File name: Pandora122s1_Downsview_20221119_L2Fit_fwvt1c1d20220801p1-8.txt File generation date: 20260318T005353.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c1p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 122 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora122_OF_v6d20161030.txt Instrument calibration file used: Pandora122s1_CF_v1d20220801.txt Level 1 file used: Pandora122s1_Downsview_20221119_L1_smca1c1d20220801p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20221119 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1652 1801 Nominal wavelengths inside fitting window [nm]: 492.1089 492.2301 492.3513 492.4725 492.5936 492.7148 492.8359 492.9570 493.0781 493.1992 493.3202 493.4412 493.5623 493.6833 493.8043 493.9252 494.0462 494.1671 494.2880 494.4090 494.5298 494.6507 494.7716 494.8924 495.0132 495.1340 495.2548 495.3756 495.4963 495.6171 495.7378 495.8585 495.9792 496.0998 496.2205 496.3411 496.4617 496.5823 496.7029 496.8235 496.9440 497.0646 497.1851 497.3056 497.4261 497.5465 497.6670 497.7874 497.9078 498.0282 498.1486 498.2690 498.3893 498.5096 498.6300 498.7502 498.8705 498.9908 499.1110 499.2313 499.3515 499.4717 499.5918 499.7120 499.8321 499.9523 500.0724 500.1925 500.3125 500.4326 500.5526 500.6726 500.7927 500.9126 501.0326 501.1526 501.2725 501.3924 501.5123 501.6322 501.7521 501.8719 501.9918 502.1116 502.2314 502.3512 502.4709 502.5907 502.7104 502.8301 502.9498 503.0695 503.1892 503.3088 503.4284 503.5481 503.6677 503.7872 503.9068 504.0263 504.1459 504.2654 504.3849 504.5043 504.6238 504.7432 504.8627 504.9821 505.1014 505.2208 505.3402 505.4595 505.5788 505.6981 505.8174 505.9367 506.0559 506.1752 506.2944 506.4136 506.5328 506.6519 506.7711 506.8902 507.0093 507.1284 507.2475 507.3665 507.4856 507.6046 507.7236 507.8426 507.9616 508.0805 508.1995 508.3184 508.4373 508.5562 508.6751 508.7939 508.9128 509.0316 509.1504 509.2692 509.3879 509.5067 509.6254 509.7441 509.8628 509.9815 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20221119T124152.7Z 8358.529083 210 1 50.48 2 86.99 120.93 43.04 160.91 0.00 1 0.00 1 0 22 4.341e-03 4.310e-03 4.740e-04 4.734e-04 3.542337e+03 2.857861e+01 2.365932e+02 -6.000000e+00 2.378777e+02 276.69 -2.00 20.00 -2.00 505.36 0.00e+00 4.437977e-03 1.296346e-05 2.421730e-04 -6.000000e+00 1.205269e-04 276.69 -2.00 20.00 -2.00 500.84 0.00e+00 1.340064e+00 9.243490e-03 4.949145e-02 -6.000000e+00 8.609695e-02 222.51 -2.00 3.57 -2.00 502.38 0.00e+00 13.558 0.048 489.00 513.00 1 -4.3833e+00 7.0711e-04 2.1358e-02 -6.0000e+00 6.5954e-03 -1.8296e-02 1.7956e-04 1.3778e-03 -6.0000e+00 1.7033e-03 2.0136e+01 -7.9027e-04 4.8305e-05 9.5498e-05 -6.0000e+00 4.5359e-04 -5.2480e-03 -1.0641e-04 11 8 0 10 0 0 99.99 21.53 1.78 -0.00525 -0.01073 119 22 1 4 0 424.131 26.62 19.99 21.53 -1073 -812 -334 -37 159 546 577 530 642 537 242 58 -131 -329 -482 -445 -366 235 224 145 42 206 296 529 610 366 300 173 67 -579 -695 -393 -88 292 140 100 61 19 -36 -159 134 146 345 594 429 415 421 132 -105 -324 -630 -1171 -1085 -764 -158 -25 144 201 153 329 559 702 619 443 103 25 -148 -342 -217 -354 -526 -472 -399 -212 -82 -83 -12 -358 -310 -568 -784 -497 -294 -274 -44 -231 -272 -378 -321 -82 60 120 325 372 302 129 -29 -341 -382 -615 -1019 -672 -414 -121 -326 -341 -388 -445 -175 -176 136 208 473 766 816 894 832 797 662 275 345 542 630 531 614 209 256 361 215 208 39 -164 -460 -516 -216 -349 -228 -168 -32 -10 108 276 302 275 28 -43 -227 -328 -585 -639 -979 -755 -320 -36 157 535 574 531 641 530 236 56 -128 -319 -466 -433 -353 231 219 144 42 205 295 530 615 371 303 172 66 -566 -672 -382 -86 292 140 101 61 19 -36 -160 133 146 349 609 435 422 426 