -63 -214 -340 -370 -202 -94 146 -146 -24 -769 -976 -708 -490 -274 -270 -424 -570 -395 -218 -27 146 147 -80 103 -61 370 587 650 557 757 370 584 368 101 219 577 1035 1246 1118 1070 14 -37 291 196 1331 616 166 -84 -258 55 -146 -274 -424 -647 -464 -915 -1523 -1682 -2278 -1450 -567 -204 346 1 342 319 524 533 76 663 627 349 -157 60 -579 -1305 -673 -810 199 198 -978 -1840 -627 -842 884 697 1067 -48 603 377 617 900 1370 647 429 -398 -492 -256 298 176 674 856 -27 1126 67 -459 -781 -1053 -414 288 455 92 368 268 8 -562 193 -611 -473
SU 20190623T122537.6Z 7113.517797 247 1 33.25 2 62.49 83.01 64.08 218.07 0.00 1 0.00 1 0 17 1.255e-02 6.320e-03 1.076e-03 2.311e-04 2.977249e-01 1.202694e-04 3.540454e-03 -6.000000e+00 7.455168e-03 232.93 -2.00 3.57 -2.00 318.17 0.00e+00 1.044978e-03 2.193668e-05 3.607172e-04 -6.000000e+00 3.285451e-04 284.79 -2.00 20.00 -2.00 317.37 0.00e+00 2.153 0.000 302.00 328.00 3 3.9232e-01 3.2668e-04 2.6529e-02 -6.0000e+00 1.8744e-02 1.8566e-02 3.6995e-04 1.5880e-02 -6.0000e+00 2.0282e-02 -7.4570e-03 2.3239e-04 7.7144e-03 -6.0000e+00 1.2041e-02 -4.9298e-03 1.1626e-04 2.1834e-03 -6.0000e+00 5.0126e-03 2.9969e-02 -5.0983e-05 6.8864e-06 2.2129e-05 -6.0000e+00 3.4820e-04 1.7629e-02 0.0000e+00 10 0 0 10 0 0 11.04 22.09 0.30 0.01763 0.01725 1851 379 1 5 0 17.890 22.09 15.00 19.21 -821 -1391 -1649 -3815 -3566 -3131 -1738 -1577 -2355 -4248 -4809 -2232 -1465 -681 43 -231 136 1162 1081 1680 1125 1048 902 472 -305 -1039 -1722 -1654 -833 -221 825 -191 10 -2963 -4009 -2550 -1915 -780 -766 -931 -1366 -980 -565 -153 262 177 -189 120 -113 809 1370 1247 1017 1323 645 969 593 128 440 997 1632 1852 1435 1264 -30 -84 434 291 1795 766 157 -75 -306 93 -194 -312 -603 -959 -665 -1119 -1839 -1783 -2389 -1379 -520 -126 285 -20 318 267 543 489 123 738 601 342 -132 21 -453 -1045 -522 -726 138 148 -714 -1453 -470 -628 581 466 641 -47 346 254 451 681 1049 493 287 -204 -332 -138 196 108 468 616 -18 798 34 -318 -519 -670 -244 116 282 38 211 149 -1 -310 102 -325 -251 -55 -98 -117 -252 -237 -206 -124 -128 -209 -394 -444 -218 -164 -80 6 -33 20 182 176 284 193 178 159 89 -61 -215 -349 -348 -167 -45 180 -46 2 -792 -1012 -650 -544 -238 -278 -384 -608 -453 -268 -72 124 84 -88 55 -52 375 677 664 571 780 390 602 375 80 271 616 1044 1283 1077 1005 -24 -61 298 200 1340 598 131 -65 -261 76 -160 -231 -413 -643 -480 -923 -1561 -1662 -2377 -1424 -573 -147 350 -24 394 317 596 492 115 685 603 382 -163 26 -599 -1354 -679 -868 158 178 -941 -1859 -626 -873 845 726 1046 -72 547 374 614 955 1482 675 421 -318 -526 -214 293 156 642 876 -25 1096 47 -473 -812 -1073 -399 198 474 68 379 274 -1 -559 176 -586 -446
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