File name: Pandora122s1_Downsview_20221111_L2Fit_fwvt1c1d20220801p1-8.txt File generation date: 20260318T005207.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c1p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 122 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora122_OF_v6d20161030.txt Instrument calibration file used: Pandora122s1_CF_v1d20220801.txt Level 1 file used: Pandora122s1_Downsview_20221111_L1_smca1c1d20220801p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20221111 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1652 1801 Nominal wavelengths inside fitting window [nm]: 492.1089 492.2301 492.3513 492.4725 492.5936 492.7148 492.8359 492.9570 493.0781 493.1992 493.3202 493.4412 493.5623 493.6833 493.8043 493.9252 494.0462 494.1671 494.2880 494.4090 494.5298 494.6507 494.7716 494.8924 495.0132 495.1340 495.2548 495.3756 495.4963 495.6171 495.7378 495.8585 495.9792 496.0998 496.2205 496.3411 496.4617 496.5823 496.7029 496.8235 496.9440 497.0646 497.1851 497.3056 497.4261 497.5465 497.6670 497.7874 497.9078 498.0282 498.1486 498.2690 498.3893 498.5096 498.6300 498.7502 498.8705 498.9908 499.1110 499.2313 499.3515 499.4717 499.5918 499.7120 499.8321 499.9523 500.0724 500.1925 500.3125 500.4326 500.5526 500.6726 500.7927 500.9126 501.0326 501.1526 501.2725 501.3924 501.5123 501.6322 501.7521 501.8719 501.9918 502.1116 502.2314 502.3512 502.4709 502.5907 502.7104 502.8301 502.9498 503.0695 503.1892 503.3088 503.4284 503.5481 503.6677 503.7872 503.9068 504.0263 504.1459 504.2654 504.3849 504.5043 504.6238 504.7432 504.8627 504.9821 505.1014 505.2208 505.3402 505.4595 505.5788 505.6981 505.8174 505.9367 506.0559 506.1752 506.2944 506.4136 506.5328 506.6519 506.7711 506.8902 507.0093 507.1284 507.2475 507.3665 507.4856 507.6046 507.7236 507.8426 507.9616 508.0805 508.1995 508.3184 508.4373 508.5562 508.6751 508.7939 508.9128 509.0316 509.1504 509.2692 509.3879 509.5067 509.6254 509.7441 509.8628 509.9815 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20221111T123222.9Z 8350.522487 274 1 49.73 2 86.75 118.14 62.90 281.41 0.00 1 0.00 1 0 22 4.421e-03 4.376e-03 7.339e-04 7.329e-04 1.218900e+04 5.037622e+01 8.352447e+02 -6.000000e+00 2.432246e+02 277.66 -2.00 20.00 -2.00 505.38 0.00e+00 2.757303e-03 2.018997e-05 1.629069e-04 -6.000000e+00 1.230302e-04 277.66 -2.00 20.00 -2.00 500.83 0.00e+00 7.948706e-01 1.434003e-02 8.647912e-02 -6.000000e+00 8.759845e-02 222.93 -2.00 3.57 -2.00 502.36 0.00e+00 13.000 0.043 489.00 513.00 1 -3.4027e+00 1.0972e-03 2.0882e-02 -6.0000e+00 6.7137e-03 -2.3465e-02 2.7500e-04 2.3462e-03 -6.0000e+00 1.7314e-03 8.5613e+00 1.0713e-03 7.0285e-05 1.1740e-04 -6.0000e+00 4.6179e-04 1.5686e-02 -1.6514e-04 11 9 0 11 32 0 67.24 22.04 1.45 0.01569 0.02312 22 4 1 4 0 2259.940 