135 -106 -320 -625 -1146 -1056 -753 -156 -26 145 204 156 335 571 720 637 456 105 25 -148 -345 -216 -351 -519 -467 -399 -210 -81 -82 -12 -350 -301 -552 -767 -489 -291 -267 -43 -228 -269 -374 -317 -81 60 119 326 374 300 129 -28 -327 -368 -585 -974 -637 -404 -119 -326 -341 -384 -437 -171 -175 138 210 482 787 846 912 855 820 676 285 352 546 636 539 628 216 264 372 223 215 40 -166 -461 -516 -217 -356 -232 -174 -34 -10 112 288 317 290 30 -44 -232 -338 -596 -654 SQ 20221119T125256.8Z 8358.536768 213 1 50.52 2 85.29 122.92 42.51 164.83 0.00 1 0.00 1 0 15 3.517e-03 3.496e-03 3.503e-04 3.500e-04 2.656731e+03 2.072556e+01 1.821131e+02 -6.000000e+00 1.927260e+02 276.69 -2.00 20.00 -2.00 505.33 0.00e+00 3.015073e-03 9.559530e-06 1.649614e-04 -6.000000e+00 9.765512e-05 276.69 -2.00 20.00 -2.00 500.71 0.00e+00 1.124937e+00 6.845296e-03 3.480934e-02 -6.000000e+00 6.980249e-02 222.51 -2.00 3.57 -2.00 502.27 0.00e+00 10.281 0.021 489.00 513.00 1 -4.4741e+00 5.2379e-04 1.5473e-02 -6.0000e+00 5.3465e-03 -1.3737e-02 1.3363e-04 1.0050e-03 -6.0000e+00 1.3819e-03 3.6106e+01 9.5815e-05 3.5766e-05 6.5575e-05 -6.0000e+00 3.6758e-04 -2.3750e-03 -1.7364e-04 10 0 0 10 0 0 99.99 21.54 1.49 -0.00238 -0.00171 192 36 1 4 0 263.102 26.62 20.00 21.54 -790 -583 -271 -15 67 410 609 444 515 443 119 91 -120 -224 -380 -319 -215 79 174 92 -20 159 213 377 457 394 184 57 39 -445 -453 -311 -40 229 84 35 -60 -6 -35 -126 104 171 321 426 348 357 453 78 -79 -327 -693 -983 -998 -591 -108 26 131 132 138 270 423 610 488 328 48 10 -162 -252 -149 -263 -427 -489 -322 -261 -111 -37 -25 -142 -193 -473 -587 -321 -167 -131 13 -256 -165 -257 -274 -75 -3 184 255 305 221 112 -59 -252 -257 -554 -678 -552 -317 -188 -292 -367 -320 -291 -214 -97 56 161 398 591 707 765 663 655 461 276 337 356 519 398 503 147 173 272 115 176 92 -153 -443 -406 -281 -273 -260 -202 -40 60 82 163 350 339 82 -13 -120 -252 -531 -440 -751 -550 -264 -15 66 410 618 455 526 447 119 89 -117 -221 -374 -309 -211 79 175 94 -21 162 217 387 461 397 189 57 38 -441 -443 -306 -39 232 86 36 -61 -6 -35 -128 104 173 327 440 355 365 470 80 -80 -324 -685 -956 -966 -578 -108 26 135 134 140 274 430 621 499 336 49 10 -164 -251 -147 -257 -416 -479 -318 -262 -112 -37 -25 -137 -189 -455 -567 -311 -163 -129 13 -251 -162 -252 -269 -74 -3 185 254 305 219 112 -58 -246 -245 -522 -641 -532 -308 -188 -290 -365 -315 -290 -213 -96 56 164 401 601 723 788 673 664 474 281 337 353 514 397 505 148 174 274 116 177 92 -154 -441 -403 -280 -271 -263 -204 -40 62 85 170 366 348 84 -13 -122 -252 -536 -445 SQ 20221119T130745.2Z 8358.547051 216 1 5.82 2 83.09 125.63 42.00 170.18 0.00 1 0.00 1 0 15 2.946e-03 2.935e-03 1.204e-04 1.203e-04 1.758528e+03 6.922304e+00 1.258966e+02 -6.000000e+00 1.614318e+02 276.69 -2.00 20.00 -2.00 505.31 0.00e+00 1.904475e-03 3.280302e-06 1.049920e-04 -6.000000e+00 8.180148e-05 276.69 -2.00 20.00 -2.00 500.68 0.00e+00 8.748435e-01 2.351016e-03 2.232896e-02 -6.000000e+00 5.847764e-02 222.51 -2.00 3.57 -2.00 502.24 0.00e+00 7.617 0.008 489.00 513.00 1 -8.3264e+00 1.7994e-04 1.1169e-02 -6.0000e+00 4.4790e-03 -1.8519e-02 4.6115e-05 7.0723e-04 -6.0000e+00 1.1579e-03 2.5546e+03 2.6059e-04 1.2328e-05 4.2754e-05 -6.0000e+00 3.0793e-04 -6.6965e-03 -1.5688e-04 10 0 0 10 0 0 23.89 21.55 1.61 -0.00670 -0.00489 543 102 1 4 0 10.684 26.62 20.00 21.55 -552 -409 -255 29 120 366 547 430 476 399 152 98 2 -128 -253 -247 -124 28 181 41 0 156 198 262 423 336 57 57 14 -369 -432 -194 -28 155 72 -127 -82 -77 -71 -156 21 269 315 381 249 355 228 66 -123 -333 -647 -839 -787 -489 -178 14 -12 43 73 229 377 484 383 206 75 -133 -251 -295 -90 -149 -377 -340 -265 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