File name: Pandora104s1_Downsview_20191007_L2Fit_fwvt1c21d20180627p1-8.txt
File generation date: 20241127T023821.7Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c21p1-8
Local principal investigator: Vitoli Fiolitov
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 104
Spectrometer number: 1
Processing software version used: BlickP v1.8.60
Instrument operation file used: Pandora104_OF_v5d20171009.txt
Instrument calibration file used: Pandora104s1_CF_v21d20180627.txt
Level 1 file used: Pandora104s1_Downsview_20191007_L1_smca1c21d20180627p1-8.txt
Full location name: Environment Canada HQ - Downsview
Short location name: Downsview
Country of location: Canada
Location latitude [deg]: 43.7810
Location longitude [deg]: -79.4680
Location altitude [m]: 187
Local noon date: 20191007
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: Based on session 12 to revisit NO2 and SO2
First and last pixel inside fitting window: 1633 1783
Nominal wavelengths inside fitting window [nm]: 492.0163 492.1368 492.2573 492.3778 492.4983 492.6187 492.7391 492.8596 492.9800 493.1003 493.2207 493.3411 493.4614 493.5817 493.7020 493.8223 493.9425 494.0628 494.1830 494.3032 494.4234 494.5436 494.6637 494.7839 494.9040 495.0241 495.1442 495.2643 495.3843 495.5044 495.6244 495.7444 495.8644 495.9844 496.1043 496.2242 496.3442 496.4641 496.5840 496.7038 496.8237 496.9435 497.0633 497.1831 497.3029 497.4227 497.5424 497.6621 497.7818 497.9015 498.0212 498.1409 498.2605 498.3801 498.4997 498.6193 498.7389 498.8585 498.9780 499.0975 499.2170 499.3365 499.4560 499.5754 499.6949 499.8143 499.9337 500.0531 500.1724 500.2918 500.4111 500.5304 500.6497 500.7690 500.8882 501.0075 501.1267 501.2459 501.3651 501.4843 501.6034 501.7226 501.8417 501.9608 502.0799 502.1989 502.3180 502.4370 502.5560 502.6750 502.7940 502.9130 503.0319 503.1509 503.2698 503.3887 503.5075 503.6264 503.7452 503.8641 503.9829 504.1017 504.2204 504.3392 504.4579 504.5766 504.6953 504.8140 504.9327 505.0513 505.1700 505.2886 505.4072 505.5258 505.6443 505.7629 505.8814 505.9999 506.1184 506.2368 506.3553 506.4737 506.5922 506.7106 506.8289 506.9473 507.0657 507.1840 507.3023 507.4206 507.5389 507.6571 507.7754 507.8936 508.0118 508.1300 508.2482 508.3663 508.4845 508.6026 508.7207 508.8388 508.9569 509.0749 509.1929 509.3109 509.4289 509.5469 509.6649 509.7828 509.9007
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Temperature at electronics board [°C], 999=no temperature signal
Column 96: Spectrometer control temperature [°C], 999=no temperature signal
Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SO 20191007T112824.0Z 7219.478056 431 1 32.01 2 89.74 97.87 153.12 320.50 0.00 1 0.00 1 0 29 1.018e-01 9.957e-02 9.767e-02 9.488e-02 2.027444e+03 5.916817e+03 7.779249e+02 -6.000000e+00 5.541743e+03 282.12 -2.00 20.00 -2.00 505.34 0.00e+00 1.091842e-03 2.612328e-03 1.366812e-04 -6.000000e+00 2.838424e-03 282.12 -2.00 20.00 -2.00 500.18 0.00e+00 4.819456e+00 1.954332e+00 1.533414e-01 -6.000000e+00 2.005404e+00 226.41 -2.00 3.57 -2.00 501.82 0.00e+00 20.116 0.159 489.00 513.00 1 1.0071e+01 1.4892e-01 3.7623e-02 -6.0000e+00 1.5298e-01 6.8485e-02 3.9431e-02 2.6709e-03 -6.0000e+00 4.0331e-02 3.3784e-06 -2.3018e-02 8.0956e-03 9.4253e-05 -6.0000e+00 9.0468e-03 3.5711e-02 1.3959e-03 12 9 8 11 8 0 -72.89 21.88 6.70 0.03571 -0.12395 8 2 1 4 0 4000.000 21.88 15.00 18.95 6075 7919 8857 3871 -8838 16619 14980 2707 -2064 -2529 14004 -196 4747 9797 3438 -19637 19712 -6200 -13339 -13197 -395 15749 6606 -7142 312 14282 -2202 12244 -13624 12961 7020 2467 -5104 -8 3710 -7875 -4361 -9938 -1370 -4006 11290 -10742 37 -2984 7469 -534 15388 1143 2944 1956 -13213 16658 122 -9077 13915 -1864 -13873 -13939 -6518 8365 5126 2498 10796 -5098 1588 15123 -7645 3667 -9013 1188 -6914 5746 13776 -4380 13487 -399 -10694 900000 -10743 -2429 11407 9116 -6892 17687 12864 23813 3803 -2604 11727 14423 -4356 -756 8718 5769 -618 11559 2228 -2589 851 -11535 9647 10421 729 8981 -2060 -810 1197 16460 1100 370 4962 1662 -27241 -7497 -17097 2172 -12055 -12546 -8747 15062 -12018 1166 26902 8343 716 14556 -57 633 -2260 8727 11565 -922 -3463 14278 -16285 4689 -9998 -16506 10071 -409 14128 2766 -8161 804 6808 21614 1736 5832 22147 900000 900000 5418 7095 8160 3869 -10176 15316 14299 2921 -2329 -2816 13134 -208 4739 9231 3425 -24559 17181 -7123 -16887 -16753 -444 15174 6947 -8616 353 14064 -2526 12125 -16827 11918 6751 2494 -5656 -9 4050 -9594 -5070 -12081 -1513 -4502 10972 -12981 41 -3413 7797 -602 14750 1236 3075 2010 -15196 14038 119 -9719 12344 -1981 -16870 -17014 -7388 8171 5157 2594 10347 -5683 1641 13486 -8312 3525 -9683 1138 -7070 5213 11658 -4472 11726 -392 -11304 900000 -11050 -2295 9443 7783 -6873 14008 10792 18093 3496 -2540 9939 11936 -4323 -733 7848 5355 -601 9816 2029 -2403 747 -11140 7532 8180 646 7672 -2003 -775 1108 12974 995 340 4436 1556 -34118 -7844 -19707 2088 -13384 -14050 -9387 12666 -12907 1088 19521 7296 679 12092 -55 601 -2199 7687 9895 -874 -3309 11417 -17364 4142 -10445 -18714 8971 -408 12368 2707 -8923 812 6505 17884 1710 5389 17118 900000 900000
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SO 20191007T113631.0Z 7219.483692 439 1 32.01 2 88.29 99.28 153.96 324.08 0.00 1 0.00 1 0 15 3.838e-02 3.814e-02 2.871e-02 2.839e-02 1.076817e+04 2.026391e+03 7.142003e+02 -6.000000e+00 2.079931e+03 282.12 -2.00 20.00 -2.00 505.29 0.00e+00 9.761463e-04 7.708589e-04 9.819211e-05 -6.000000e+00 1.065386e-03 282.12 -2.00 20.00 -2.00 500.11 0.00e+00 1.091338e+00 5.710846e-01 6.370503e-02 -6.000000e+00 7.511468e-01 226.41 -2.00 3.57 -2.00 501.74 0.00e+00 16.841 0.093 489.00 513.00 1 9.5439e+00 4.3582e-02 2.7583e-02 -6.0000e+00 5.7493e-02 1.0893e-01 1.1222e-02 2.1542e-03 -6.0000e+00 1.5040e-02 1.1947e-05 -3.0980e-03 2.3185e-03 6.7422e-05 -6.0000e+00 3.3870e-03 2.9492e-02 -1.1774e-04 12 8 8 10 0 0 41.52 21.98 4.74 0.02949 0.00800 8 2 1 4 0 4000.000 21.98 15.00 18.97 2143 3777 -1844 -2988 -2105 -596 -4135 10146 -2707 5978 -2244 2646 -7474 214 -3569 -1826 -1250 1671 -2239 -307 -1597 948 1673 2478 1545 2456 -352 -8292 3775 -2418 1375 -5511 4499 -3307 3413 -653 8764 -3009 589 546 8469 1230 854 614 1788 2733 -2412 784 -841 -803 -5463 2286 -1083 -1135 -2220 122 -4289 4718 -1288 6712 1166 1563 1843 -3165 1486 -3925 2947 -1027 -566 -5979 479 -210 40 472 2442 -3753 2997 -1881 9071 -1546 752 3639 2948 5835 2781 1768 3877 308 1065 -479 -3359 1357 -6993 2382 -2174 -11 3782 2616 -2619 2853 -851 4959 3779 103 -2216 -516 2957 -1669 1792 -6835 5054 -7166 3060 -5995 -4071 179 3247 -4038 2968 3827 9220 -2351 6136 -143 1917 -2634 -744 737 -5542 4263 -7587 2904 -10079 3990 -7652 5343 -2034 -1996 -2779 5224 7462 4131 -1231 1355 3887 807 4087 -4526 654 -5388 -1027 1985 3476 -1839 -3127 -2250 -638 -4686 10151 -3076 6205 -2471 2749 -8446 221 -3789 -1898 -1303 1725 -2476 -340 -1791 1037 1821 2673 1693 2676 -392 -9902 3963 -2607 1377 -5873 4386 -3574 3607 -731 8895 -3382 633 579 8283 1294 908 661 1926 2939 -2718 848 -909 -852 -5899 2219 -1063 -1104 -2215 124 -4648 4772 -1383 6650 1212 1622 1921 -3464 1552 -4265 2945 -1047 -568 -6254 463 -203 39 459 2370 -3893 2870 -1844 7859 -1474 696 3287 2702 5223 2586 1683 3639 298 1021 -463 -3334 1291 -7314 2303 -2178 -11 3367 2283 -2337 2371 -717 3939 3102 91 -2117 -500 2780 -1628 1668 -6856 4562 -7382 2886 -6205 -4147 175 3090 -4174 2900 3695 8305 -2321 5469 -134 1770 -2561 -709 694 -5529 3845 -7698 2649 -10193 3469 -7407 4550 -1890 -1903 -2706 4767 6762 3899 -1229 1325 3717 794 3871 -4585 616 -5265 -957
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