27.15 20.00 22.04 -794 -502 213 336 338 831 847 427 936 739 225 60 -206 -339 -622 -280 -239 263 224 -31 18 91 189 686 288 202 226 -83 -107 -849 -729 -527 -1 234 -51 234 -187 75 105 -131 131 -310 281 548 493 195 357 -60 -90 -288 -703 -1535 -1067 -737 -124 18 220 98 235 239 445 779 634 300 -398 61 14 -250 -378 -360 -532 -633 -486 -378 -251 -128 10 -192 -86 -370 -649 -185 -254 -90 68 -307 -140 -55 -406 88 -159 285 312 689 154 219 38 -472 -624 -616 -1124 -537 -418 13 -283 -366 -329 -482 -83 -172 -26 144 338 855 683 995 658 647 260 -132 -37 465 824 401 585 220 101 232 111 210 -75 -31 -675 -547 -79 -217 -68 13 169 23 10 536 447 489 92 258 -273 -318 -450 -358 -734 -473 201 328 330 827 834 425 923 721 222 59 -199 -327 -600 -272 -231 259 226 -31 18 91 190 689 292 205 228 -83 -106 -829 -706 -515 -1 236 -52 236 -188 76 106 -132 133 -312 286 562 511 203 368 -61 -90 -289 -689 -1494 -1033 -726 -123 18 226 99 238 242 453 795 650 307 -406 62 14 -250 -375 -354 -523 -628 -488 -382 -255 -128 10 -186 -83 -357 -631 -180 -250 -90 67 -303 -138 -54 -399 87 -158 287 314 684 150 210 36 -443 -577 -565 -1046 -513 -408 12 -282 -367 -327 -477 -82 -172 -27 147 342 864 696 1022 671 664 266 -136 -38 463 835 402 589 223 103 236 113 213 -75 -31 -682 -553 -79 -221 -69 14 177 24 10 564 473 518 98 269 -281 -329 -464 -371 SQ 20221111T124515.1Z 8350.531424 277 1 52.11 2 84.72 120.45 65.09 283.33 0.00 1 0.00 1 0 22 4.018e-03 3.987e-03 8.484e-04 8.475e-04 9.155460e+03 5.655518e+01 6.329412e+02 -6.000000e+00 2.210969e+02 277.66 -2.00 20.00 -2.00 505.34 0.00e+00 2.565216e-03 2.325691e-05 1.487595e-04 -6.000000e+00 1.118341e-04 277.66 -2.00 20.00 -2.00 500.71 0.00e+00 6.510855e-01 1.664952e-02 6.846816e-02 -6.000000e+00 7.961504e-02 222.93 -2.00 3.57 -2.00 502.26 0.00e+00 9.446 0.016 489.00 513.00 1 -2.5670e+00 1.2741e-03 1.5037e-02 -6.0000e+00 6.1020e-03 -1.6755e-02 3.2162e-04 1.7760e-03 -6.0000e+00 1.5732e-03 6.1989e+00 9.5384e-04 8.3260e-05 9.2345e-05 -6.0000e+00 4.1974e-04 -4.4233e-03 -3.0154e-05 11 9 0 11 32 0 98.35 22.05 1.54 -0.00442 0.00219 14 3 1 4 0 3721.951 27.26 20.00 22.05 -803 -273 9 69 125 697 627 222 718 598 190 109 -236 -104 -197 -487 70 -81 54 -92 -5 -88 199 588 398 1 142 -14 31 -990 -284 -214 137 287 -252 -117 -36 269 252 -101 258 289 -128 566 456 57 462 -93 -136 -112 -390 -1465 -977 -789 91 -162 355 65 150 115 255 862 570 269 -5 104 -182 -521 -277 -481 -322 -475 -157 -108 -256 -331 213 -200 52 -265 -704 -201 -150 -93 -86 -439 -232 -147 -440 147 -28 71 297 647 33 66 164 -321 -226 -918 -970 -648 -225 170 -287 -260 -299 -381 112 -156 162 112 339 1076 398 691 636 568 321 -331 44 365 926 172 657 -7 227 203 -14 235 249 205 -490 -594 -427 32 -99 -268 212 153 -144 128 414 428 -52 113 -399 -296 -250 -202 -762 -256 9 68 125 692 632 226 724 596 