File name: Pandora104s1_Downsview_20190728_L2Fit_fwvt1c21d20180627p1-8.txt File generation date: 20241127T014845.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c21p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 104 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora104_OF_v5d20171009.txt Instrument calibration file used: Pandora104s1_CF_v21d20180627.txt Level 1 file used: Pandora104s1_Downsview_20190728_L1_smca1c21d20180627p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20190728 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 12 to revisit NO2 and SO2 First and last pixel inside fitting window: 1633 1783 Nominal wavelengths inside fitting window [nm]: 492.0163 492.1368 492.2573 492.3778 492.4983 492.6187 492.7391 492.8596 492.9800 493.1003 493.2207 493.3411 493.4614 493.5817 493.7020 493.8223 493.9425 494.0628 494.1830 494.3032 494.4234 494.5436 494.6637 494.7839 494.9040 495.0241 495.1442 495.2643 495.3843 495.5044 495.6244 495.7444 495.8644 495.9844 496.1043 496.2242 496.3442 496.4641 496.5840 496.7038 496.8237 496.9435 497.0633 497.1831 497.3029 497.4227 497.5424 497.6621 497.7818 497.9015 498.0212 498.1409 498.2605 498.3801 498.4997 498.6193 498.7389 498.8585 498.9780 499.0975 499.2170 499.3365 499.4560 499.5754 499.6949 499.8143 499.9337 500.0531 500.1724 500.2918 500.4111 500.5304 500.6497 500.7690 500.8882 501.0075 501.1267 501.2459 501.3651 501.4843 501.6034 501.7226 501.8417 501.9608 502.0799 502.1989 502.3180 502.4370 502.5560 502.6750 502.7940 502.9130 503.0319 503.1509 503.2698 503.3887 503.5075 503.6264 503.7452 503.8641 503.9829 504.1017 504.2204 504.3392 504.4579 504.5766 504.6953 504.8140 504.9327 505.0513 505.1700 505.2886 505.4072 505.5258 505.6443 505.7629 505.8814 505.9999 506.1184 506.2368 506.3553 506.4737 506.5922 506.7106 506.8289 506.9473 507.0657 507.1840 507.3023 507.4206 507.5389 507.6571 507.7754 507.8936 508.0118 508.1300 508.2482 508.3663 508.4845 508.6026 508.7207 508.8388 508.9569 509.0749 509.1929 509.3109 509.4289 509.5469 509.6649 509.7828 509.9007 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190728T100843.0Z 7148.422720 251 1 32.01 2 89.79 63.43 52.83 98.69 0.00 1 0.00 1 0 15 1.210e-01 1.081e-01 1.067e-01 1.027e-01 -2.904251e+03 5.984125e+03 2.682755e+02 -6.000000e+00 6.726395e+03 287.09 -2.00 20.00 -2.00 505.25 0.00e+00 -8.980202e-04 2.829532e-03 1.028033e-04 -6.000000e+00 3.406336e-03 287.09 -2.00 20.00 -2.00 499.90 0.00e+00 4.408468e+00 2.080932e+00 1.683722e-02 -6.000000e+00 2.398362e+00 232.58 -2.00 3.57 -2.00 501.60 0.00e+00 20.008 0.156 489.00 513.00 1 1.0198e+01 1.5958e-01 3.5681e-02 -6.0000e+00 1.8322e-01 1.0072e-01 4.1371e-02 1.9905e-03 -6.0000e+00 4.8118e-02 3.2054e-06 -8.5657e-04 9.0887e-03 4.0038e-05 -6.0000e+00 1.0775e-02 4.5777e-02 -3.3234e-04 12 9 8 11 8 0 -5.17 22.09 11.74 0.04578 0.03984 8 2 1 4 0 4000.000 22.09 14.99 19.32 -4382 -3233 18242 -4309 -10701 1693 19176 -12198 3645 -4183 5190 3002 -6124 6057 8680 -17488 -1153 -5978 -4121 -8136 -8874 -1003 1805 -12079 -5490 14563 27509 4567 -4994 16103 9938 4389 -4390 1967 2246 6962 11589 -3779 -8110 19527 134 13752 990 -861 5023 -3990 2782 -8113 2581 -1002 26527 -4530 12703 9624 -3949 9789 -1451 7881 -9000 -13065 9406 -1292 1515 -6421 9789 5701 -6795 13949 8176 -4615 -7304 -11310 -7956 28181 -4478 7748 -2619 900000 -5508 -8445 20831 1293 2443 -4755 3932 -20599 21956 7772 -3360 18544 16396 -9887 19030 6071 9075 -13600 15772 3346 4239 -9451 -6447 -7735 11386 1286 9076 2549 18522 4998 -23438 5560 272 15574 3864 20869 -6706 -9491 464 -7310 214 11543 -789 -15960 3041 36712 -7432 -12210 -725 4121 29893 10694 -1688 -3950 -479 -4295 6805 16672 18821 