File name: Pandora104s1_Downsview_20191021_L2Fit_fwvt1c21d20180627p1-8.txt
File generation date: 20241127T024645.1Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c21p1-8
Local principal investigator: Vitoli Fiolitov
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 104
Spectrometer number: 1
Processing software version used: BlickP v1.8.60
Instrument operation file used: Pandora104_OF_v5d20171009.txt
Instrument calibration file used: Pandora104s1_CF_v21d20180627.txt
Level 1 file used: Pandora104s1_Downsview_20191021_L1_smca1c21d20180627p1-8.txt
Full location name: Environment Canada HQ - Downsview
Short location name: Downsview
Country of location: Canada
Location latitude [deg]: 43.7810
Location longitude [deg]: -79.4680
Location altitude [m]: 187
Local noon date: 20191021
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: Based on session 12 to revisit NO2 and SO2
First and last pixel inside fitting window: 1633 1783
Nominal wavelengths inside fitting window [nm]: 492.0163 492.1368 492.2573 492.3778 492.4983 492.6187 492.7391 492.8596 492.9800 493.1003 493.2207 493.3411 493.4614 493.5817 493.7020 493.8223 493.9425 494.0628 494.1830 494.3032 494.4234 494.5436 494.6637 494.7839 494.9040 495.0241 495.1442 495.2643 495.3843 495.5044 495.6244 495.7444 495.8644 495.9844 496.1043 496.2242 496.3442 496.4641 496.5840 496.7038 496.8237 496.9435 497.0633 497.1831 497.3029 497.4227 497.5424 497.6621 497.7818 497.9015 498.0212 498.1409 498.2605 498.3801 498.4997 498.6193 498.7389 498.8585 498.9780 499.0975 499.2170 499.3365 499.4560 499.5754 499.6949 499.8143 499.9337 500.0531 500.1724 500.2918 500.4111 500.5304 500.6497 500.7690 500.8882 501.0075 501.1267 501.2459 501.3651 501.4843 501.6034 501.7226 501.8417 501.9608 502.0799 502.1989 502.3180 502.4370 502.5560 502.6750 502.7940 502.9130 503.0319 503.1509 503.2698 503.3887 503.5075 503.6264 503.7452 503.8641 503.9829 504.1017 504.2204 504.3392 504.4579 504.5766 504.6953 504.8140 504.9327 505.0513 505.1700 505.2886 505.4072 505.5258 505.6443 505.7629 505.8814 505.9999 506.1184 506.2368 506.3553 506.4737 506.5922 506.7106 506.8289 506.9473 507.0657 507.1840 507.3023 507.4206 507.5389 507.6571 507.7754 507.8936 508.0118 508.1300 508.2482 508.3663 508.4845 508.6026 508.7207 508.8388 508.9569 509.0749 509.1929 509.3109 509.4289 509.5469 509.6649 509.7828 509.9007
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Temperature at electronics board [°C], 999=no temperature signal
Column 96: Spectrometer control temperature [°C], 999=no temperature signal
Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SO 20191021T114542.0Z 7233.490070 258 1 32.01 2 89.75 105.14 22.82 197.04 0.00 1 0.00 1 0 15 1.196e-02 1.188e-02 1.096e-02 1.092e-02 5.537758e+03 6.935330e+02 2.925903e+02 -6.000000e+00 6.438012e+02 280.35 -2.00 20.00 -2.00 505.39 0.00e+00 2.754453e-03 2.973120e-04 1.468281e-04 -6.000000e+00 3.305696e-04 280.35 -2.00 20.00 -2.00 500.67 0.00e+00 2.388616e+00 2.117075e-01 6.378942e-02 -6.000000e+00 2.334930e-01 224.87 -2.00 3.57 -2.00 502.24 0.00e+00 20.182 0.160 489.00 513.00 1 7.9716e+00 1.6204e-02 3.6631e-02 -6.0000e+00 1.7873e-02 5.0793e-02 4.1197e-03 2.3224e-03 -6.0000e+00 4.6616e-03 3.2390e-05 3.2173e-04 9.3368e-04 4.9724e-05 -6.0000e+00 1.0577e-03 -7.5859e-02 7.0787e-04 12 8 8 10 0 0 13.91 21.88 2.67 -0.07586 -0.07363 8 2 1 4 0 4000.000 21.88 15.00 18.88 -984 317 -2319 -989 -1569 -1032 -70 -749 -302 912 -2332 777 582 255 1300 -524 931 403 -384 517 888 1606 1 -246 -377 977 1107 369 1743 -1539 -1506 671 -2367 -862 -1762 -1878 205 524 -64 300 1607 578 -613 1938 1791 807 -535 -273 491 887 -143 568 -102 716 -1201 612 2210 877 332 -1317 1834 386 720 3652 -1342 536 114 -651 242 -81 -665 -457 -801 -316 -814 -2386 -179 -2213 344 -769 -14 -955 1074 939 473 -562 507 442 671 -1497 -815 -114 -86 -782 1023 -1160 98 -1786 393 -1893 3794 -867 122 1557 314 -274 -318 2803 -783 -227 -1714 1456 1027 -762 -918 574 1036 2833 77 -87 -592 62 397 -182 1443 1913 113 1155 2492 -560 -2840 -377 -848 -1296 -204 -436 -339 -692 1091 125 -731 -1033 -1476 1912 22 -1476 26 -809 856 -1600 935 -867 280 -2169 -949 -1552 -1035 -71 -772 -311 917 -2375 762 563 244 1227 -503 893 397 -393 532 909 1637 1 -257 -397 1017 1146 382 1755 -1539 -1468 642 -2359 -879 -1880 -2026 215 543 -66 306 1617 591 -641 2002 1877 859 -574 -289 509 899 -142 545 -97 674 -1182 613 2236 909 346 -1392 1876 402 753 3718 -1424 552 116 -656 239 -80 -646 -442 -783 -311 -817 -2431 -175 -2162 324 -730 -13 -911 1012 889 455 -551 493 430 648 -1473 -799 -112 -86 -795 1013 -1147 94 -1696 357 -1723 3208 -770 110 1440 306 -272 -313 2650 -756 -219 -1700 1425 1023 -780 -948 586 1061 2881 81 -90 -607 62 392 -181 1428 1894 114 1155 2451 -567 -2953 -378 -839 -1274 -197 -424 -337 -706 1109 129 -775 -1104 -1590 2007 24 -1603 28 -849 862 -1626 932
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SO 20191021T115337.6Z 7233.495574 266 1 33.20 2 88.38 106.52 23.29 201.46 0.00 1 0.00 1 0 29 7.707e-03 7.532e-03 4.168e-04 4.140e-04 1.227395e+04 2.740105e+01 8.287105e+02 -6.000000e+00 4.147032e+02 280.35 -2.00 20.00 -2.00 505.47 0.00e+00 5.033644e-03 1.136974e-05 2.663505e-04 -6.000000e+00 2.130516e-04 280.35 -2.00 20.00 -2.00 501.20 0.00e+00 1.145741e+00 7.838744e-03 9.612608e-02 -6.000000e+00 1.505969e-01 224.87 -2.00 3.57 -2.00 502.68 0.00e+00 17.089 0.097 489.00 513.00 1 3.7433e+00 5.9739e-04 2.9417e-02 -6.0000e+00 1.1523e-02 -6.0846e-02 1.5110e-04 2.6577e-03 -6.0000e+00 3.0123e-03 3.6060e-03 1.8465e-03 3.4454e-05 1.2099e-04 -6.0000e+00 6.8106e-04 2.1741e-02 -3.2566e-05 12 8 8 10 0 0 84.45 21.88 5.31 0.02174 0.03455 89 18 1 4 0 372.910 21.88 15.00 18.89 -2552 -2013 -1447 -486 -104 341 963 937 1028 531 167 -52 -571 -901 -872 -969 -529 -195 471 326 541 621 615 830 1034 963 794 621 -69 -864 -1225 -788 -924 188 463 521 231 316 119 -82 75 182 376 702 1008 1009 1012 797 504 -65 -766 -1256 -1509 -1507 -633 -186 151 357 571 508 677 879 1059 916 787 468 277 -34 -161 -516 -860 -613 -399 -307 -100 -199 -632 -1044 -1011 -859 -1080 -768 -724 -762 -423 -300 -342 -270 -203 5 431 472 954 1013 995 788 754 168 -422 -1126 -1639 -1443 -1163 -556 -106 -289 -352 -431 -630 -495 -219 -37 204 672 950 1336 1542 1619 1125 685 260 271 150 506 775 516 401 495 220 177 251 -252 -486 -572 -985 -987 -454 -349 -100 225 294 139 212 342 477 370 39 -419 -844 -1150 -1117 -2215 -1774 -1242 -431 -95 315 907 893 981 504 156 -49 -526 -822 -791 -882 -486 -183 455 302 501 578 574 778 980 918 758 592 -65 -792 -1159 -747 -843 177 453 516 228 309 116 -79 73 179 375 710 1034 992 995 779 514 -66 -756 -1215 -1445 -1443 -619 -188 150 358 574 511 679 890 1080 938 806 475 278 -33 -159 -505 -833 -592 -388 -302 -100 -200 -627 -1017 -974 -823 -1034 -739 -702 -744 -417 -299 -342 -270 -201 5 425 471 967 1040 1009 778 723 158 -409 -1082 -1555 -1376 -1079 -539 -108 -302 -351 -448 -650 -511 -219 -38 211 700 994 1397 1627 1741 1230 748 280 287 156 525 814 548 429 532 236 191 272 -272 -515 -602 -1039 -1047 -492 -369 -107 244 324 154 238 386 538 418 44 -466 -923 -1243 -1215
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