192 108 -233 -102 -192 -481 68 -82 55 -93 -5 -89 202 597 407 1 145 -14 31 -976 -275 -210 138 291 -261 -121 -37 273 255 -102 261 296 -131 580 471 59 474 -95 -138 -112 -388 -1450 -961 -770 91 -163 361 67 154 118 263 888 589 278 -5 105 -182 -516 -277 -477 -318 -473 -158 -107 -254 -326 210 -195 50 -257 -688 -197 -148 -91 -85 -436 -230 -146 -435 145 -28 70 295 634 33 64 157 -301 -212 -861 -896 -614 -216 169 -286 -260 -296 -375 110 -155 163 115 341 1080 405 707 643 576 331 -338 44 360 928 171 652 -7 227 203 -14 234 245 204 -485 -589 -427 31 -100 -271 216 158 -150 134 425 439 -53 117 -407 -296 -248 -201 SQ 20221111T130924.7Z 8350.548203 283 1 35.41 2 81.06 124.93 69.17 286.90 0.00 1 0.00 1 0 15 3.831e-03 3.793e-03 1.021e-03 1.020e-03 5.370851e+03 6.451115e+01 3.791093e+02 -6.000000e+00 2.107756e+02 277.66 -2.00 20.00 -2.00 505.31 0.00e+00 1.433269e-03 2.790204e-05 8.805928e-05 -6.000000e+00 1.065927e-04 277.66 -2.00 20.00 -2.00 500.60 0.00e+00 4.206424e-01 2.009939e-02 4.220732e-02 -6.000000e+00 7.573467e-02 222.92 -2.00 3.57 -2.00 502.18 0.00e+00 6.095 0.004 489.00 513.00 1 -2.1772e+00 1.5390e-03 9.4950e-03 -6.0000e+00 5.8066e-03 -3.2108e-03 3.9145e-04 1.0903e-03 -6.0000e+00 1.4931e-03 6.9674e+00 -1.9721e-03 1.0219e-04 5.6414e-05 -6.0000e+00 3.9942e-04 -1.3184e-02 1.7470e-04 12 9 1 12 1 1 99.03 22.05 1.47 -0.01318 -0.02686 9 3 1 4 0 3524.259 27.26 20.00 22.05 -629 -57 174 73 76 450 425 70 710 491 1 77 -143 -85 -594 -374 -145 323 89 -172 104 -63 104 356 362 50 -81 181 179 -713 -165 -174 309 171 -70 100 -168 138 213 57 338 -143 112 329 329 59 332 -257 15 -5 -521 -1329 -661 -528 306 -45 231 24 62 2 305 535 253 196 -744 64 -150 -135 -112 -362 -314 -327 -303 -312 -286 22 391 -93 331 -200 -750 -1 -158 21 239 -356 -159 -555 -272 -4 -76 195 -16 453 -112 0 181 -84 -142 52 -465 -2323 120 156 -402 -81 -302 -184 266 -16 -99 160 112 824 585 672 631 364 165 -451 245 315 937 280 455 157 154 -2 170 74 5 -11 -339 -390 344 199 202 -60 180 -185 -135 -128 304 312 -143 -76 -179 -256 -163 -362 -601 -55 170 74 76 463 443 72 738 504 1 77 -142 -86 -599 -370 -146 332 92 -178 107 -66 108 371 378 52 -84 184 182 -714 -163 -174 308 176 -72 102 -171 142 217 58 345 -149 114 339 341 61 341 -262 15 -5 -518 -1308 -646 -524 303 -46 234 25 63 2 311 546 260 201 -760 64 -151 -135 -110 -354 -305 -321 -301 -314 -287 22 379 -89 323 -191 -725 -1 -155 21 237 -350 -156 -546 -267 -3 -76 196 -16 454 -111 0 174 -79 -134 49 -441 -2252 115 155 -398 -79 -302 -182 262 -16 -98 161 113 834 584 674 637 368 166 -448 244 309 915 276 450 156 153 -2 169 73 5 -11 -331 -380 336 193 201 -60 180 -188 -137 -131 312 313 -144 -77 -178 -249 -161 -352 SQ 20221111T131757.4Z 8350.554137 285 1 14.79 2 79.81 126.56 70.59 288.16 0.00 1 0.00 1 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