16341 -3646 -11507 -1319 -25563 16828 -3860 -1127 24972 -11352 -7456 47521 -3361 -8352 -4408 -3248 15308 -4659 -12672 1809 17738 -15463 3987 -4903 5458 3193 -7023 6085 8435 -21774 -1240 -6862 -4799 -10065 -11058 -1161 2036 -15545 -6673 14631 24259 4986 -5901 15038 9494 4404 -4825 2091 2483 7487 11836 -4419 -9778 17803 147 13166 1078 -960 5350 -4657 3030 -9699 2736 -1078 21307 -4738 11010 8492 -4021 9031 -1531 7725 -10380 -15589 8988 -1368 1570 -7171 9317 5570 -7348 12129 7411 -4680 -7468 -11902 -8138 20586 -4541 7034 -2587 900000 -5369 -8417 15623 1176 2217 -4633 3547 -23783 16960 6877 -3308 14817 13425 -10442 15459 5666 8260 -15237 13182 3107 3801 -9426 -6097 -7363 9164 1170 7961 2408 14841 4484 -27173 4835 251 12575 3545 16543 -6997 -10220 456 -7753 210 10075 -761 -17608 2767 24123 -7525 -13008 -690 3750 21192 9079 -1621 -3862 -445 -4073 5732 12695 14219 12989 -3580 -12354 -1299 -31930 14007 -3943 -1130 19571 -12556 -7805 28655 -3213 -8321 SO 20190728T101246.0Z 7148.425532 255 1 32.01 2 89.13 64.13 52.12 99.45 0.00 1 0.00 1 0 22 5.477e-02 5.284e-02 5.156e-02 5.066e-02 1.684477e+04 3.960456e+03 4.979140e+02 -6.000000e+00 3.028376e+03 287.09 -2.00 20.00 -2.00 505.25 0.00e+00 3.252880e-03 1.396826e-03 3.092349e-04 -6.000000e+00 1.538674e-03 287.09 -2.00 20.00 -2.00 500.01 0.00e+00 -3.155960e-02 1.037348e+00 1.478210e-01 -6.000000e+00 1.075814e+00 232.58 -2.00 3.57 -2.00 501.64 0.00e+00 18.821 0.130 489.00 513.00 1 9.8734e+00 7.9049e-02 3.4814e-02 -6.0000e+00 8.2473e-02 1.5937e-01 2.0439e-02 3.1399e-03 -6.0000e+00 2.1526e-02 6.7544e-06 -1.4557e-02 3.9495e-03 8.5540e-05 -6.0000e+00 4.8495e-03 1.5531e-03 1.7567e-04 12 8 8 10 0 0 99.25 22.19 3.29 0.00155 -0.09942 8 2 1 4 0 4000.000 22.19 15.00 19.33 2282 827 2114 -8614 -3637 1242 5962 14 -48 5651 -2491 -6855 -10509 3840 2395 -3175 -2211 -7755 3491 1881 15027 1136 2269 3947 1715 -510 9643 -7041 3996 -580 -4823 754 424 -6505 -7106 5461 1266 -5077 4143 5987 729 4926 8302 7087 -3251 4339 -6298 2204 154 1848 132 -7902 -4888 -2697 919 -924 -2355 -2702 -4067 275 4783 -1237 893 10436 2989 -773 6605 -2029 -5689 -3689 -1976 -4326 1968 5112 -6179 5323 7272 -7697 9091 2731 6947 13168 8710 9504 2578 -2244 4011 -869 810 -6849 4774 -1856 -5294 -5457 -3728 -4422 -4907 -2753 8531 -1876 2521 15941 12479 -2647 2949 -8567 3042 -2493 7937 -5512 1058 -5874 -5204 1693 -3544 -2105 -2100 1705 6826 9950 1048 2550 2556 1302 -358 4052 4213 5432 -121 3821 -7453 -9580 -7657 -6990 9556 -1399 -103 -7554 3220 -5108 4933 4053 -3208 -1627 7638 -3695 3241 -5054 9750 -5117 2996 2175 795 2044 -9538 -3986 1324 6189 15 -54 6025 -2828 -7962 -12503 3910 2440 -3382 -2335 -8741 3612 2034 14434 1243 2460 4205 1873 -573 9822 -8371 4239 -630 -5230 757 428 -7119 -8139 5729 1389 -5855 4327 6071 770 5002 8224 7174 -3684 4626 -7459 2395 169 1955 139 -8718 -5097 -2713 892 -939 -2513 -2961 -4567 295 4906 -1341 956 10228 3145 -839 6564 -2151 -6143 -3871 -2014 -4440 1898 4818 -6569 5138 6860 -8212 8060 2541 6158 10931 7585 8259 2405 -2221 3778 -857 783 -7045 4354 -1805 -5366 -5628 -3789 -4409 -4726 -2500 6709 -1595 2017 11023 9017 -2280 2539 -8668 2810 -2434 6944 -5422 977 -5886 -5250 1608 -3546 -2075 -2069 1633 6340 9041 1028 2414 2362 1189 -331 3626 3774 4807 -113 3421 -7417 -9752 -7520 -6660 7706 -1250 -92 -7369 2884 -4997 4442 3728 -3184 -1596 6863 -3693 3013 -5033 8253 -4885 2609 SO 20190728T101642.0Z 7148.428264 259 1 32.01 2 88.49 64.81 51.44 100.19 0.00 1 0.00 1 0 15 3.140e-02 3.081e-02 2.665e-02 2.632e-02 9.337161e+03 1.872623e+03 7.124282e+02 -6.000000e+00 1.736962e+03 287.09 -2.00 20.00 -2.00 505.25 0.00e+00 1.343771e-03 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