File name: Pandora104s1_Downsview_20190727_L2Fit_fwvt1c21d20180627p1-8.txt File generation date: 20241127T014826.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c21p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 104 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora104_OF_v5d20171009.txt Instrument calibration file used: Pandora104s1_CF_v21d20180627.txt Level 1 file used: Pandora104s1_Downsview_20190727_L1_smca1c21d20180627p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20190727 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 12 to revisit NO2 and SO2 First and last pixel inside fitting window: 1633 1783 Nominal wavelengths inside fitting window [nm]: 492.0163 492.1368 492.2573 492.3778 492.4983 492.6187 492.7391 492.8596 492.9800 493.1003 493.2207 493.3411 493.4614 493.5817 493.7020 493.8223 493.9425 494.0628 494.1830 494.3032 494.4234 494.5436 494.6637 494.7839 494.9040 495.0241 495.1442 495.2643 495.3843 495.5044 495.6244 495.7444 495.8644 495.9844 496.1043 496.2242 496.3442 496.4641 496.5840 496.7038 496.8237 496.9435 497.0633 497.1831 497.3029 497.4227 497.5424 497.6621 497.7818 497.9015 498.0212 498.1409 498.2605 498.3801 498.4997 498.6193 498.7389 498.8585 498.9780 499.0975 499.2170 499.3365 499.4560 499.5754 499.6949 499.8143 499.9337 500.0531 500.1724 500.2918 500.4111 500.5304 500.6497 500.7690 500.8882 501.0075 501.1267 501.2459 501.3651 501.4843 501.6034 501.7226 501.8417 501.9608 502.0799 502.1989 502.3180 502.4370 502.5560 502.6750 502.7940 502.9130 503.0319 503.1509 503.2698 503.3887 503.5075 503.6264 503.7452 503.8641 503.9829 504.1017 504.2204 504.3392 504.4579 504.5766 504.6953 504.8140 504.9327 505.0513 505.1700 505.2886 505.4072 505.5258 505.6443 505.7629 505.8814 505.9999 506.1184 506.2368 506.3553 506.4737 506.5922 506.7106 506.8289 506.9473 507.0657 507.1840 507.3023 507.4206 507.5389 507.6571 507.7754 507.8936 508.0118 508.1300 508.2482 508.3663 508.4845 508.6026 508.7207 508.8388 508.9569 509.0749 509.1929 509.3109 509.4289 509.5469 509.6649 509.7828 509.9007 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190727T100742.0Z 7147.422014 230 1 32.01 2 89.79 63.10 46.08 112.41 0.00 1 0.00 1 0 22 8.316e-02 1.193e-01 3.835e-02 3.771e-02 2.689000e+04 2.990744e+03 1.818405e+03 -6.000000e+00 4.595456e+03 287.07 -2.00 20.00 -2.00 505.30 0.00e+00 7.324894e-03 1.055067e-03 2.146405e-04 -6.000000e+00 2.339110e-03 287.07 -2.00 20.00 -2.00 500.33 0.00e+00 -2.261544e+00 7.688493e-01 1.554068e-01 -6.000000e+00 1.647794e+00 232.62 -2.00 3.57 -2.00 501.92 0.00e+00 20.007 0.156 489.00 513.00 1 9.4818e+00 5.8969e-02 3.8399e-02 -6.0000e+00 1.2603e-01 1.6053e-01 1.5192e-02 4.3927e-03 -6.0000e+00 3.3387e-02 9.1749e-06 -1.3868e-02 2.7603e-03 1.5350e-04 -6.0000e+00 7.3477e-03 1.0891e-01 -1.0089e-03 12 8 8 10 0 0 99.72 22.19 6.96 0.10891 0.01272 8 2 1 4 0 4000.000 22.19 15.00 19.28 900000 7152 2937 -3437 -1429 -2476 -3574 2490 2126 4165 3089 3468 7968 3306 1801 -2306 -3784 1082 -4113 -4341 146 2950 700 -5166 -3199 -851 7431 3854 -76 3368 3167 -2955 -4030 -5895 -10138 -1776 -3675 -3531 -3352 544 -3695 514 -4699 5540 4726 1718 9234 897 137 12014 2366 6433 5751 5759 590 -802 -4012 3761 -1060 3890 6445 3731 6529 1418 5211 8260 13760 9705 9912 8189 12269 1037 2370 13282 745 269 5694 -64250 7085 5489 360 11456 6908 4292 -2305 8437 4227 3703 11853 13336 11722 -5622 6692 8427 2546 8737 2811 1112 -493 -866 -1000 -11177 -4857 -10827 -8692 -9633 3690 4673 8483 -7166 11819 2958 6606 677 8534 4652 563 4017 -2707 4872 5724 8019 4365 4763 -2709 3503 4438 2404 248 9182 -3741 8672 -338 7606 2353 -1857 -7410 -7463 1843 -4389 -5329 -8457 -3476 -3830 513 -4633 1354 1883 31427 -2764 630 900000 6198 2678 -3420 -1453 -2616 -3881 2603 2259 4336 3220 3517 7621 3259 1770 -2334 -3860 1060 -4299 -4670 153 3007 729 -5694 -3463 -908 7381 3952 -80 3412 3107 -2958 -4052 -6085 -11192 -1888 -4060 -3877 -3631 564 -3946 526 -5109 5531 4830 1839 9292 982 150 11566 2464 6287 5497 5401 578 -808 -4327 3882 -1171 4116 6655 3948 6748 1558 5526 8510 13305 9603 9611 7975 11402 1057 2364 11975 764 281 5701 -124536 6746 5206 355 10068 6317 4046 -2326 7731 4098 3624 10661 11690 10256 -5773 6128 7695 2497 7961 2596 994 -427 -728 -831 -10045 -4079 -9823 -8082 -9641 3409 4367 7660 -7462 10170 2804 6165 677 7917 4471 561 3882 -2848 4881 5730 7744 4258 4486 -2680 3271 4152 2300 243 8278 -3791 7796 -331 6700 2142 -1759 -7406 -7571 1749 -4460 -5503 -9149 -3626 -4035 520 -4913 1344 1844 22805 -2738 592 SO 20190727T101141.0Z 7147.424780 234 1 32.01 2 89.14 63.79 45.43 113.34 0.00 1 0.00 1 0 29 2.384e-02 2.349e-02 1.753e-02 1.744e-02 7.421165e+03 1.183501e+03 4.811340e+02 -6.000000e+00 1.318549e+03 287.07 -2.00 20.00 -2.00 505.35 0.00e+00 3.345929e-03 4.813958e-04 1.606671e-04 -6.000000e+00 6.698865e-04 287.07 -2.00 20.00 -2.00 500.42 0.00e+00 2.345191e+00 3.447577e-01 5.904231e-02 -6.000000e+00 4.692865e-01 232.62 -2.00 3.57 -2.00 502.02 0.00e+00 18.847 0.130 489.00 513.00 1 8.5985e+00 2.6430e-02 3.2757e-02 -6.0000e+00 3.5962e-02 6.6414e-02 6.7165e-03 2.1731e-03 -6.0000e+00 9.4087e-03 2.0536e-05 4.5838e-03 1.4844e-03 6.2982e-05 -6.0000e+00 2.1042e-03 -2.2683e-02 1.8398e-04 12 8 8 10 0 0 -89.24 22.19 4.10 -0.02268 0.00911 8 2 1 4 0 4000.000 22.19 14.99 19.30 -5434 114 -624 -53 -2 -1216 -338 -2018 948 -1917 4797 -1970 -2492 -1773 697 -4871 -262 872 2479 -432 -965 1746 424 4137 -1835 832 -1981 88 -2340 2307 -575 1645 60 4235 -3226 4228 294 2787 -1236 690 -907 -1424 759 -666 4387 -278 408 795 3432 -549 3882 -723 -1328 -921 770 -3569 5203 -2840 909 -1173 1070 458 -730 -380 -578 338 -1952 1547 908 2824 -3559 2388 -1148 1841 -2864 3824 -3771 7710 -2596 -681 -1053 -2457 2906 981 -1181 -2692 2305 2977 -1548 -1705 2102 2129 4766 -2551 330 137 852 -351 13 -3493 1467 258 -2455 2516 -2351 3294 -2301 1652 -358 1118 -303 -1076 -4187 -1134 -2226 4164 -1291 4755 -648 1120 -224 -2350 2758 -2097 1609 -2267 3436 1387 4989 850 2073 -1204 2144 -3170 1645 -4598 -335 -1133 -149 -1714 4186 965 -2201 490 569 -255 -1442 748 -3818 94 -2987 -5153 104 -594 -52 -2 -1262 -355 -2175 994 -2037 4694 -2038 -2550 -1779 678 -5001 -260 877 2534 -459 -1028 1817 448 4225 -2005 887 -2157 93 -2495 2263 -565 1590 60 4200 -3561 4381 313 2870 -1308 710 -949 -1509 797 -717 4561 -303 441 846 3507 -572 3758 -712 -1296 -893 754 -3772 5186 -3091 955 -1252 1115 483 -783 -407 -615 352 -2039 1537 899 2711 -3576 2260 -1132 1783 -2948 3684 -3830 6864 -2520 -646 -997 -2375 2683 925 -1150 -2685 2193 2807 -1515 -1665 1985 2025 4502 -2607 324 131 793 -322 11 -3154 1238 222 -2214 2257 -2305 3097 -2271 1552 -339 1044 -292 -1061 -4308 -1144 -2281 4024 -1325 4658 -670 1128 -225 -2365 2603 -2073 1553 -2282 3274 1353 4677 829 2007 -1188 2007 -3090 1523 -4531 -324 -1130 -149 -1764 4121 985 -2323 507 588 -266 -1506 750 -3899 91 -2993 SO 20190727T101531.0Z 7147.427442 238 1 20.05 2 88.52 64.44 44.80 114.25 0.00 1 0.00 1 0 29 1.873e-02 1.826e-02 2.030e-03 2.016e-03 1.185878e+04 1.374284e+02 7.529858e+02 -6.000000e+00 1.036008e+03 287.07 -2.00 20.00 -2.00 505.49 0.00e+00 4.287562e-03 5.599224e-05 1.959747e-04 -6.000000e+00 5.263417e-04 287.07 -2.00 20.00 -2.00 501.19 0.00e+00 1.492774e+00 3.806664e-02 9.161536e-02 -6.000000e+00 3.686830e-01 232.62 -2.00 3.57 -2.00 502.67 0.00e+00 17.333 0.101 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